Three transition-metal complexes with the macrocyclic ligand meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (L): [Cu(ClO4)2(L)], [Zn(NO3)2(L)] and [CuCl(L)(H2O)]C...

Autores: Yasmin, S.; Suarez, S.; Doctorovich, F.; Roy, T.G.; Baggio, R.
Año de publicación: 2013
Idioma: inglés
Tipo de recurso: artículo
Estado: versión publicada
Descripción: The three transition-metal complexes, (meso-5,7,7,12,14,14-hexa methyl-1,4,8,11-tetra azacyclo tetra decane-κ4 N)bis (perchlorato-κO)copper(II), [Cu(ClO4)2(C18H40N4)], (I), (meso-5,7,7,12,14,14-hexa methyl-1,4,8,11-tetra azacyclo tetra decane-κ4 N)bis (nitrato-κO)zinc(II), [Zn(NO3)2(C18H40N4)], (II), and aqua chlorido (meso-5,7,7,12,14,14-hexa methyl-1,4,8,11-tetraazacyclo tetra decane-κ4 N)copper(II) chloride, [CuCl(C18H40N4)(H2O)]Cl, (III), are described. The mol ecules display a very similarly distorted 4+2 octa hedral environment for the cation [located at an inversion centre in (I) and (II)], defined by the macrocycle N4 group in the equatorial sites and two further ligands in trans-axial positions [two O-ClO3 ligands in (I), two O-NO2 ligands in (II) and one chloride and one aqua ligand in (III)]. The most significant difference in mol ecular shape resides in these axial ligands, the effect of which on the intra- and inter molecular hydrogen bonding is discussed. In the case of (I), all strong hydrogen-bond donors are saturated in intra molecular inter actions, while weak inter molecular C - H⋯O contacts result in a three-dimensional network. In (II) and (III), instead, there are N - H and O - H donors left over for inter molecular inter actions, giving rise to the formation of strongly linked but weakly inter acting chains. © 2013 International Union of Crystallography.
Fil:Suarez, S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fuente: Acta Crystallogr Sect C Cryst Struct Commun 2013;69(8):862-867
Materia: biologically important compounds
chiral compounds
crystal structure
macrocycles
biologically important compounds
Chiral compounds
Hydrogen-bond donors
Inter molecular hydrogen bondings
Macrocycles
Significant differences
Three-dimensional networks
Transition-metal complex
Chlorine compounds
Crystal structure
Hydrogen bonds
Ligands
Metal complexes
Nitrogen compounds
Paraffins
Zinc
Zinc compounds
Copper
alkane
coordination compound
copper
heterocyclic compound
ligand
macrocyclic compound
n tetradecane
n-tetradecane
zinc
article
biologically important compounds
chemical structure
chemistry
chiral compounds
crystal structure
hydrogen bond
macrocycles
synthesis
X ray crystallography
biologically important compounds
chiral compounds
crystal structure
macrocycles
Alkanes
Aza Compounds
Coordination Complexes
Copper
Crystallography, X-Ray
Hydrogen Bonding
Ligands
Macrocyclic Compounds
Models, Molecular
Zinc
Nivel de accesibilidad: acceso abierto
Condiciones de uso: http://creativecommons.org/licenses/by/2.5/ar
Repositorio
Institución: Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
OAI Identificador: paperaa:paper_01082701_v69_n8_p862_Yasmin

Acceder

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network_acronym_str	BDUBAFCEN
repository_id_str	1896
network_name_str	Biblioteca Digital (UBA-FCEN)
spelling	Three transition-metal complexes with the macrocyclic ligand meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (L): [Cu(ClO4)2(L)], [Zn(NO3)2(L)] and [CuCl(L)(H2O)]ClYasmin, S.Suarez, S.Doctorovich, F.Roy, T.G.Baggio, R.biologically important compoundschiral compoundscrystal structuremacrocyclesbiologically important compoundsChiral compoundsHydrogen-bond donorsInter molecular hydrogen bondingsMacrocyclesSignificant differencesThree-dimensional networksTransition-metal complexChlorine compoundsCrystal structureHydrogen bondsLigandsMetal complexesNitrogen compoundsParaffinsZincZinc compoundsCopperalkanecoordination compoundcopperheterocyclic compoundligandmacrocyclic compoundn tetradecanen-tetradecanezincarticlebiologically important compoundschemical structurechemistrychiral compoundscrystal structurehydrogen bondmacrocyclessynthesisX ray crystallographybiologically important compoundschiral compoundscrystal structuremacrocyclesAlkanesAza CompoundsCoordination ComplexesCopperCrystallography, X-RayHydrogen BondingLigandsMacrocyclic CompoundsModels, MolecularZincThe three transition-metal complexes, (meso-5,7,7,12,14,14-hexa methyl-1,4,8,11-tetra azacyclo tetra decane-κ4 N)bis (perchlorato-κO)copper(II), [Cu(ClO4)2(C18H40N4)], (I), (meso-5,7,7,12,14,14-hexa methyl-1,4,8,11-tetra azacyclo tetra decane-κ4 N)bis (nitrato-κO)zinc(II), [Zn(NO3)2(C18H40N4)], (II), and aqua chlorido (meso-5,7,7,12,14,14-hexa methyl-1,4,8,11-tetraazacyclo tetra decane-κ4 N)copper(II) chloride, [CuCl(C18H40N4)(H2O)]Cl, (III), are described. The mol ecules display a very similarly distorted 4+2 octa hedral environment for the cation [located at an inversion centre in (I) and (II)], defined by the macrocycle N4 group in the equatorial sites and two further ligands in trans-axial positions [two O-ClO3 ligands in (I), two O-NO2 ligands in (II) and one chloride and one aqua ligand in (III)]. The most significant difference in mol ecular shape resides in these axial ligands, the effect of which on the intra- and inter molecular hydrogen bonding is discussed. In the case of (I), all strong hydrogen-bond donors are saturated in intra molecular inter actions, while weak inter molecular C - H⋯O contacts result in a three-dimensional network. In (II) and (III), instead, there are N - H and O - H donors left over for inter molecular inter actions, giving rise to the formation of strongly linked but weakly inter acting chains. © 2013 International Union of Crystallography.Fil:Suarez, S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.2013info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12110/paper_01082701_v69_n8_p862_YasminActa Crystallogr Sect C Cryst Struct Commun 2013;69(8):862-867reponame:Biblioteca Digital (UBA-FCEN)instname:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturalesinstacron:UBA-FCENenginfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/2.5/ar2025-09-29T13:43:03Zpaperaa:paper_01082701_v69_n8_p862_YasminInstitucionalhttps://digital.bl.fcen.uba.ar/Universidad públicaNo correspondehttps://digital.bl.fcen.uba.ar/cgi-bin/oaiserver.cgiana@bl.fcen.uba.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:18962025-09-29 13:43:04.299Biblioteca Digital (UBA-FCEN) - Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturalesfalse
dc.title.none.fl_str_mv	Three transition-metal complexes with the macrocyclic ligand meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (L): [Cu(ClO4)2(L)], [Zn(NO3)2(L)] and [CuCl(L)(H2O)]Cl
title	Three transition-metal complexes with the macrocyclic ligand meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (L): [Cu(ClO4)2(L)], [Zn(NO3)2(L)] and [CuCl(L)(H2O)]Cl
spellingShingle	Three transition-metal complexes with the macrocyclic ligand meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (L): [Cu(ClO4)2(L)], [Zn(NO3)2(L)] and [CuCl(L)(H2O)]Cl Yasmin, S. biologically important compounds chiral compounds crystal structure macrocycles biologically important compounds Chiral compounds Hydrogen-bond donors Inter molecular hydrogen bondings Macrocycles Significant differences Three-dimensional networks Transition-metal complex Chlorine compounds Crystal structure Hydrogen bonds Ligands Metal complexes Nitrogen compounds Paraffins Zinc Zinc compounds Copper alkane coordination compound copper heterocyclic compound ligand macrocyclic compound n tetradecane n-tetradecane zinc article biologically important compounds chemical structure chemistry chiral compounds crystal structure hydrogen bond macrocycles synthesis X ray crystallography biologically important compounds chiral compounds crystal structure macrocycles Alkanes Aza Compounds Coordination Complexes Copper Crystallography, X-Ray Hydrogen Bonding Ligands Macrocyclic Compounds Models, Molecular Zinc
title_short	Three transition-metal complexes with the macrocyclic ligand meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (L): [Cu(ClO4)2(L)], [Zn(NO3)2(L)] and [CuCl(L)(H2O)]Cl
title_full	Three transition-metal complexes with the macrocyclic ligand meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (L): [Cu(ClO4)2(L)], [Zn(NO3)2(L)] and [CuCl(L)(H2O)]Cl
title_fullStr	Three transition-metal complexes with the macrocyclic ligand meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (L): [Cu(ClO4)2(L)], [Zn(NO3)2(L)] and [CuCl(L)(H2O)]Cl
title_full_unstemmed	Three transition-metal complexes with the macrocyclic ligand meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (L): [Cu(ClO4)2(L)], [Zn(NO3)2(L)] and [CuCl(L)(H2O)]Cl
title_sort	Three transition-metal complexes with the macrocyclic ligand meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (L): [Cu(ClO4)2(L)], [Zn(NO3)2(L)] and [CuCl(L)(H2O)]Cl
dc.creator.none.fl_str_mv	Yasmin, S. Suarez, S. Doctorovich, F. Roy, T.G. Baggio, R.
author	Yasmin, S.
author_facet	Yasmin, S. Suarez, S. Doctorovich, F. Roy, T.G. Baggio, R.
author_role	author
author2	Suarez, S. Doctorovich, F. Roy, T.G. Baggio, R.
author2_role	author author author author
dc.subject.none.fl_str_mv	biologically important compounds chiral compounds crystal structure macrocycles biologically important compounds Chiral compounds Hydrogen-bond donors Inter molecular hydrogen bondings Macrocycles Significant differences Three-dimensional networks Transition-metal complex Chlorine compounds Crystal structure Hydrogen bonds Ligands Metal complexes Nitrogen compounds Paraffins Zinc Zinc compounds Copper alkane coordination compound copper heterocyclic compound ligand macrocyclic compound n tetradecane n-tetradecane zinc article biologically important compounds chemical structure chemistry chiral compounds crystal structure hydrogen bond macrocycles synthesis X ray crystallography biologically important compounds chiral compounds crystal structure macrocycles Alkanes Aza Compounds Coordination Complexes Copper Crystallography, X-Ray Hydrogen Bonding Ligands Macrocyclic Compounds Models, Molecular Zinc
topic	biologically important compounds chiral compounds crystal structure macrocycles biologically important compounds Chiral compounds Hydrogen-bond donors Inter molecular hydrogen bondings Macrocycles Significant differences Three-dimensional networks Transition-metal complex Chlorine compounds Crystal structure Hydrogen bonds Ligands Metal complexes Nitrogen compounds Paraffins Zinc Zinc compounds Copper alkane coordination compound copper heterocyclic compound ligand macrocyclic compound n tetradecane n-tetradecane zinc article biologically important compounds chemical structure chemistry chiral compounds crystal structure hydrogen bond macrocycles synthesis X ray crystallography biologically important compounds chiral compounds crystal structure macrocycles Alkanes Aza Compounds Coordination Complexes Copper Crystallography, X-Ray Hydrogen Bonding Ligands Macrocyclic Compounds Models, Molecular Zinc
dc.description.none.fl_txt_mv	The three transition-metal complexes, (meso-5,7,7,12,14,14-hexa methyl-1,4,8,11-tetra azacyclo tetra decane-κ4 N)bis (perchlorato-κO)copper(II), [Cu(ClO4)2(C18H40N4)], (I), (meso-5,7,7,12,14,14-hexa methyl-1,4,8,11-tetra azacyclo tetra decane-κ4 N)bis (nitrato-κO)zinc(II), [Zn(NO3)2(C18H40N4)], (II), and aqua chlorido (meso-5,7,7,12,14,14-hexa methyl-1,4,8,11-tetraazacyclo tetra decane-κ4 N)copper(II) chloride, [CuCl(C18H40N4)(H2O)]Cl, (III), are described. The mol ecules display a very similarly distorted 4+2 octa hedral environment for the cation [located at an inversion centre in (I) and (II)], defined by the macrocycle N4 group in the equatorial sites and two further ligands in trans-axial positions [two O-ClO3 ligands in (I), two O-NO2 ligands in (II) and one chloride and one aqua ligand in (III)]. The most significant difference in mol ecular shape resides in these axial ligands, the effect of which on the intra- and inter molecular hydrogen bonding is discussed. In the case of (I), all strong hydrogen-bond donors are saturated in intra molecular inter actions, while weak inter molecular C - H⋯O contacts result in a three-dimensional network. In (II) and (III), instead, there are N - H and O - H donors left over for inter molecular inter actions, giving rise to the formation of strongly linked but weakly inter acting chains. © 2013 International Union of Crystallography. Fil:Suarez, S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
description	The three transition-metal complexes, (meso-5,7,7,12,14,14-hexa methyl-1,4,8,11-tetra azacyclo tetra decane-κ4 N)bis (perchlorato-κO)copper(II), [Cu(ClO4)2(C18H40N4)], (I), (meso-5,7,7,12,14,14-hexa methyl-1,4,8,11-tetra azacyclo tetra decane-κ4 N)bis (nitrato-κO)zinc(II), [Zn(NO3)2(C18H40N4)], (II), and aqua chlorido (meso-5,7,7,12,14,14-hexa methyl-1,4,8,11-tetraazacyclo tetra decane-κ4 N)copper(II) chloride, [CuCl(C18H40N4)(H2O)]Cl, (III), are described. The mol ecules display a very similarly distorted 4+2 octa hedral environment for the cation [located at an inversion centre in (I) and (II)], defined by the macrocycle N4 group in the equatorial sites and two further ligands in trans-axial positions [two O-ClO3 ligands in (I), two O-NO2 ligands in (II) and one chloride and one aqua ligand in (III)]. The most significant difference in mol ecular shape resides in these axial ligands, the effect of which on the intra- and inter molecular hydrogen bonding is discussed. In the case of (I), all strong hydrogen-bond donors are saturated in intra molecular inter actions, while weak inter molecular C - H⋯O contacts result in a three-dimensional network. In (II) and (III), instead, there are N - H and O - H donors left over for inter molecular inter actions, giving rise to the formation of strongly linked but weakly inter acting chains. © 2013 International Union of Crystallography.
publishDate	2013
dc.date.none.fl_str_mv	2013
dc.type.none.fl_str_mv	info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo
format	article
status_str	publishedVersion
dc.identifier.none.fl_str_mv	http://hdl.handle.net/20.500.12110/paper_01082701_v69_n8_p862_Yasmin
url	http://hdl.handle.net/20.500.12110/paper_01082701_v69_n8_p862_Yasmin
dc.language.none.fl_str_mv	eng
language	eng
dc.rights.none.fl_str_mv	info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar
eu_rights_str_mv	openAccess
rights_invalid_str_mv	http://creativecommons.org/licenses/by/2.5/ar
dc.format.none.fl_str_mv	application/pdf
dc.source.none.fl_str_mv	Acta Crystallogr Sect C Cryst Struct Commun 2013;69(8):862-867 reponame:Biblioteca Digital (UBA-FCEN) instname:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales instacron:UBA-FCEN
reponame_str	Biblioteca Digital (UBA-FCEN)
collection	Biblioteca Digital (UBA-FCEN)
instname_str	Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
instacron_str	UBA-FCEN
institution	UBA-FCEN
repository.name.fl_str_mv	Biblioteca Digital (UBA-FCEN) - Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
repository.mail.fl_str_mv	ana@bl.fcen.uba.ar
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score	13.070432

Three transition-metal complexes with the macrocyclic ligand meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (L): [Cu(ClO4)2(L)], [Zn(NO3)2(L)] and [CuCl(L)(H2O)]C...

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