Platinum nanoparticles produced by EG/PVP method: The effect of cleaning on the electrooxidation of glycerol

Autores
Fernández, Pablo Sebastián; Ferreira, Dênis S.; Martins, Cauê A.; Troiani, Horacio Esteban; Câmara, Giuseppe A.; Martins, María Elisa
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Carbon supported Pt nanoparticles (NPs) have been prepared through polyols method using PVP. As observed with a large number of surfactants employed in NPs synthesis, it is very difficult to attain an efficient NPs cleaning, which is a fundamental requirement in catalysis researches. The aim of this paper was to obtain clean NPs, beginning by using “soft” methods, in order to keep unaltered both the NPs size and shape; however, an important surfactant remnant was observed. Consequently, it was performed an electrochemical cleaning through PVP and glycolate electro-oxidation, being accompanied with important perturbations of NPs atoms and dissolution and re-deposition of Pt. Finally, the performance of the catalyst towards the glycerol electro-oxidation reaction (GER), before and after the cleaning process was studied. In addition, we demonstrate how the impurities bring about poor reproducibility in this kind of experiments due to the fact that the cleaning process is occurring at the same time that the GER and because cleaning extent along cycles varies for each independent experiment.
Fil: Fernández, Pablo Sebastián. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
Fil: Ferreira, Dênis S.. Universidade Federal Do Mato Grosso Do Sul; Brasil
Fil: Martins, Cauê A.. Universidade Federal Do Mato Grosso Do Sul; Brasil
Fil: Troiani, Horacio Esteban. Comisión Nacional de Energía Atómica. Gerencia del Area de Investigación y Aplicaciones No Nucleares. Gerencia de Física (Centro Atómico Bariloche); Argentina
Fil: Câmara, Giuseppe A.. Universidade Federal Do Mato Grosso Do Sul; Brasil
Fil: Martins, María Elisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
Materia
Platinum Nanoparticles
Ethylene Glycol Synthesis
Surfactant Removal
Glycerol Electro-Oxidation Reaction
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/4769
Acceder
id CONICETDig_5665bafc20fb263889bab7711a84328f
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network_name_str CONICET Digital (CONICET)
spelling Platinum nanoparticles produced by EG/PVP method: The effect of cleaning on the electrooxidation of glycerolFernández, Pablo SebastiánFerreira, Dênis S.Martins, Cauê A.Troiani, Horacio EstebanCâmara, Giuseppe A.Martins, María ElisaPlatinum NanoparticlesEthylene Glycol SynthesisSurfactant RemovalGlycerol Electro-Oxidation Reactionhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Carbon supported Pt nanoparticles (NPs) have been prepared through polyols method using PVP. As observed with a large number of surfactants employed in NPs synthesis, it is very difficult to attain an efficient NPs cleaning, which is a fundamental requirement in catalysis researches. The aim of this paper was to obtain clean NPs, beginning by using “soft” methods, in order to keep unaltered both the NPs size and shape; however, an important surfactant remnant was observed. Consequently, it was performed an electrochemical cleaning through PVP and glycolate electro-oxidation, being accompanied with important perturbations of NPs atoms and dissolution and re-deposition of Pt. Finally, the performance of the catalyst towards the glycerol electro-oxidation reaction (GER), before and after the cleaning process was studied. In addition, we demonstrate how the impurities bring about poor reproducibility in this kind of experiments due to the fact that the cleaning process is occurring at the same time that the GER and because cleaning extent along cycles varies for each independent experiment.Fil: Fernández, Pablo Sebastián. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; ArgentinaFil: Ferreira, Dênis S.. Universidade Federal Do Mato Grosso Do Sul; BrasilFil: Martins, Cauê A.. Universidade Federal Do Mato Grosso Do Sul; BrasilFil: Troiani, Horacio Esteban. Comisión Nacional de Energía Atómica. Gerencia del Area de Investigación y Aplicaciones No Nucleares. Gerencia de Física (Centro Atómico Bariloche); ArgentinaFil: Câmara, Giuseppe A.. Universidade Federal Do Mato Grosso Do Sul; BrasilFil: Martins, María Elisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; ArgentinaElsevier2013-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/4769Fernández, Pablo Sebastián; Ferreira, Dênis S.; Martins, Cauê A.; Troiani, Horacio Esteban; Câmara, Giuseppe A.; et al.; Platinum nanoparticles produced by EG/PVP method: The effect of cleaning on the electrooxidation of glycerol; Elsevier; Electrochimica Acta; 98; 5-2013; 25-310013-4686enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0013468613003745info:eu-repo/semantics/altIdentifier/doi/10.1016/j.electacta.2013.02.129info:eu-repo/semantics/altIdentifier/issn/0013-4686info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:07:25Zoai:ri.conicet.gov.ar:11336/4769instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:07:25.777CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Platinum nanoparticles produced by EG/PVP method: The effect of cleaning on the electrooxidation of glycerol
title Platinum nanoparticles produced by EG/PVP method: The effect of cleaning on the electrooxidation of glycerol
spellingShingle Platinum nanoparticles produced by EG/PVP method: The effect of cleaning on the electrooxidation of glycerol
Fernández, Pablo Sebastián
Platinum Nanoparticles
Ethylene Glycol Synthesis
Surfactant Removal
Glycerol Electro-Oxidation Reaction
title_short Platinum nanoparticles produced by EG/PVP method: The effect of cleaning on the electrooxidation of glycerol
title_full Platinum nanoparticles produced by EG/PVP method: The effect of cleaning on the electrooxidation of glycerol
title_fullStr Platinum nanoparticles produced by EG/PVP method: The effect of cleaning on the electrooxidation of glycerol
title_full_unstemmed Platinum nanoparticles produced by EG/PVP method: The effect of cleaning on the electrooxidation of glycerol
title_sort Platinum nanoparticles produced by EG/PVP method: The effect of cleaning on the electrooxidation of glycerol
dc.creator.none.fl_str_mv Fernández, Pablo Sebastián
Ferreira, Dênis S.
Martins, Cauê A.
Troiani, Horacio Esteban
Câmara, Giuseppe A.
Martins, María Elisa
author Fernández, Pablo Sebastián
author_facet Fernández, Pablo Sebastián
Ferreira, Dênis S.
Martins, Cauê A.
Troiani, Horacio Esteban
Câmara, Giuseppe A.
Martins, María Elisa
author_role author
author2 Ferreira, Dênis S.
Martins, Cauê A.
Troiani, Horacio Esteban
Câmara, Giuseppe A.
Martins, María Elisa
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Platinum Nanoparticles
Ethylene Glycol Synthesis
Surfactant Removal
Glycerol Electro-Oxidation Reaction
topic Platinum Nanoparticles
Ethylene Glycol Synthesis
Surfactant Removal
Glycerol Electro-Oxidation Reaction
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Carbon supported Pt nanoparticles (NPs) have been prepared through polyols method using PVP. As observed with a large number of surfactants employed in NPs synthesis, it is very difficult to attain an efficient NPs cleaning, which is a fundamental requirement in catalysis researches. The aim of this paper was to obtain clean NPs, beginning by using “soft” methods, in order to keep unaltered both the NPs size and shape; however, an important surfactant remnant was observed. Consequently, it was performed an electrochemical cleaning through PVP and glycolate electro-oxidation, being accompanied with important perturbations of NPs atoms and dissolution and re-deposition of Pt. Finally, the performance of the catalyst towards the glycerol electro-oxidation reaction (GER), before and after the cleaning process was studied. In addition, we demonstrate how the impurities bring about poor reproducibility in this kind of experiments due to the fact that the cleaning process is occurring at the same time that the GER and because cleaning extent along cycles varies for each independent experiment.
Fil: Fernández, Pablo Sebastián. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
Fil: Ferreira, Dênis S.. Universidade Federal Do Mato Grosso Do Sul; Brasil
Fil: Martins, Cauê A.. Universidade Federal Do Mato Grosso Do Sul; Brasil
Fil: Troiani, Horacio Esteban. Comisión Nacional de Energía Atómica. Gerencia del Area de Investigación y Aplicaciones No Nucleares. Gerencia de Física (Centro Atómico Bariloche); Argentina
Fil: Câmara, Giuseppe A.. Universidade Federal Do Mato Grosso Do Sul; Brasil
Fil: Martins, María Elisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
description Carbon supported Pt nanoparticles (NPs) have been prepared through polyols method using PVP. As observed with a large number of surfactants employed in NPs synthesis, it is very difficult to attain an efficient NPs cleaning, which is a fundamental requirement in catalysis researches. The aim of this paper was to obtain clean NPs, beginning by using “soft” methods, in order to keep unaltered both the NPs size and shape; however, an important surfactant remnant was observed. Consequently, it was performed an electrochemical cleaning through PVP and glycolate electro-oxidation, being accompanied with important perturbations of NPs atoms and dissolution and re-deposition of Pt. Finally, the performance of the catalyst towards the glycerol electro-oxidation reaction (GER), before and after the cleaning process was studied. In addition, we demonstrate how the impurities bring about poor reproducibility in this kind of experiments due to the fact that the cleaning process is occurring at the same time that the GER and because cleaning extent along cycles varies for each independent experiment.
publishDate 2013
dc.date.none.fl_str_mv 2013-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/4769
Fernández, Pablo Sebastián; Ferreira, Dênis S.; Martins, Cauê A.; Troiani, Horacio Esteban; Câmara, Giuseppe A.; et al.; Platinum nanoparticles produced by EG/PVP method: The effect of cleaning on the electrooxidation of glycerol; Elsevier; Electrochimica Acta; 98; 5-2013; 25-31
0013-4686
url http://hdl.handle.net/11336/4769
identifier_str_mv Fernández, Pablo Sebastián; Ferreira, Dênis S.; Martins, Cauê A.; Troiani, Horacio Esteban; Câmara, Giuseppe A.; et al.; Platinum nanoparticles produced by EG/PVP method: The effect of cleaning on the electrooxidation of glycerol; Elsevier; Electrochimica Acta; 98; 5-2013; 25-31
0013-4686
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0013468613003745
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.electacta.2013.02.129
info:eu-repo/semantics/altIdentifier/issn/0013-4686
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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