Theoretical insights into homogeneous catalysis impact on ion transfer-electron transfer coupled processes at thick-film modified electrodes

Autores
Fernández, Ricardo Ariel; Zanotto, Franco Martín; Dassie, Sergio Alberto
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The ion transfer-electron transfer coupled reactions that occur in thick-film modified electrodes is analysed in this work, including a homogeneous catalytic reaction in one of the phases. The model of two polarized interfaces composed in series presented investigates the similarities and differences that arise when compared with the classical electrochemical chemical catalytic mechanism (EC’) in a single electrode|solution interface. Special attention is paid to the charge balance of the diffusive flux at each of these two interfaces and to the distribution of the total applied potential at each one. The aim is to find how the applied potential is distributed between the S|L interface and the L|L interface and its dependence on simple external parameters. This will allow us to fully understand the system for its future application in the interfacial electrosynthesis of new materials.
Fil: Fernández, Ricardo Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Zanotto, Franco Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Dassie, Sergio Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
ion transfer-electron transfer
electrochemistry
liquid-liquid interfaces
cumputer simulations
Nivel de accesibilidad
acceso embargado
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/244032
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Theoretical insights into homogeneous catalysis impact on ion transfer-electron transfer coupled processes at thick-film modified electrodesFernández, Ricardo ArielZanotto, Franco MartínDassie, Sergio Albertoion transfer-electron transferelectrochemistryliquid-liquid interfacescumputer simulationshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The ion transfer-electron transfer coupled reactions that occur in thick-film modified electrodes is analysed in this work, including a homogeneous catalytic reaction in one of the phases. The model of two polarized interfaces composed in series presented investigates the similarities and differences that arise when compared with the classical electrochemical chemical catalytic mechanism (EC’) in a single electrode|solution interface. Special attention is paid to the charge balance of the diffusive flux at each of these two interfaces and to the distribution of the total applied potential at each one. The aim is to find how the applied potential is distributed between the S|L interface and the L|L interface and its dependence on simple external parameters. This will allow us to fully understand the system for its future application in the interfacial electrosynthesis of new materials.Fil: Fernández, Ricardo Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Zanotto, Franco Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Dassie, Sergio Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaElsevier Science SA2024-06info:eu-repo/date/embargoEnd/2024-12-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/244032Fernández, Ricardo Ariel; Zanotto, Franco Martín; Dassie, Sergio Alberto; Theoretical insights into homogeneous catalysis impact on ion transfer-electron transfer coupled processes at thick-film modified electrodes; Elsevier Science SA; Journal of Electroanalytical Chemistry; 967; 6-2024; 1-271572-6657CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jelechem.2024.118456info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S157266572400434Xinfo:eu-repo/semantics/embargoedAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:34:53Zoai:ri.conicet.gov.ar:11336/244032instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:34:54.032CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Theoretical insights into homogeneous catalysis impact on ion transfer-electron transfer coupled processes at thick-film modified electrodes
title Theoretical insights into homogeneous catalysis impact on ion transfer-electron transfer coupled processes at thick-film modified electrodes
spellingShingle Theoretical insights into homogeneous catalysis impact on ion transfer-electron transfer coupled processes at thick-film modified electrodes
Fernández, Ricardo Ariel
ion transfer-electron transfer
electrochemistry
liquid-liquid interfaces
cumputer simulations
title_short Theoretical insights into homogeneous catalysis impact on ion transfer-electron transfer coupled processes at thick-film modified electrodes
title_full Theoretical insights into homogeneous catalysis impact on ion transfer-electron transfer coupled processes at thick-film modified electrodes
title_fullStr Theoretical insights into homogeneous catalysis impact on ion transfer-electron transfer coupled processes at thick-film modified electrodes
title_full_unstemmed Theoretical insights into homogeneous catalysis impact on ion transfer-electron transfer coupled processes at thick-film modified electrodes
title_sort Theoretical insights into homogeneous catalysis impact on ion transfer-electron transfer coupled processes at thick-film modified electrodes
dc.creator.none.fl_str_mv Fernández, Ricardo Ariel
Zanotto, Franco Martín
Dassie, Sergio Alberto
author Fernández, Ricardo Ariel
author_facet Fernández, Ricardo Ariel
Zanotto, Franco Martín
Dassie, Sergio Alberto
author_role author
author2 Zanotto, Franco Martín
Dassie, Sergio Alberto
author2_role author
author
dc.subject.none.fl_str_mv ion transfer-electron transfer
electrochemistry
liquid-liquid interfaces
cumputer simulations
topic ion transfer-electron transfer
electrochemistry
liquid-liquid interfaces
cumputer simulations
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The ion transfer-electron transfer coupled reactions that occur in thick-film modified electrodes is analysed in this work, including a homogeneous catalytic reaction in one of the phases. The model of two polarized interfaces composed in series presented investigates the similarities and differences that arise when compared with the classical electrochemical chemical catalytic mechanism (EC’) in a single electrode|solution interface. Special attention is paid to the charge balance of the diffusive flux at each of these two interfaces and to the distribution of the total applied potential at each one. The aim is to find how the applied potential is distributed between the S|L interface and the L|L interface and its dependence on simple external parameters. This will allow us to fully understand the system for its future application in the interfacial electrosynthesis of new materials.
Fil: Fernández, Ricardo Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Zanotto, Franco Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Dassie, Sergio Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description The ion transfer-electron transfer coupled reactions that occur in thick-film modified electrodes is analysed in this work, including a homogeneous catalytic reaction in one of the phases. The model of two polarized interfaces composed in series presented investigates the similarities and differences that arise when compared with the classical electrochemical chemical catalytic mechanism (EC’) in a single electrode|solution interface. Special attention is paid to the charge balance of the diffusive flux at each of these two interfaces and to the distribution of the total applied potential at each one. The aim is to find how the applied potential is distributed between the S|L interface and the L|L interface and its dependence on simple external parameters. This will allow us to fully understand the system for its future application in the interfacial electrosynthesis of new materials.
publishDate 2024
dc.date.none.fl_str_mv 2024-06
info:eu-repo/date/embargoEnd/2024-12-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/244032
Fernández, Ricardo Ariel; Zanotto, Franco Martín; Dassie, Sergio Alberto; Theoretical insights into homogeneous catalysis impact on ion transfer-electron transfer coupled processes at thick-film modified electrodes; Elsevier Science SA; Journal of Electroanalytical Chemistry; 967; 6-2024; 1-27
1572-6657
CONICET Digital
CONICET
url http://hdl.handle.net/11336/244032
identifier_str_mv Fernández, Ricardo Ariel; Zanotto, Franco Martín; Dassie, Sergio Alberto; Theoretical insights into homogeneous catalysis impact on ion transfer-electron transfer coupled processes at thick-film modified electrodes; Elsevier Science SA; Journal of Electroanalytical Chemistry; 967; 6-2024; 1-27
1572-6657
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jelechem.2024.118456
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S157266572400434X
dc.rights.none.fl_str_mv info:eu-repo/semantics/embargoedAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv embargoedAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science SA
publisher.none.fl_str_mv Elsevier Science SA
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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