Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo-...
- Autores
- Nath, Babul Chandra; Suarez, Sebastian; Doctorovich, Fabio; Roy, Tapashi G.; Baggio, Ricardo Fortunato
- Año de publicación
- 2013
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Two copper complex solvatomorphs, namely (3,10-C-meso- 3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane) bis(perchlorato-O)copper(II) 1.2-hydrate, [Cu(ClO4)2 (C18H40N4)]1.2H2O, (I), and (3,10-C-meso-3,5,7,7,10,12,14,14 octamethyl-1,4,8,11-tetraazacyclotetradecane)bis(perchlorato O)copper(II), [Cu(ClO4)2(C18H40N4)], (II), are described and compared with each other and with a third, already reported, anhydrous diastereomer, denoted (III). Both compounds present very similar centrosymmetic coordination environments, with the CuII cation lying on an inversion centre in a distorted 4+2 octahedral environment, defined by the macrocyclic N4 group in the equatorial sites and two perchlorate groups in trans-axial positions [one of the perchlorate ligands in (I) is partially disordered]. The most significant difference in molecular shape is seen in the orientation of the perchlorate anions, and the influence of this on the intramolecular hydrogen bonding is discussed. The (partially) hydrated state of (I) favours the formation of chains along [011], while the anhydrous character of (II) and (III) promotes loosely bound structures with low packing indices.
Fil: Nath, Babul Chandra. University Of Chittagong; Bangladesh
Fil: Suarez, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Doctorovich, Fabio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Roy, Tapashi G.. University of Chittagong; Bangladesh
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica; Argentina - Materia
-
Solvatomorphic Forms
Copper Complex
Tetraazacyclo-Tetradecane
Coordination - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/731
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Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecaneNath, Babul ChandraSuarez, SebastianDoctorovich, FabioRoy, Tapashi G.Baggio, Ricardo FortunatoSolvatomorphic FormsCopper ComplexTetraazacyclo-TetradecaneCoordinationhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Two copper complex solvatomorphs, namely (3,10-C-meso- 3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane) bis(perchlorato-O)copper(II) 1.2-hydrate, [Cu(ClO4)2 (C18H40N4)]1.2H2O, (I), and (3,10-C-meso-3,5,7,7,10,12,14,14 octamethyl-1,4,8,11-tetraazacyclotetradecane)bis(perchlorato O)copper(II), [Cu(ClO4)2(C18H40N4)], (II), are described and compared with each other and with a third, already reported, anhydrous diastereomer, denoted (III). Both compounds present very similar centrosymmetic coordination environments, with the CuII cation lying on an inversion centre in a distorted 4+2 octahedral environment, defined by the macrocyclic N4 group in the equatorial sites and two perchlorate groups in trans-axial positions [one of the perchlorate ligands in (I) is partially disordered]. The most significant difference in molecular shape is seen in the orientation of the perchlorate anions, and the influence of this on the intramolecular hydrogen bonding is discussed. The (partially) hydrated state of (I) favours the formation of chains along [011], while the anhydrous character of (II) and (III) promotes loosely bound structures with low packing indices.Fil: Nath, Babul Chandra. University Of Chittagong; BangladeshFil: Suarez, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Doctorovich, Fabio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Roy, Tapashi G.. University of Chittagong; BangladeshFil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica; ArgentinaWiley Blackwell Publishing, Inc2013-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/731Nath, Babul Chandra; Suarez, Sebastian; Doctorovich, Fabio; Roy, Tapashi G.; Baggio, Ricardo Fortunato; Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 69; 7; 3-2013; 689-6950108-2701enginfo:eu-repo/semantics/altIdentifier/doi/10.1107/S0108270113013711info:eu-repo/semantics/altIdentifier/url/http://journals.iucr.org/c/issues/2013/07/00/issconts.htmlinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:43:16Zoai:ri.conicet.gov.ar:11336/731instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:43:16.461CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane |
title |
Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane |
spellingShingle |
Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane Nath, Babul Chandra Solvatomorphic Forms Copper Complex Tetraazacyclo-Tetradecane Coordination |
title_short |
Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane |
title_full |
Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane |
title_fullStr |
Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane |
title_full_unstemmed |
Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane |
title_sort |
Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane |
dc.creator.none.fl_str_mv |
Nath, Babul Chandra Suarez, Sebastian Doctorovich, Fabio Roy, Tapashi G. Baggio, Ricardo Fortunato |
author |
Nath, Babul Chandra |
author_facet |
Nath, Babul Chandra Suarez, Sebastian Doctorovich, Fabio Roy, Tapashi G. Baggio, Ricardo Fortunato |
author_role |
author |
author2 |
Suarez, Sebastian Doctorovich, Fabio Roy, Tapashi G. Baggio, Ricardo Fortunato |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Solvatomorphic Forms Copper Complex Tetraazacyclo-Tetradecane Coordination |
topic |
Solvatomorphic Forms Copper Complex Tetraazacyclo-Tetradecane Coordination |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Two copper complex solvatomorphs, namely (3,10-C-meso- 3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane) bis(perchlorato-O)copper(II) 1.2-hydrate, [Cu(ClO4)2 (C18H40N4)]1.2H2O, (I), and (3,10-C-meso-3,5,7,7,10,12,14,14 octamethyl-1,4,8,11-tetraazacyclotetradecane)bis(perchlorato O)copper(II), [Cu(ClO4)2(C18H40N4)], (II), are described and compared with each other and with a third, already reported, anhydrous diastereomer, denoted (III). Both compounds present very similar centrosymmetic coordination environments, with the CuII cation lying on an inversion centre in a distorted 4+2 octahedral environment, defined by the macrocyclic N4 group in the equatorial sites and two perchlorate groups in trans-axial positions [one of the perchlorate ligands in (I) is partially disordered]. The most significant difference in molecular shape is seen in the orientation of the perchlorate anions, and the influence of this on the intramolecular hydrogen bonding is discussed. The (partially) hydrated state of (I) favours the formation of chains along [011], while the anhydrous character of (II) and (III) promotes loosely bound structures with low packing indices. Fil: Nath, Babul Chandra. University Of Chittagong; Bangladesh Fil: Suarez, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina Fil: Doctorovich, Fabio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina Fil: Roy, Tapashi G.. University of Chittagong; Bangladesh Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica; Argentina |
description |
Two copper complex solvatomorphs, namely (3,10-C-meso- 3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane) bis(perchlorato-O)copper(II) 1.2-hydrate, [Cu(ClO4)2 (C18H40N4)]1.2H2O, (I), and (3,10-C-meso-3,5,7,7,10,12,14,14 octamethyl-1,4,8,11-tetraazacyclotetradecane)bis(perchlorato O)copper(II), [Cu(ClO4)2(C18H40N4)], (II), are described and compared with each other and with a third, already reported, anhydrous diastereomer, denoted (III). Both compounds present very similar centrosymmetic coordination environments, with the CuII cation lying on an inversion centre in a distorted 4+2 octahedral environment, defined by the macrocyclic N4 group in the equatorial sites and two perchlorate groups in trans-axial positions [one of the perchlorate ligands in (I) is partially disordered]. The most significant difference in molecular shape is seen in the orientation of the perchlorate anions, and the influence of this on the intramolecular hydrogen bonding is discussed. The (partially) hydrated state of (I) favours the formation of chains along [011], while the anhydrous character of (II) and (III) promotes loosely bound structures with low packing indices. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-03 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/731 Nath, Babul Chandra; Suarez, Sebastian; Doctorovich, Fabio; Roy, Tapashi G.; Baggio, Ricardo Fortunato; Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 69; 7; 3-2013; 689-695 0108-2701 |
url |
http://hdl.handle.net/11336/731 |
identifier_str_mv |
Nath, Babul Chandra; Suarez, Sebastian; Doctorovich, Fabio; Roy, Tapashi G.; Baggio, Ricardo Fortunato; Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2- 1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclo- tetradecane; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 69; 7; 3-2013; 689-695 0108-2701 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1107/S0108270113013711 info:eu-repo/semantics/altIdentifier/url/http://journals.iucr.org/c/issues/2013/07/00/issconts.html |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Wiley Blackwell Publishing, Inc |
publisher.none.fl_str_mv |
Wiley Blackwell Publishing, Inc |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613361842520064 |
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13.070432 |