Sulfur- and phosphorus-Kβ spectra analyses in sulfite, sulfate and phosphate compounds by X-ray fluorescence spectrometry
- Autores
- Torres Deluigi, María del Rosario; Perino, Ernesto; Olsina, Roberto Antonio; Riveros de la Vega, Jose Alberto
- Año de publicación
- 2003
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Several sulfite, sulfate and phosphate compounds were studied by X-ray fluorescence spectrometry. Sulfur- and phosphorus-Kβ spectral profile modified by the number of bonding hydrogen and oxygen atoms were analyzed. As it could be confirmed, the molecular orbital theory provides a suitable explanation of the origin and properties of the satellite Kβ′ lines. Also, for the compounds analyzed, it was found that sulfur- and phosphorus-Kβ spectra present two main components and two secondary ones which exhibit a different behavior depending on the number of bonding hydrogen and oxygen atoms. Particularly, the peak corresponding to satellite Kβ′ line increases its intensity and moves away from the main peak when the number of oxygen atoms combined with the sulfur atom is increased. The energy differences between the main peak and the satellite peak found in the analyzed compounds were in average 14.2±0.4 eV, thus being demonstrated that such a separation is a characteristic of the bonding atom, in this instance oxygen.
Fil: Torres Deluigi, María del Rosario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Departamento de Física; Argentina
Fil: Perino, Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química. Área de Química Analítica; Argentina
Fil: Olsina, Roberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química. Área de Química Analítica; Argentina
Fil: Riveros de la Vega, Jose Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina - Materia
-
X-ray fluorescence
Satellite lines
Phosphates
Sulfites
Sulfates - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/156800
Ver los metadatos del registro completo
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Sulfur- and phosphorus-Kβ spectra analyses in sulfite, sulfate and phosphate compounds by X-ray fluorescence spectrometryTorres Deluigi, María del RosarioPerino, ErnestoOlsina, Roberto AntonioRiveros de la Vega, Jose AlbertoX-ray fluorescenceSatellite linesPhosphatesSulfitesSulfateshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Several sulfite, sulfate and phosphate compounds were studied by X-ray fluorescence spectrometry. Sulfur- and phosphorus-Kβ spectral profile modified by the number of bonding hydrogen and oxygen atoms were analyzed. As it could be confirmed, the molecular orbital theory provides a suitable explanation of the origin and properties of the satellite Kβ′ lines. Also, for the compounds analyzed, it was found that sulfur- and phosphorus-Kβ spectra present two main components and two secondary ones which exhibit a different behavior depending on the number of bonding hydrogen and oxygen atoms. Particularly, the peak corresponding to satellite Kβ′ line increases its intensity and moves away from the main peak when the number of oxygen atoms combined with the sulfur atom is increased. The energy differences between the main peak and the satellite peak found in the analyzed compounds were in average 14.2±0.4 eV, thus being demonstrated that such a separation is a characteristic of the bonding atom, in this instance oxygen.Fil: Torres Deluigi, María del Rosario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Departamento de Física; ArgentinaFil: Perino, Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química. Área de Química Analítica; ArgentinaFil: Olsina, Roberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química. Área de Química Analítica; ArgentinaFil: Riveros de la Vega, Jose Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; ArgentinaElsevier Science2003-09-26info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/156800Torres Deluigi, María del Rosario; Perino, Ernesto; Olsina, Roberto Antonio; Riveros de la Vega, Jose Alberto; Sulfur- and phosphorus-Kβ spectra analyses in sulfite, sulfate and phosphate compounds by X-ray fluorescence spectrometry; Elsevier Science; Spectrochimica Acta Part B: Atomic Spectroscopy; 58; 9; 26-9-2003; 1699-17070584-8547CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0584854703001551info:eu-repo/semantics/altIdentifier/doi/10.1016/S0584-8547(03)00155-1info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:43:17Zoai:ri.conicet.gov.ar:11336/156800instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:43:17.887CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Sulfur- and phosphorus-Kβ spectra analyses in sulfite, sulfate and phosphate compounds by X-ray fluorescence spectrometry |
title |
Sulfur- and phosphorus-Kβ spectra analyses in sulfite, sulfate and phosphate compounds by X-ray fluorescence spectrometry |
spellingShingle |
Sulfur- and phosphorus-Kβ spectra analyses in sulfite, sulfate and phosphate compounds by X-ray fluorescence spectrometry Torres Deluigi, María del Rosario X-ray fluorescence Satellite lines Phosphates Sulfites Sulfates |
title_short |
Sulfur- and phosphorus-Kβ spectra analyses in sulfite, sulfate and phosphate compounds by X-ray fluorescence spectrometry |
title_full |
Sulfur- and phosphorus-Kβ spectra analyses in sulfite, sulfate and phosphate compounds by X-ray fluorescence spectrometry |
title_fullStr |
Sulfur- and phosphorus-Kβ spectra analyses in sulfite, sulfate and phosphate compounds by X-ray fluorescence spectrometry |
title_full_unstemmed |
Sulfur- and phosphorus-Kβ spectra analyses in sulfite, sulfate and phosphate compounds by X-ray fluorescence spectrometry |
title_sort |
Sulfur- and phosphorus-Kβ spectra analyses in sulfite, sulfate and phosphate compounds by X-ray fluorescence spectrometry |
dc.creator.none.fl_str_mv |
Torres Deluigi, María del Rosario Perino, Ernesto Olsina, Roberto Antonio Riveros de la Vega, Jose Alberto |
author |
Torres Deluigi, María del Rosario |
author_facet |
Torres Deluigi, María del Rosario Perino, Ernesto Olsina, Roberto Antonio Riveros de la Vega, Jose Alberto |
author_role |
author |
author2 |
Perino, Ernesto Olsina, Roberto Antonio Riveros de la Vega, Jose Alberto |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
X-ray fluorescence Satellite lines Phosphates Sulfites Sulfates |
topic |
X-ray fluorescence Satellite lines Phosphates Sulfites Sulfates |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Several sulfite, sulfate and phosphate compounds were studied by X-ray fluorescence spectrometry. Sulfur- and phosphorus-Kβ spectral profile modified by the number of bonding hydrogen and oxygen atoms were analyzed. As it could be confirmed, the molecular orbital theory provides a suitable explanation of the origin and properties of the satellite Kβ′ lines. Also, for the compounds analyzed, it was found that sulfur- and phosphorus-Kβ spectra present two main components and two secondary ones which exhibit a different behavior depending on the number of bonding hydrogen and oxygen atoms. Particularly, the peak corresponding to satellite Kβ′ line increases its intensity and moves away from the main peak when the number of oxygen atoms combined with the sulfur atom is increased. The energy differences between the main peak and the satellite peak found in the analyzed compounds were in average 14.2±0.4 eV, thus being demonstrated that such a separation is a characteristic of the bonding atom, in this instance oxygen. Fil: Torres Deluigi, María del Rosario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Departamento de Física; Argentina Fil: Perino, Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química. Área de Química Analítica; Argentina Fil: Olsina, Roberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química. Área de Química Analítica; Argentina Fil: Riveros de la Vega, Jose Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina |
description |
Several sulfite, sulfate and phosphate compounds were studied by X-ray fluorescence spectrometry. Sulfur- and phosphorus-Kβ spectral profile modified by the number of bonding hydrogen and oxygen atoms were analyzed. As it could be confirmed, the molecular orbital theory provides a suitable explanation of the origin and properties of the satellite Kβ′ lines. Also, for the compounds analyzed, it was found that sulfur- and phosphorus-Kβ spectra present two main components and two secondary ones which exhibit a different behavior depending on the number of bonding hydrogen and oxygen atoms. Particularly, the peak corresponding to satellite Kβ′ line increases its intensity and moves away from the main peak when the number of oxygen atoms combined with the sulfur atom is increased. The energy differences between the main peak and the satellite peak found in the analyzed compounds were in average 14.2±0.4 eV, thus being demonstrated that such a separation is a characteristic of the bonding atom, in this instance oxygen. |
publishDate |
2003 |
dc.date.none.fl_str_mv |
2003-09-26 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/156800 Torres Deluigi, María del Rosario; Perino, Ernesto; Olsina, Roberto Antonio; Riveros de la Vega, Jose Alberto; Sulfur- and phosphorus-Kβ spectra analyses in sulfite, sulfate and phosphate compounds by X-ray fluorescence spectrometry; Elsevier Science; Spectrochimica Acta Part B: Atomic Spectroscopy; 58; 9; 26-9-2003; 1699-1707 0584-8547 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/156800 |
identifier_str_mv |
Torres Deluigi, María del Rosario; Perino, Ernesto; Olsina, Roberto Antonio; Riveros de la Vega, Jose Alberto; Sulfur- and phosphorus-Kβ spectra analyses in sulfite, sulfate and phosphate compounds by X-ray fluorescence spectrometry; Elsevier Science; Spectrochimica Acta Part B: Atomic Spectroscopy; 58; 9; 26-9-2003; 1699-1707 0584-8547 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0584854703001551 info:eu-repo/semantics/altIdentifier/doi/10.1016/S0584-8547(03)00155-1 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614467902504960 |
score |
13.070432 |