Cellulose-Based Materials and Their Application in Lithium–Sulfur Batteries

Autores
Zampieri, Muriel; Tommasone, Guillermina; Morel, Luciana; Luque, Guillermina Leticia
Año de publicación
2025
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Lithium–sulfur (Li-S) batteries are promising candidates for next-generationenergy storage due to their high energy density, cost-effectiveness, and environmentalfriendliness. However, their commercialization is hindered by challenges, such as thepolysulfide shuttle effect, lithium dendrite growth, and low electrical conductivity of sulfurcathodes. Cellulose, a natural, renewable, and versatile biopolymer, has emerged asa multifunctional material to address these issues. In anode protection, cellulose-basedcomposites and coatings mitigate dendrite formation and improve lithium-ion diffusion,extending cycle life and enhancing safety. As separators, cellulose materials exhibit highionic conductivity, thermal stability, and excellent wettability, effectively suppressing thepolysulfide shuttle effect and maintaining electrolyte stability. For the cathode, cellulosederivedcarbon frameworks and binders improve sulfur loading, conductivity, and activematerial retention, resulting in higher energy density and cycling stability. This reviewhighlights the diverse roles of cellulose in Li-S batteries, emphasizing its potential to enablesustainable and high-performance energy storage. The integration of cellulose into Li-S systemsnot only enhances electrochemical performance but also aligns with the goals of greenenergy technologies. Further advancements in cellulose processing and functionalizationcould pave the way for its broader application in next-generation battery systems.
Fil: Zampieri, Muriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Tommasone, Guillermina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Morel, Luciana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Luque, Guillermina Leticia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
cellulose
lithium-sulfur
cathode
anode
separator
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/277701
Acceder
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spelling Cellulose-Based Materials and Their Application in Lithium–Sulfur BatteriesZampieri, MurielTommasone, GuillerminaMorel, LucianaLuque, Guillermina Leticiacelluloselithium-sulfurcathodeanodeseparatorhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Lithium–sulfur (Li-S) batteries are promising candidates for next-generationenergy storage due to their high energy density, cost-effectiveness, and environmentalfriendliness. However, their commercialization is hindered by challenges, such as thepolysulfide shuttle effect, lithium dendrite growth, and low electrical conductivity of sulfurcathodes. Cellulose, a natural, renewable, and versatile biopolymer, has emerged asa multifunctional material to address these issues. In anode protection, cellulose-basedcomposites and coatings mitigate dendrite formation and improve lithium-ion diffusion,extending cycle life and enhancing safety. As separators, cellulose materials exhibit highionic conductivity, thermal stability, and excellent wettability, effectively suppressing thepolysulfide shuttle effect and maintaining electrolyte stability. For the cathode, cellulosederivedcarbon frameworks and binders improve sulfur loading, conductivity, and activematerial retention, resulting in higher energy density and cycling stability. This reviewhighlights the diverse roles of cellulose in Li-S batteries, emphasizing its potential to enablesustainable and high-performance energy storage. The integration of cellulose into Li-S systemsnot only enhances electrochemical performance but also aligns with the goals of greenenergy technologies. Further advancements in cellulose processing and functionalizationcould pave the way for its broader application in next-generation battery systems.Fil: Zampieri, Muriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaFil: Tommasone, Guillermina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Morel, Luciana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Luque, Guillermina Leticia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaMDPI2025-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/277701Zampieri, Muriel; Tommasone, Guillermina; Morel, Luciana; Luque, Guillermina Leticia; Cellulose-Based Materials and Their Application in Lithium–Sulfur Batteries; MDPI; Polymers; 17; 2; 1-2025; 1-262073-4360CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4360/17/2/164info:eu-repo/semantics/altIdentifier/doi/10.3390/polym17020164info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-12-23T13:50:05Zoai:ri.conicet.gov.ar:11336/277701instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-12-23 13:50:05.541CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Cellulose-Based Materials and Their Application in Lithium–Sulfur Batteries
title Cellulose-Based Materials and Their Application in Lithium–Sulfur Batteries
spellingShingle Cellulose-Based Materials and Their Application in Lithium–Sulfur Batteries
Zampieri, Muriel
cellulose
lithium-sulfur
cathode
anode
separator
title_short Cellulose-Based Materials and Their Application in Lithium–Sulfur Batteries
title_full Cellulose-Based Materials and Their Application in Lithium–Sulfur Batteries
title_fullStr Cellulose-Based Materials and Their Application in Lithium–Sulfur Batteries
title_full_unstemmed Cellulose-Based Materials and Their Application in Lithium–Sulfur Batteries
title_sort Cellulose-Based Materials and Their Application in Lithium–Sulfur Batteries
dc.creator.none.fl_str_mv Zampieri, Muriel
Tommasone, Guillermina
Morel, Luciana
Luque, Guillermina Leticia
author Zampieri, Muriel
author_facet Zampieri, Muriel
Tommasone, Guillermina
Morel, Luciana
Luque, Guillermina Leticia
author_role author
author2 Tommasone, Guillermina
Morel, Luciana
Luque, Guillermina Leticia
author2_role author
author
author
dc.subject.none.fl_str_mv cellulose
lithium-sulfur
cathode
anode
separator
topic cellulose
lithium-sulfur
cathode
anode
separator
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Lithium–sulfur (Li-S) batteries are promising candidates for next-generationenergy storage due to their high energy density, cost-effectiveness, and environmentalfriendliness. However, their commercialization is hindered by challenges, such as thepolysulfide shuttle effect, lithium dendrite growth, and low electrical conductivity of sulfurcathodes. Cellulose, a natural, renewable, and versatile biopolymer, has emerged asa multifunctional material to address these issues. In anode protection, cellulose-basedcomposites and coatings mitigate dendrite formation and improve lithium-ion diffusion,extending cycle life and enhancing safety. As separators, cellulose materials exhibit highionic conductivity, thermal stability, and excellent wettability, effectively suppressing thepolysulfide shuttle effect and maintaining electrolyte stability. For the cathode, cellulosederivedcarbon frameworks and binders improve sulfur loading, conductivity, and activematerial retention, resulting in higher energy density and cycling stability. This reviewhighlights the diverse roles of cellulose in Li-S batteries, emphasizing its potential to enablesustainable and high-performance energy storage. The integration of cellulose into Li-S systemsnot only enhances electrochemical performance but also aligns with the goals of greenenergy technologies. Further advancements in cellulose processing and functionalizationcould pave the way for its broader application in next-generation battery systems.
Fil: Zampieri, Muriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Tommasone, Guillermina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Morel, Luciana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Luque, Guillermina Leticia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description Lithium–sulfur (Li-S) batteries are promising candidates for next-generationenergy storage due to their high energy density, cost-effectiveness, and environmentalfriendliness. However, their commercialization is hindered by challenges, such as thepolysulfide shuttle effect, lithium dendrite growth, and low electrical conductivity of sulfurcathodes. Cellulose, a natural, renewable, and versatile biopolymer, has emerged asa multifunctional material to address these issues. In anode protection, cellulose-basedcomposites and coatings mitigate dendrite formation and improve lithium-ion diffusion,extending cycle life and enhancing safety. As separators, cellulose materials exhibit highionic conductivity, thermal stability, and excellent wettability, effectively suppressing thepolysulfide shuttle effect and maintaining electrolyte stability. For the cathode, cellulosederivedcarbon frameworks and binders improve sulfur loading, conductivity, and activematerial retention, resulting in higher energy density and cycling stability. This reviewhighlights the diverse roles of cellulose in Li-S batteries, emphasizing its potential to enablesustainable and high-performance energy storage. The integration of cellulose into Li-S systemsnot only enhances electrochemical performance but also aligns with the goals of greenenergy technologies. Further advancements in cellulose processing and functionalizationcould pave the way for its broader application in next-generation battery systems.
publishDate 2025
dc.date.none.fl_str_mv 2025-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/277701
Zampieri, Muriel; Tommasone, Guillermina; Morel, Luciana; Luque, Guillermina Leticia; Cellulose-Based Materials and Their Application in Lithium–Sulfur Batteries; MDPI; Polymers; 17; 2; 1-2025; 1-26
2073-4360
CONICET Digital
CONICET
url http://hdl.handle.net/11336/277701
identifier_str_mv Zampieri, Muriel; Tommasone, Guillermina; Morel, Luciana; Luque, Guillermina Leticia; Cellulose-Based Materials and Their Application in Lithium–Sulfur Batteries; MDPI; Polymers; 17; 2; 1-2025; 1-26
2073-4360
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4360/17/2/164
info:eu-repo/semantics/altIdentifier/doi/10.3390/polym17020164
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.952241

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