Inhibition of steel corrosion by calcium benzoate adsorption in nitrate solutions: Theoretical and experimental approaches

Autores
Blustein, Guillermo; Zinola Sanchez, Carlos Fernandeo
Año de publicación
2004
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The inhibitive effects of calcium benzoate on steel corrosion were studied in sodium nitrate solutions at room temperature. Corrosion parameters of the steel/nitrate and steel/benzoate+nitrate interfaces were obtained from polarization curves. Adsorption parameters of benzoate on steel in sodium nitrate solutions were determined through changes in the degree of surface coverage by the inhibitor, as a function of concentration, time, and adsorption potential. The most likely adsorption configuration of benzoate on iron was envisaged with the help of semiempirical calculations such as extended Hückel calculations. A two-dimensional flat configuration was involving at least two metal atoms, one interacting with the phenolic group and the other with the carboxylate moiety. The effect of chloride on the corrosion inhibition of benzoate was analyzed by exposing the metal to different chloride solution concentrations, from which corrosion parameters were calculated and compared with those in nitrate solutions.
Fil: Blustein, Guillermo. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
Fil: Zinola Sanchez, Carlos Fernandeo. Universidad de la República; Uruguay
Materia
ADSORPTION
CALCIUM BENZOATE
EHMO CALCULATIONS
INHIBITION
STEEL
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/95477
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Inhibition of steel corrosion by calcium benzoate adsorption in nitrate solutions: Theoretical and experimental approachesBlustein, GuillermoZinola Sanchez, Carlos FernandeoADSORPTIONCALCIUM BENZOATEEHMO CALCULATIONSINHIBITIONSTEELhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The inhibitive effects of calcium benzoate on steel corrosion were studied in sodium nitrate solutions at room temperature. Corrosion parameters of the steel/nitrate and steel/benzoate+nitrate interfaces were obtained from polarization curves. Adsorption parameters of benzoate on steel in sodium nitrate solutions were determined through changes in the degree of surface coverage by the inhibitor, as a function of concentration, time, and adsorption potential. The most likely adsorption configuration of benzoate on iron was envisaged with the help of semiempirical calculations such as extended Hückel calculations. A two-dimensional flat configuration was involving at least two metal atoms, one interacting with the phenolic group and the other with the carboxylate moiety. The effect of chloride on the corrosion inhibition of benzoate was analyzed by exposing the metal to different chloride solution concentrations, from which corrosion parameters were calculated and compared with those in nitrate solutions.Fil: Blustein, Guillermo. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: Zinola Sanchez, Carlos Fernandeo. Universidad de la República; UruguayAcademic Press Inc Elsevier Science2004-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/95477Blustein, Guillermo; Zinola Sanchez, Carlos Fernandeo; Inhibition of steel corrosion by calcium benzoate adsorption in nitrate solutions: Theoretical and experimental approaches; Academic Press Inc Elsevier Science; Journal of Colloid and Interface Science; 278; 2; 10-2004; 393-4030021-9797CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/sciencedirect.com/science/article/pii/S0021979704005181info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jcis.2004.06.009info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:29:22Zoai:ri.conicet.gov.ar:11336/95477instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:29:22.862CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Inhibition of steel corrosion by calcium benzoate adsorption in nitrate solutions: Theoretical and experimental approaches
title Inhibition of steel corrosion by calcium benzoate adsorption in nitrate solutions: Theoretical and experimental approaches
spellingShingle Inhibition of steel corrosion by calcium benzoate adsorption in nitrate solutions: Theoretical and experimental approaches
Blustein, Guillermo
ADSORPTION
CALCIUM BENZOATE
EHMO CALCULATIONS
INHIBITION
STEEL
title_short Inhibition of steel corrosion by calcium benzoate adsorption in nitrate solutions: Theoretical and experimental approaches
title_full Inhibition of steel corrosion by calcium benzoate adsorption in nitrate solutions: Theoretical and experimental approaches
title_fullStr Inhibition of steel corrosion by calcium benzoate adsorption in nitrate solutions: Theoretical and experimental approaches
title_full_unstemmed Inhibition of steel corrosion by calcium benzoate adsorption in nitrate solutions: Theoretical and experimental approaches
title_sort Inhibition of steel corrosion by calcium benzoate adsorption in nitrate solutions: Theoretical and experimental approaches
dc.creator.none.fl_str_mv Blustein, Guillermo
Zinola Sanchez, Carlos Fernandeo
author Blustein, Guillermo
author_facet Blustein, Guillermo
Zinola Sanchez, Carlos Fernandeo
author_role author
author2 Zinola Sanchez, Carlos Fernandeo
author2_role author
dc.subject.none.fl_str_mv ADSORPTION
CALCIUM BENZOATE
EHMO CALCULATIONS
INHIBITION
STEEL
topic ADSORPTION
CALCIUM BENZOATE
EHMO CALCULATIONS
INHIBITION
STEEL
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The inhibitive effects of calcium benzoate on steel corrosion were studied in sodium nitrate solutions at room temperature. Corrosion parameters of the steel/nitrate and steel/benzoate+nitrate interfaces were obtained from polarization curves. Adsorption parameters of benzoate on steel in sodium nitrate solutions were determined through changes in the degree of surface coverage by the inhibitor, as a function of concentration, time, and adsorption potential. The most likely adsorption configuration of benzoate on iron was envisaged with the help of semiempirical calculations such as extended Hückel calculations. A two-dimensional flat configuration was involving at least two metal atoms, one interacting with the phenolic group and the other with the carboxylate moiety. The effect of chloride on the corrosion inhibition of benzoate was analyzed by exposing the metal to different chloride solution concentrations, from which corrosion parameters were calculated and compared with those in nitrate solutions.
Fil: Blustein, Guillermo. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
Fil: Zinola Sanchez, Carlos Fernandeo. Universidad de la República; Uruguay
description The inhibitive effects of calcium benzoate on steel corrosion were studied in sodium nitrate solutions at room temperature. Corrosion parameters of the steel/nitrate and steel/benzoate+nitrate interfaces were obtained from polarization curves. Adsorption parameters of benzoate on steel in sodium nitrate solutions were determined through changes in the degree of surface coverage by the inhibitor, as a function of concentration, time, and adsorption potential. The most likely adsorption configuration of benzoate on iron was envisaged with the help of semiempirical calculations such as extended Hückel calculations. A two-dimensional flat configuration was involving at least two metal atoms, one interacting with the phenolic group and the other with the carboxylate moiety. The effect of chloride on the corrosion inhibition of benzoate was analyzed by exposing the metal to different chloride solution concentrations, from which corrosion parameters were calculated and compared with those in nitrate solutions.
publishDate 2004
dc.date.none.fl_str_mv 2004-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/95477
Blustein, Guillermo; Zinola Sanchez, Carlos Fernandeo; Inhibition of steel corrosion by calcium benzoate adsorption in nitrate solutions: Theoretical and experimental approaches; Academic Press Inc Elsevier Science; Journal of Colloid and Interface Science; 278; 2; 10-2004; 393-403
0021-9797
CONICET Digital
CONICET
url http://hdl.handle.net/11336/95477
identifier_str_mv Blustein, Guillermo; Zinola Sanchez, Carlos Fernandeo; Inhibition of steel corrosion by calcium benzoate adsorption in nitrate solutions: Theoretical and experimental approaches; Academic Press Inc Elsevier Science; Journal of Colloid and Interface Science; 278; 2; 10-2004; 393-403
0021-9797
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/sciencedirect.com/science/article/pii/S0021979704005181
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jcis.2004.06.009
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Academic Press Inc Elsevier Science
publisher.none.fl_str_mv Academic Press Inc Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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