Mechanical evaluation of polylactic acid (PLA) based composites reinforced with different calcium phosphates
- Autores
- Pérez, Claudio Javier; Eisenberg, Patricia; Bernal, Celina Raquel; Perez, Ezequiel Martin
- Año de publicación
- 2018
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- In the present work, the mechanical performance of polylactic acid (PLA) based composites reinforced with hydroxyapatite (HA) or β-tricalcium phosphate (β-TCP) was investigated. The polymer was melt compounded with 1 and 2.5 wt% of particles by using an intensive mixer or a twin screw extruder. Morphological, thermal and rheological studies were performed to analyze the composites internal structure and filler-matrix interaction. The mechanical behavior was investigated through uniaxial tensile and quasi-static fracture tests. The different characterization techniques evidenced a better filler dispersion for composites obtained by extrusion independently of the filler used. A relatively weak filler-matrix interaction was revealed from morphological observations and rheological measurements. In addition, thermal analysis evidenced similar crystalline structure for all of the investigated materials. In general, uniaxial tensile parameters displayed almost constant values independently of the filler content or compounding method. Particularly, extruded composites with 2.5 wt% filler exhibited slightly increased ductility respect to neat PLA which was related to improved filler dispersion. The PLA matrix displayed load-displacement curves with ductile instability in quasi-static fracture tests. On the other hand, the composites with 2.5 wt% filler exhibited an increased stable crack growth followed by ductile instability. The fracture process was quantitatively described by means of critical stress intensity factor (K IQ) and strain energy release rate at propagation (G CP) parameters. The extruded composites with 2.5 wt% filler displayed improved propagation fracture toughness. Based on fractured surfaces analysis this enhanced behavior, not largely reported for untreated rigid fillers, was attributed to the effective activation of the toughening mechanisms of particle debonding and subsequent plastic void growth.
Fil: Pérez, Claudio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Eisenberg, Patricia. Instituto Nacional de Tecnología Industrial; Argentina
Fil: Bernal, Celina Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Perez, Ezequiel Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina - Materia
-
Polylactic Acid (PLA)
Calcium phosphates
Mechanical properties
Fracture toughness - Nivel de accesibilidad
- acceso embargado
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/90907
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Mechanical evaluation of polylactic acid (PLA) based composites reinforced with different calcium phosphatesPérez, Claudio JavierEisenberg, PatriciaBernal, Celina RaquelPerez, Ezequiel MartinPolylactic Acid (PLA)Calcium phosphatesMechanical propertiesFracture toughnesshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2In the present work, the mechanical performance of polylactic acid (PLA) based composites reinforced with hydroxyapatite (HA) or β-tricalcium phosphate (β-TCP) was investigated. The polymer was melt compounded with 1 and 2.5 wt% of particles by using an intensive mixer or a twin screw extruder. Morphological, thermal and rheological studies were performed to analyze the composites internal structure and filler-matrix interaction. The mechanical behavior was investigated through uniaxial tensile and quasi-static fracture tests. The different characterization techniques evidenced a better filler dispersion for composites obtained by extrusion independently of the filler used. A relatively weak filler-matrix interaction was revealed from morphological observations and rheological measurements. In addition, thermal analysis evidenced similar crystalline structure for all of the investigated materials. In general, uniaxial tensile parameters displayed almost constant values independently of the filler content or compounding method. Particularly, extruded composites with 2.5 wt% filler exhibited slightly increased ductility respect to neat PLA which was related to improved filler dispersion. The PLA matrix displayed load-displacement curves with ductile instability in quasi-static fracture tests. On the other hand, the composites with 2.5 wt% filler exhibited an increased stable crack growth followed by ductile instability. The fracture process was quantitatively described by means of critical stress intensity factor (K IQ) and strain energy release rate at propagation (G CP) parameters. The extruded composites with 2.5 wt% filler displayed improved propagation fracture toughness. Based on fractured surfaces analysis this enhanced behavior, not largely reported for untreated rigid fillers, was attributed to the effective activation of the toughening mechanisms of particle debonding and subsequent plastic void growth.Fil: Pérez, Claudio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Eisenberg, Patricia. Instituto Nacional de Tecnología Industrial; ArgentinaFil: Bernal, Celina Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; ArgentinaFil: Perez, Ezequiel Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; ArgentinaInstitute of Physics Publishing2018-08-31info:eu-repo/date/embargoEnd/2020-02-18info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/90907Pérez, Claudio Javier; Eisenberg, Patricia; Bernal, Celina Raquel; Perez, Ezequiel Martin; Mechanical evaluation of polylactic acid (PLA) based composites reinforced with different calcium phosphates; Institute of Physics Publishing; Materials Research Express; 5; 10; 31-8-2018; 1053042053-1591CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://iopscience.iop.org/article/10.1088/2053-1591/aadb5binfo:eu-repo/semantics/altIdentifier/doi/10.1088/2053-1591/aadb5binfo:eu-repo/semantics/embargoedAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:43:35Zoai:ri.conicet.gov.ar:11336/90907instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:43:35.464CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Mechanical evaluation of polylactic acid (PLA) based composites reinforced with different calcium phosphates |
title |
Mechanical evaluation of polylactic acid (PLA) based composites reinforced with different calcium phosphates |
spellingShingle |
Mechanical evaluation of polylactic acid (PLA) based composites reinforced with different calcium phosphates Pérez, Claudio Javier Polylactic Acid (PLA) Calcium phosphates Mechanical properties Fracture toughness |
title_short |
Mechanical evaluation of polylactic acid (PLA) based composites reinforced with different calcium phosphates |
title_full |
Mechanical evaluation of polylactic acid (PLA) based composites reinforced with different calcium phosphates |
title_fullStr |
Mechanical evaluation of polylactic acid (PLA) based composites reinforced with different calcium phosphates |
title_full_unstemmed |
Mechanical evaluation of polylactic acid (PLA) based composites reinforced with different calcium phosphates |
title_sort |
Mechanical evaluation of polylactic acid (PLA) based composites reinforced with different calcium phosphates |
dc.creator.none.fl_str_mv |
Pérez, Claudio Javier Eisenberg, Patricia Bernal, Celina Raquel Perez, Ezequiel Martin |
author |
Pérez, Claudio Javier |
author_facet |
Pérez, Claudio Javier Eisenberg, Patricia Bernal, Celina Raquel Perez, Ezequiel Martin |
author_role |
author |
author2 |
Eisenberg, Patricia Bernal, Celina Raquel Perez, Ezequiel Martin |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Polylactic Acid (PLA) Calcium phosphates Mechanical properties Fracture toughness |
topic |
Polylactic Acid (PLA) Calcium phosphates Mechanical properties Fracture toughness |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
In the present work, the mechanical performance of polylactic acid (PLA) based composites reinforced with hydroxyapatite (HA) or β-tricalcium phosphate (β-TCP) was investigated. The polymer was melt compounded with 1 and 2.5 wt% of particles by using an intensive mixer or a twin screw extruder. Morphological, thermal and rheological studies were performed to analyze the composites internal structure and filler-matrix interaction. The mechanical behavior was investigated through uniaxial tensile and quasi-static fracture tests. The different characterization techniques evidenced a better filler dispersion for composites obtained by extrusion independently of the filler used. A relatively weak filler-matrix interaction was revealed from morphological observations and rheological measurements. In addition, thermal analysis evidenced similar crystalline structure for all of the investigated materials. In general, uniaxial tensile parameters displayed almost constant values independently of the filler content or compounding method. Particularly, extruded composites with 2.5 wt% filler exhibited slightly increased ductility respect to neat PLA which was related to improved filler dispersion. The PLA matrix displayed load-displacement curves with ductile instability in quasi-static fracture tests. On the other hand, the composites with 2.5 wt% filler exhibited an increased stable crack growth followed by ductile instability. The fracture process was quantitatively described by means of critical stress intensity factor (K IQ) and strain energy release rate at propagation (G CP) parameters. The extruded composites with 2.5 wt% filler displayed improved propagation fracture toughness. Based on fractured surfaces analysis this enhanced behavior, not largely reported for untreated rigid fillers, was attributed to the effective activation of the toughening mechanisms of particle debonding and subsequent plastic void growth. Fil: Pérez, Claudio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Eisenberg, Patricia. Instituto Nacional de Tecnología Industrial; Argentina Fil: Bernal, Celina Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina Fil: Perez, Ezequiel Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina |
description |
In the present work, the mechanical performance of polylactic acid (PLA) based composites reinforced with hydroxyapatite (HA) or β-tricalcium phosphate (β-TCP) was investigated. The polymer was melt compounded with 1 and 2.5 wt% of particles by using an intensive mixer or a twin screw extruder. Morphological, thermal and rheological studies were performed to analyze the composites internal structure and filler-matrix interaction. The mechanical behavior was investigated through uniaxial tensile and quasi-static fracture tests. The different characterization techniques evidenced a better filler dispersion for composites obtained by extrusion independently of the filler used. A relatively weak filler-matrix interaction was revealed from morphological observations and rheological measurements. In addition, thermal analysis evidenced similar crystalline structure for all of the investigated materials. In general, uniaxial tensile parameters displayed almost constant values independently of the filler content or compounding method. Particularly, extruded composites with 2.5 wt% filler exhibited slightly increased ductility respect to neat PLA which was related to improved filler dispersion. The PLA matrix displayed load-displacement curves with ductile instability in quasi-static fracture tests. On the other hand, the composites with 2.5 wt% filler exhibited an increased stable crack growth followed by ductile instability. The fracture process was quantitatively described by means of critical stress intensity factor (K IQ) and strain energy release rate at propagation (G CP) parameters. The extruded composites with 2.5 wt% filler displayed improved propagation fracture toughness. Based on fractured surfaces analysis this enhanced behavior, not largely reported for untreated rigid fillers, was attributed to the effective activation of the toughening mechanisms of particle debonding and subsequent plastic void growth. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-08-31 info:eu-repo/date/embargoEnd/2020-02-18 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/90907 Pérez, Claudio Javier; Eisenberg, Patricia; Bernal, Celina Raquel; Perez, Ezequiel Martin; Mechanical evaluation of polylactic acid (PLA) based composites reinforced with different calcium phosphates; Institute of Physics Publishing; Materials Research Express; 5; 10; 31-8-2018; 105304 2053-1591 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/90907 |
identifier_str_mv |
Pérez, Claudio Javier; Eisenberg, Patricia; Bernal, Celina Raquel; Perez, Ezequiel Martin; Mechanical evaluation of polylactic acid (PLA) based composites reinforced with different calcium phosphates; Institute of Physics Publishing; Materials Research Express; 5; 10; 31-8-2018; 105304 2053-1591 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://iopscience.iop.org/article/10.1088/2053-1591/aadb5b info:eu-repo/semantics/altIdentifier/doi/10.1088/2053-1591/aadb5b |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/embargoedAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
embargoedAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Institute of Physics Publishing |
publisher.none.fl_str_mv |
Institute of Physics Publishing |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842268611908993024 |
score |
13.13397 |