Phase Equilibria for Quaternary Mixtures in Esterification Reaction Systems

Autores
Campanella, Enrique Angel; Mandagaran, Beatriz Adriana
Año de publicación
2003
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This paper examines the effect of the simultaneous chemical and phase equilibrium on the conceptual design of reactive distillation processes. Esterification of acetic acid with methanol, ethanol and butanol are examined. Using commercial software, azeotropic points, residue curve maps and distillation line diagrams having been calculated. The analyzed systems have showed different behavior when phase equilibrium parameters and chemical equilibrium constants are changed. The methyl acetate system does not change the topological features of residue curve maps and distillation line diagrams. The ethyl acetate system and the butyl acetate system change the topological features of the graphs when different chemical equilibrium constants are used.
Fil: Campanella, Enrique Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Mandagaran, Beatriz Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Materia
CHEMICAL EQUILIBRIUM
ESTERIFICATION
REACTIVE DISTILLATION
REACTIVE SYSTEM
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/100621
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/100621
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Phase Equilibria for Quaternary Mixtures in Esterification Reaction SystemsCampanella, Enrique AngelMandagaran, Beatriz AdrianaCHEMICAL EQUILIBRIUMESTERIFICATIONREACTIVE DISTILLATIONREACTIVE SYSTEMhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2This paper examines the effect of the simultaneous chemical and phase equilibrium on the conceptual design of reactive distillation processes. Esterification of acetic acid with methanol, ethanol and butanol are examined. Using commercial software, azeotropic points, residue curve maps and distillation line diagrams having been calculated. The analyzed systems have showed different behavior when phase equilibrium parameters and chemical equilibrium constants are changed. The methyl acetate system does not change the topological features of residue curve maps and distillation line diagrams. The ethyl acetate system and the butyl acetate system change the topological features of the graphs when different chemical equilibrium constants are used.Fil: Campanella, Enrique Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Mandagaran, Beatriz Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaPlanta Piloto de Ingeniería Química2003-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/100621Campanella, Enrique Angel; Mandagaran, Beatriz Adriana; Phase Equilibria for Quaternary Mixtures in Esterification Reaction Systems; Planta Piloto de Ingeniería Química; Latin American Applied Research; 33; 3; 9-2003; 313-3210327-07931851-8796CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.laar.plapiqui.edu.ar/OJS/public/site/volumens/indexes/artic_v3303/p313.pdfinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:22:40Zoai:ri.conicet.gov.ar:11336/100621instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:22:41.276CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Phase Equilibria for Quaternary Mixtures in Esterification Reaction Systems
title Phase Equilibria for Quaternary Mixtures in Esterification Reaction Systems
spellingShingle Phase Equilibria for Quaternary Mixtures in Esterification Reaction Systems
Campanella, Enrique Angel
CHEMICAL EQUILIBRIUM
ESTERIFICATION
REACTIVE DISTILLATION
REACTIVE SYSTEM
title_short Phase Equilibria for Quaternary Mixtures in Esterification Reaction Systems
title_full Phase Equilibria for Quaternary Mixtures in Esterification Reaction Systems
title_fullStr Phase Equilibria for Quaternary Mixtures in Esterification Reaction Systems
title_full_unstemmed Phase Equilibria for Quaternary Mixtures in Esterification Reaction Systems
title_sort Phase Equilibria for Quaternary Mixtures in Esterification Reaction Systems
dc.creator.none.fl_str_mv Campanella, Enrique Angel
Mandagaran, Beatriz Adriana
author Campanella, Enrique Angel
author_facet Campanella, Enrique Angel
Mandagaran, Beatriz Adriana
author_role author
author2 Mandagaran, Beatriz Adriana
author2_role author
dc.subject.none.fl_str_mv CHEMICAL EQUILIBRIUM
ESTERIFICATION
REACTIVE DISTILLATION
REACTIVE SYSTEM
topic CHEMICAL EQUILIBRIUM
ESTERIFICATION
REACTIVE DISTILLATION
REACTIVE SYSTEM
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv This paper examines the effect of the simultaneous chemical and phase equilibrium on the conceptual design of reactive distillation processes. Esterification of acetic acid with methanol, ethanol and butanol are examined. Using commercial software, azeotropic points, residue curve maps and distillation line diagrams having been calculated. The analyzed systems have showed different behavior when phase equilibrium parameters and chemical equilibrium constants are changed. The methyl acetate system does not change the topological features of residue curve maps and distillation line diagrams. The ethyl acetate system and the butyl acetate system change the topological features of the graphs when different chemical equilibrium constants are used.
Fil: Campanella, Enrique Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Mandagaran, Beatriz Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
description This paper examines the effect of the simultaneous chemical and phase equilibrium on the conceptual design of reactive distillation processes. Esterification of acetic acid with methanol, ethanol and butanol are examined. Using commercial software, azeotropic points, residue curve maps and distillation line diagrams having been calculated. The analyzed systems have showed different behavior when phase equilibrium parameters and chemical equilibrium constants are changed. The methyl acetate system does not change the topological features of residue curve maps and distillation line diagrams. The ethyl acetate system and the butyl acetate system change the topological features of the graphs when different chemical equilibrium constants are used.
publishDate 2003
dc.date.none.fl_str_mv 2003-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/100621
Campanella, Enrique Angel; Mandagaran, Beatriz Adriana; Phase Equilibria for Quaternary Mixtures in Esterification Reaction Systems; Planta Piloto de Ingeniería Química; Latin American Applied Research; 33; 3; 9-2003; 313-321
0327-0793
1851-8796
CONICET Digital
CONICET
url http://hdl.handle.net/11336/100621
identifier_str_mv Campanella, Enrique Angel; Mandagaran, Beatriz Adriana; Phase Equilibria for Quaternary Mixtures in Esterification Reaction Systems; Planta Piloto de Ingeniería Química; Latin American Applied Research; 33; 3; 9-2003; 313-321
0327-0793
1851-8796
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.laar.plapiqui.edu.ar/OJS/public/site/volumens/indexes/artic_v3303/p313.pdf
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Planta Piloto de Ingeniería Química
publisher.none.fl_str_mv Planta Piloto de Ingeniería Química
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.48226

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