Application of pressure programmed absorption and desorption to characterize hydriding and dehydriding kinetics of LaNi5 during activation

Autores
Fuster, Valeria de Los Angeles; Castro, Facundo; Urretavizcaya, Guillermina
Año de publicación
2007
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Hydriding and dehydriding kinetics is an important aspect of the reaction of hydrogen with different hydride forming materials. In particular, it is a key factor in several applications of hydrogen from an energetic point of view. We present here the use of a recently developed technique to characterize hydrogen absorption and desorption kinetics: pressure programmed absorption and desorption (PPAD). The technique is based on an isothermal pressure-ramped measurement of the hydriding and dehydriding rate, and its principal advantages are the absence of an initial blind period, the short time required to complete an experimental run, and the possibility to automatically perform consecutive hydrogen absorption and desorption cycles. To illustrate this, we present the use of PPAD to follow the evolution of hydriding and dehydriding kinetics of LaNi5 during the activation process. Additionally, we analyze the effect of using hydrogen with different purity levels.
Fil: Fuster, Valeria de Los Angeles. Comisión Nacional de Energía Atómica. Gerencia de Área de Aplicaciones de la Tecnología Nuclear. Gerencia de Investigación Aplicada; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Castro, Facundo. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Urretavizcaya, Guillermina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia de Área de Aplicaciones de la Tecnología Nuclear. Gerencia de Investigación Aplicada; Argentina
Materia
HYDROGEN ABSORBING MATERIALS
METAL HYDRIDES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/244163

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spelling Application of pressure programmed absorption and desorption to characterize hydriding and dehydriding kinetics of LaNi5 during activationFuster, Valeria de Los AngelesCastro, FacundoUrretavizcaya, GuillerminaHYDROGEN ABSORBING MATERIALSMETAL HYDRIDEShttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Hydriding and dehydriding kinetics is an important aspect of the reaction of hydrogen with different hydride forming materials. In particular, it is a key factor in several applications of hydrogen from an energetic point of view. We present here the use of a recently developed technique to characterize hydrogen absorption and desorption kinetics: pressure programmed absorption and desorption (PPAD). The technique is based on an isothermal pressure-ramped measurement of the hydriding and dehydriding rate, and its principal advantages are the absence of an initial blind period, the short time required to complete an experimental run, and the possibility to automatically perform consecutive hydrogen absorption and desorption cycles. To illustrate this, we present the use of PPAD to follow the evolution of hydriding and dehydriding kinetics of LaNi5 during the activation process. Additionally, we analyze the effect of using hydrogen with different purity levels.Fil: Fuster, Valeria de Los Angeles. Comisión Nacional de Energía Atómica. Gerencia de Área de Aplicaciones de la Tecnología Nuclear. Gerencia de Investigación Aplicada; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Castro, Facundo. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Urretavizcaya, Guillermina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia de Área de Aplicaciones de la Tecnología Nuclear. Gerencia de Investigación Aplicada; ArgentinaElsevier Science SA2007-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/244163Fuster, Valeria de Los Angeles; Castro, Facundo; Urretavizcaya, Guillermina; Application of pressure programmed absorption and desorption to characterize hydriding and dehydriding kinetics of LaNi5 during activation; Elsevier Science SA; Journal of Alloys and Compounds; 446-447; 10-2007; 224-2270925-8388CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jallcom.2007.02.064info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:40:08Zoai:ri.conicet.gov.ar:11336/244163instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:40:08.607CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Application of pressure programmed absorption and desorption to characterize hydriding and dehydriding kinetics of LaNi5 during activation
title Application of pressure programmed absorption and desorption to characterize hydriding and dehydriding kinetics of LaNi5 during activation
spellingShingle Application of pressure programmed absorption and desorption to characterize hydriding and dehydriding kinetics of LaNi5 during activation
Fuster, Valeria de Los Angeles
HYDROGEN ABSORBING MATERIALS
METAL HYDRIDES
title_short Application of pressure programmed absorption and desorption to characterize hydriding and dehydriding kinetics of LaNi5 during activation
title_full Application of pressure programmed absorption and desorption to characterize hydriding and dehydriding kinetics of LaNi5 during activation
title_fullStr Application of pressure programmed absorption and desorption to characterize hydriding and dehydriding kinetics of LaNi5 during activation
title_full_unstemmed Application of pressure programmed absorption and desorption to characterize hydriding and dehydriding kinetics of LaNi5 during activation
title_sort Application of pressure programmed absorption and desorption to characterize hydriding and dehydriding kinetics of LaNi5 during activation
dc.creator.none.fl_str_mv Fuster, Valeria de Los Angeles
Castro, Facundo
Urretavizcaya, Guillermina
author Fuster, Valeria de Los Angeles
author_facet Fuster, Valeria de Los Angeles
Castro, Facundo
Urretavizcaya, Guillermina
author_role author
author2 Castro, Facundo
Urretavizcaya, Guillermina
author2_role author
author
dc.subject.none.fl_str_mv HYDROGEN ABSORBING MATERIALS
METAL HYDRIDES
topic HYDROGEN ABSORBING MATERIALS
METAL HYDRIDES
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Hydriding and dehydriding kinetics is an important aspect of the reaction of hydrogen with different hydride forming materials. In particular, it is a key factor in several applications of hydrogen from an energetic point of view. We present here the use of a recently developed technique to characterize hydrogen absorption and desorption kinetics: pressure programmed absorption and desorption (PPAD). The technique is based on an isothermal pressure-ramped measurement of the hydriding and dehydriding rate, and its principal advantages are the absence of an initial blind period, the short time required to complete an experimental run, and the possibility to automatically perform consecutive hydrogen absorption and desorption cycles. To illustrate this, we present the use of PPAD to follow the evolution of hydriding and dehydriding kinetics of LaNi5 during the activation process. Additionally, we analyze the effect of using hydrogen with different purity levels.
Fil: Fuster, Valeria de Los Angeles. Comisión Nacional de Energía Atómica. Gerencia de Área de Aplicaciones de la Tecnología Nuclear. Gerencia de Investigación Aplicada; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Castro, Facundo. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Urretavizcaya, Guillermina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia de Área de Aplicaciones de la Tecnología Nuclear. Gerencia de Investigación Aplicada; Argentina
description Hydriding and dehydriding kinetics is an important aspect of the reaction of hydrogen with different hydride forming materials. In particular, it is a key factor in several applications of hydrogen from an energetic point of view. We present here the use of a recently developed technique to characterize hydrogen absorption and desorption kinetics: pressure programmed absorption and desorption (PPAD). The technique is based on an isothermal pressure-ramped measurement of the hydriding and dehydriding rate, and its principal advantages are the absence of an initial blind period, the short time required to complete an experimental run, and the possibility to automatically perform consecutive hydrogen absorption and desorption cycles. To illustrate this, we present the use of PPAD to follow the evolution of hydriding and dehydriding kinetics of LaNi5 during the activation process. Additionally, we analyze the effect of using hydrogen with different purity levels.
publishDate 2007
dc.date.none.fl_str_mv 2007-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/244163
Fuster, Valeria de Los Angeles; Castro, Facundo; Urretavizcaya, Guillermina; Application of pressure programmed absorption and desorption to characterize hydriding and dehydriding kinetics of LaNi5 during activation; Elsevier Science SA; Journal of Alloys and Compounds; 446-447; 10-2007; 224-227
0925-8388
CONICET Digital
CONICET
url http://hdl.handle.net/11336/244163
identifier_str_mv Fuster, Valeria de Los Angeles; Castro, Facundo; Urretavizcaya, Guillermina; Application of pressure programmed absorption and desorption to characterize hydriding and dehydriding kinetics of LaNi5 during activation; Elsevier Science SA; Journal of Alloys and Compounds; 446-447; 10-2007; 224-227
0925-8388
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jallcom.2007.02.064
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science SA
publisher.none.fl_str_mv Elsevier Science SA
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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