Phase Equilibria for Heterogeneous Azeotropic Distillation
- Autores
- Campanella, Enrique Angel; Mandagaran, Beatriz Adriana
- Año de publicación
- 2008
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Heterogeneous azeotropic distillation is used for separating no ideal mixtures. The technique uses minimum-boiling azeotropes and liquid-liquid immiscibilities in combination to break the azeotropes or tangent pinches in the mixture that would prevent the desired separation. However, other configurations are possible. Azeotropic distillation processes are developed using residue curve maps to explain the behavior of entire systems of heterogeneous azeotropic distillation columns as well as the individual columns that make up the system (Pham and Doherty 1990a, 1990b, 1990c). This conceptual design is a starting point to most rigorous design. Nevertheless, to generate a good conceptual design it is necessary to have a no ideal solution model capable of predicting vapor-liquid equilibrium, liquid-liquid equilibrium, vapor-liquid-liquid equilibrium, homogeneous and heterogeneous azeotropic points (Cairns and Furzer, 1990). Recently, a surprising feature of azeotropic distillation columns, multiple steady states, was discovered. It refers to output multiplicities, that is, that a column of a given design exhibits different columns profiles at steady state for the set of inputs and the same values of the operating parameters. This aspect, multiple steady states (MSS), should be studied with azeotropic distillation simulation. In this paper we discuss a recommendation to correlate heterogeneous azeotropic ternary system. The reability of the use of the recommended correlation is analyzed through heterogeneous azeotropic distillation.
Fil: Campanella, Enrique Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Mandagaran, Beatriz Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina - Materia
-
Vapor-Liquid-Liquid Equilibrium
Liquid-Liquid Equilibrium
Heterogeneous Azeotropic Distillation - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/19801
Ver los metadatos del registro completo
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Phase Equilibria for Heterogeneous Azeotropic DistillationCampanella, Enrique AngelMandagaran, Beatriz AdrianaVapor-Liquid-Liquid EquilibriumLiquid-Liquid EquilibriumHeterogeneous Azeotropic Distillationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Heterogeneous azeotropic distillation is used for separating no ideal mixtures. The technique uses minimum-boiling azeotropes and liquid-liquid immiscibilities in combination to break the azeotropes or tangent pinches in the mixture that would prevent the desired separation. However, other configurations are possible. Azeotropic distillation processes are developed using residue curve maps to explain the behavior of entire systems of heterogeneous azeotropic distillation columns as well as the individual columns that make up the system (Pham and Doherty 1990a, 1990b, 1990c). This conceptual design is a starting point to most rigorous design. Nevertheless, to generate a good conceptual design it is necessary to have a no ideal solution model capable of predicting vapor-liquid equilibrium, liquid-liquid equilibrium, vapor-liquid-liquid equilibrium, homogeneous and heterogeneous azeotropic points (Cairns and Furzer, 1990). Recently, a surprising feature of azeotropic distillation columns, multiple steady states, was discovered. It refers to output multiplicities, that is, that a column of a given design exhibits different columns profiles at steady state for the set of inputs and the same values of the operating parameters. This aspect, multiple steady states (MSS), should be studied with azeotropic distillation simulation. In this paper we discuss a recommendation to correlate heterogeneous azeotropic ternary system. The reability of the use of the recommended correlation is analyzed through heterogeneous azeotropic distillation.Fil: Campanella, Enrique Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Mandagaran, Beatriz Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaDe gruyter2008-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/19801Campanella, Enrique Angel; Mandagaran, Beatriz Adriana; Phase Equilibria for Heterogeneous Azeotropic Distillation; De gruyter; Chemical Product and Process Modeling; 3; 1; 3-2008; 1-131934-2659CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.2202/1934-2659.1114info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/view/j/cppm.2008.3.1/cppm.2008.3.1.1114/cppm.2008.3.1.1114.xmlinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:07:19Zoai:ri.conicet.gov.ar:11336/19801instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:07:20.099CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Phase Equilibria for Heterogeneous Azeotropic Distillation |
title |
Phase Equilibria for Heterogeneous Azeotropic Distillation |
spellingShingle |
Phase Equilibria for Heterogeneous Azeotropic Distillation Campanella, Enrique Angel Vapor-Liquid-Liquid Equilibrium Liquid-Liquid Equilibrium Heterogeneous Azeotropic Distillation |
title_short |
Phase Equilibria for Heterogeneous Azeotropic Distillation |
title_full |
Phase Equilibria for Heterogeneous Azeotropic Distillation |
title_fullStr |
Phase Equilibria for Heterogeneous Azeotropic Distillation |
title_full_unstemmed |
Phase Equilibria for Heterogeneous Azeotropic Distillation |
title_sort |
Phase Equilibria for Heterogeneous Azeotropic Distillation |
dc.creator.none.fl_str_mv |
Campanella, Enrique Angel Mandagaran, Beatriz Adriana |
author |
Campanella, Enrique Angel |
author_facet |
Campanella, Enrique Angel Mandagaran, Beatriz Adriana |
author_role |
author |
author2 |
Mandagaran, Beatriz Adriana |
author2_role |
author |
dc.subject.none.fl_str_mv |
Vapor-Liquid-Liquid Equilibrium Liquid-Liquid Equilibrium Heterogeneous Azeotropic Distillation |
topic |
Vapor-Liquid-Liquid Equilibrium Liquid-Liquid Equilibrium Heterogeneous Azeotropic Distillation |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Heterogeneous azeotropic distillation is used for separating no ideal mixtures. The technique uses minimum-boiling azeotropes and liquid-liquid immiscibilities in combination to break the azeotropes or tangent pinches in the mixture that would prevent the desired separation. However, other configurations are possible. Azeotropic distillation processes are developed using residue curve maps to explain the behavior of entire systems of heterogeneous azeotropic distillation columns as well as the individual columns that make up the system (Pham and Doherty 1990a, 1990b, 1990c). This conceptual design is a starting point to most rigorous design. Nevertheless, to generate a good conceptual design it is necessary to have a no ideal solution model capable of predicting vapor-liquid equilibrium, liquid-liquid equilibrium, vapor-liquid-liquid equilibrium, homogeneous and heterogeneous azeotropic points (Cairns and Furzer, 1990). Recently, a surprising feature of azeotropic distillation columns, multiple steady states, was discovered. It refers to output multiplicities, that is, that a column of a given design exhibits different columns profiles at steady state for the set of inputs and the same values of the operating parameters. This aspect, multiple steady states (MSS), should be studied with azeotropic distillation simulation. In this paper we discuss a recommendation to correlate heterogeneous azeotropic ternary system. The reability of the use of the recommended correlation is analyzed through heterogeneous azeotropic distillation. Fil: Campanella, Enrique Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina Fil: Mandagaran, Beatriz Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina |
description |
Heterogeneous azeotropic distillation is used for separating no ideal mixtures. The technique uses minimum-boiling azeotropes and liquid-liquid immiscibilities in combination to break the azeotropes or tangent pinches in the mixture that would prevent the desired separation. However, other configurations are possible. Azeotropic distillation processes are developed using residue curve maps to explain the behavior of entire systems of heterogeneous azeotropic distillation columns as well as the individual columns that make up the system (Pham and Doherty 1990a, 1990b, 1990c). This conceptual design is a starting point to most rigorous design. Nevertheless, to generate a good conceptual design it is necessary to have a no ideal solution model capable of predicting vapor-liquid equilibrium, liquid-liquid equilibrium, vapor-liquid-liquid equilibrium, homogeneous and heterogeneous azeotropic points (Cairns and Furzer, 1990). Recently, a surprising feature of azeotropic distillation columns, multiple steady states, was discovered. It refers to output multiplicities, that is, that a column of a given design exhibits different columns profiles at steady state for the set of inputs and the same values of the operating parameters. This aspect, multiple steady states (MSS), should be studied with azeotropic distillation simulation. In this paper we discuss a recommendation to correlate heterogeneous azeotropic ternary system. The reability of the use of the recommended correlation is analyzed through heterogeneous azeotropic distillation. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-03 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/19801 Campanella, Enrique Angel; Mandagaran, Beatriz Adriana; Phase Equilibria for Heterogeneous Azeotropic Distillation; De gruyter; Chemical Product and Process Modeling; 3; 1; 3-2008; 1-13 1934-2659 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/19801 |
identifier_str_mv |
Campanella, Enrique Angel; Mandagaran, Beatriz Adriana; Phase Equilibria for Heterogeneous Azeotropic Distillation; De gruyter; Chemical Product and Process Modeling; 3; 1; 3-2008; 1-13 1934-2659 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.2202/1934-2659.1114 info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/view/j/cppm.2008.3.1/cppm.2008.3.1.1114/cppm.2008.3.1.1114.xml |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
De gruyter |
publisher.none.fl_str_mv |
De gruyter |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
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13.070432 |