Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo-...

Autores
Nath, Babul Chandra; Suarez, Sebastian; Doctorovich, Fabio; Roy, Tapashi G.; Baggio, Ricardo Fortunato
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Two copper complex solvatomorphs, namely (3,10-C-meso- 3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane) bis(perchlorato-O)copper(II) 1.2-hydrate, [Cu(ClO4)2 (C18H40N4)]1.2H2O, (I), and (3,10-C-meso-3,5,7,7,10,12,14,14 octamethyl-1,4,8,11-tetraazacyclotetradecane)bis(perchlorato O)copper(II), [Cu(ClO4)2(C18H40N4)], (II), are described and compared with each other and with a third, already reported, anhydrous diastereomer, denoted (III). Both compounds present very similar centrosymmetic coordination environments, with the CuII cation lying on an inversion centre in a distorted 4+2 octahedral environment, defined by the macrocyclic N4 group in the equatorial sites and two perchlorate groups in trans-axial positions [one of the perchlorate ligands in (I) is partially disordered]. The most significant difference in molecular shape is seen in the orientation of the perchlorate anions, and the influence of this on the intramolecular hydrogen bonding is discussed. The (partially) hydrated state of (I) favours the formation of chains along [011], while the anhydrous character of (II) and (III) promotes loosely bound structures with low packing indices.
Fil: Nath, Babul Chandra. University Of Chittagong; Bangladesh
Fil: Suarez, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Doctorovich, Fabio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Roy, Tapashi G.. University of Chittagong; Bangladesh
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica; Argentina
Materia
Solvatomorphic Forms
Copper Complex
Tetraazacyclo-Tetradecane
Coordination
Nivel de accesibilidad
acceso abierto
Condiciones de uso
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Consejo Nacional de Investigaciones Científicas y Técnicas
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Acceder
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network_name_str CONICET Digital (CONICET)
spelling Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecaneNath, Babul ChandraSuarez, SebastianDoctorovich, FabioRoy, Tapashi G.Baggio, Ricardo FortunatoSolvatomorphic FormsCopper ComplexTetraazacyclo-TetradecaneCoordinationhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Two copper complex solvatomorphs, namely (3,10-C-meso- 3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane) bis(perchlorato-O)copper(II) 1.2-hydrate, [Cu(ClO4)2 (C18H40N4)]1.2H2O, (I), and (3,10-C-meso-3,5,7,7,10,12,14,14 octamethyl-1,4,8,11-tetraazacyclotetradecane)bis(perchlorato O)copper(II), [Cu(ClO4)2(C18H40N4)], (II), are described and compared with each other and with a third, already reported, anhydrous diastereomer, denoted (III). Both compounds present very similar centrosymmetic coordination environments, with the CuII cation lying on an inversion centre in a distorted 4+2 octahedral environment, defined by the macrocyclic N4 group in the equatorial sites and two perchlorate groups in trans-axial positions [one of the perchlorate ligands in (I) is partially disordered]. The most significant difference in molecular shape is seen in the orientation of the perchlorate anions, and the influence of this on the intramolecular hydrogen bonding is discussed. The (partially) hydrated state of (I) favours the formation of chains along [011], while the anhydrous character of (II) and (III) promotes loosely bound structures with low packing indices.Fil: Nath, Babul Chandra. University Of Chittagong; BangladeshFil: Suarez, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Doctorovich, Fabio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Roy, Tapashi G.. University of Chittagong; BangladeshFil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica; ArgentinaWiley Blackwell Publishing, Inc2013-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/731Nath, Babul Chandra; Suarez, Sebastian; Doctorovich, Fabio; Roy, Tapashi G.; Baggio, Ricardo Fortunato; Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 69; 7; 3-2013; 689-6950108-2701enginfo:eu-repo/semantics/altIdentifier/doi/10.1107/S0108270113013711info:eu-repo/semantics/altIdentifier/url/http://journals.iucr.org/c/issues/2013/07/00/issconts.htmlinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:11:53Zoai:ri.conicet.gov.ar:11336/731instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:11:54.027CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane
title Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane
spellingShingle Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane
Nath, Babul Chandra
Solvatomorphic Forms
Copper Complex
Tetraazacyclo-Tetradecane
Coordination
title_short Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane
title_full Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane
title_fullStr Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane
title_full_unstemmed Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane
title_sort Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane
dc.creator.none.fl_str_mv Nath, Babul Chandra
Suarez, Sebastian
Doctorovich, Fabio
Roy, Tapashi G.
Baggio, Ricardo Fortunato
author Nath, Babul Chandra
author_facet Nath, Babul Chandra
Suarez, Sebastian
Doctorovich, Fabio
Roy, Tapashi G.
Baggio, Ricardo Fortunato
author_role author
author2 Suarez, Sebastian
Doctorovich, Fabio
Roy, Tapashi G.
Baggio, Ricardo Fortunato
author2_role author
author
author
author
dc.subject.none.fl_str_mv Solvatomorphic Forms
Copper Complex
Tetraazacyclo-Tetradecane
Coordination
topic Solvatomorphic Forms
Copper Complex
Tetraazacyclo-Tetradecane
Coordination
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Two copper complex solvatomorphs, namely (3,10-C-meso- 3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane) bis(perchlorato-O)copper(II) 1.2-hydrate, [Cu(ClO4)2 (C18H40N4)]1.2H2O, (I), and (3,10-C-meso-3,5,7,7,10,12,14,14 octamethyl-1,4,8,11-tetraazacyclotetradecane)bis(perchlorato O)copper(II), [Cu(ClO4)2(C18H40N4)], (II), are described and compared with each other and with a third, already reported, anhydrous diastereomer, denoted (III). Both compounds present very similar centrosymmetic coordination environments, with the CuII cation lying on an inversion centre in a distorted 4+2 octahedral environment, defined by the macrocyclic N4 group in the equatorial sites and two perchlorate groups in trans-axial positions [one of the perchlorate ligands in (I) is partially disordered]. The most significant difference in molecular shape is seen in the orientation of the perchlorate anions, and the influence of this on the intramolecular hydrogen bonding is discussed. The (partially) hydrated state of (I) favours the formation of chains along [011], while the anhydrous character of (II) and (III) promotes loosely bound structures with low packing indices.
Fil: Nath, Babul Chandra. University Of Chittagong; Bangladesh
Fil: Suarez, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Doctorovich, Fabio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Roy, Tapashi G.. University of Chittagong; Bangladesh
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica; Argentina
description Two copper complex solvatomorphs, namely (3,10-C-meso- 3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane) bis(perchlorato-O)copper(II) 1.2-hydrate, [Cu(ClO4)2 (C18H40N4)]1.2H2O, (I), and (3,10-C-meso-3,5,7,7,10,12,14,14 octamethyl-1,4,8,11-tetraazacyclotetradecane)bis(perchlorato O)copper(II), [Cu(ClO4)2(C18H40N4)], (II), are described and compared with each other and with a third, already reported, anhydrous diastereomer, denoted (III). Both compounds present very similar centrosymmetic coordination environments, with the CuII cation lying on an inversion centre in a distorted 4+2 octahedral environment, defined by the macrocyclic N4 group in the equatorial sites and two perchlorate groups in trans-axial positions [one of the perchlorate ligands in (I) is partially disordered]. The most significant difference in molecular shape is seen in the orientation of the perchlorate anions, and the influence of this on the intramolecular hydrogen bonding is discussed. The (partially) hydrated state of (I) favours the formation of chains along [011], while the anhydrous character of (II) and (III) promotes loosely bound structures with low packing indices.
publishDate 2013
dc.date.none.fl_str_mv 2013-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/731
Nath, Babul Chandra; Suarez, Sebastian; Doctorovich, Fabio; Roy, Tapashi G.; Baggio, Ricardo Fortunato; Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 69; 7; 3-2013; 689-695
0108-2701
url http://hdl.handle.net/11336/731
identifier_str_mv Nath, Babul Chandra; Suarez, Sebastian; Doctorovich, Fabio; Roy, Tapashi G.; Baggio, Ricardo Fortunato; Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 69; 7; 3-2013; 689-695
0108-2701
dc.language.none.fl_str_mv eng
language eng
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dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
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eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
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instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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