Tuning the Molecular Sensitivity of Conductive Polymer Resistive Sensors by Chemical Functionalization

Autores
Frontera, Evelina; Cavallo, Pablo César; Olejnik, Robert; Acevedo, Diego Fernando; Slobodian, Petr; Barbero, César Alfredo; Saha, Petr
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Polyaniline thin films are chemically functionalized by nucleophilic addition of thiols beareing different functional groups: carboxylic, amine, -dodecyl and sulfonic. The modification is tested using FTIR and XPS spectroscopy. Then, the films are used as resistive sensors for different volatile organic compounds in a static measuring system. The sensitivity of conducting polymers to alcohols and heptane is strongly affected by the chemical functionalization of the materials. Polyaniline show an increasing signal when the chain length of different alcohols is increased. The incorporation of hydrophilic groups on the PANI chains seems to maintain the trend. On the other hand, the polymer modified with a long alkyl chain (PANI-DOT) show negative response for methanol and the signal increases up to propanol to decrease for longer chains. PANI-DOT show the largest signal for heptane of all polymers tested. Therefore, the functional group attached to the conductive polymer chain can be used to tune the molecular sensitivity of the resistive sensor
Fil: Frontera, Evelina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Cavallo, Pablo César. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Olejnik, Robert. Tomas Bata University in Zlin; República Checa
Fil: Acevedo, Diego Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Slobodian, Petr. Tomas Bata University in Zlin; República Checa
Fil: Barbero, César Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Saha, Petr. Tomas Bata University in Zlin; República Checa
Materia
Conductive Polymer
Functionalization
Resistive Gas Sensor
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/33977
Acceder
id CONICETDig_54247bf6bfce53315143755142afb92c
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Tuning the Molecular Sensitivity of Conductive Polymer Resistive Sensors by Chemical FunctionalizationFrontera, EvelinaCavallo, Pablo CésarOlejnik, RobertAcevedo, Diego FernandoSlobodian, PetrBarbero, César AlfredoSaha, PetrConductive PolymerFunctionalizationResistive Gas Sensorhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Polyaniline thin films are chemically functionalized by nucleophilic addition of thiols beareing different functional groups: carboxylic, amine, -dodecyl and sulfonic. The modification is tested using FTIR and XPS spectroscopy. Then, the films are used as resistive sensors for different volatile organic compounds in a static measuring system. The sensitivity of conducting polymers to alcohols and heptane is strongly affected by the chemical functionalization of the materials. Polyaniline show an increasing signal when the chain length of different alcohols is increased. The incorporation of hydrophilic groups on the PANI chains seems to maintain the trend. On the other hand, the polymer modified with a long alkyl chain (PANI-DOT) show negative response for methanol and the signal increases up to propanol to decrease for longer chains. PANI-DOT show the largest signal for heptane of all polymers tested. Therefore, the functional group attached to the conductive polymer chain can be used to tune the molecular sensitivity of the resistive sensorFil: Frontera, Evelina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Río Cuarto; ArgentinaFil: Cavallo, Pablo César. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Río Cuarto; ArgentinaFil: Olejnik, Robert. Tomas Bata University in Zlin; República ChecaFil: Acevedo, Diego Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Río Cuarto; ArgentinaFil: Slobodian, Petr. Tomas Bata University in Zlin; República ChecaFil: Barbero, César Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Río Cuarto; ArgentinaFil: Saha, Petr. Tomas Bata University in Zlin; República ChecaEvangelos Hristoforou and D.S. Vlachos2014-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/33977Frontera, Evelina; Cavallo, Pablo César; Olejnik, Robert; Acevedo, Diego Fernando; Slobodian, Petr; et al.; Tuning the Molecular Sensitivity of Conductive Polymer Resistive Sensors by Chemical Functionalization; Evangelos Hristoforou and D.S. Vlachos; Key Engineering Materials; 605; 4-2014; 597-6991013-9826CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.scientific.net/KEM.605.597info:eu-repo/semantics/altIdentifier/doi/10.4028/www.scientific.net/KEM.605.597info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:43:52Zoai:ri.conicet.gov.ar:11336/33977instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:43:53.161CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Tuning the Molecular Sensitivity of Conductive Polymer Resistive Sensors by Chemical Functionalization
title Tuning the Molecular Sensitivity of Conductive Polymer Resistive Sensors by Chemical Functionalization
spellingShingle Tuning the Molecular Sensitivity of Conductive Polymer Resistive Sensors by Chemical Functionalization
Frontera, Evelina
Conductive Polymer
Functionalization
Resistive Gas Sensor
title_short Tuning the Molecular Sensitivity of Conductive Polymer Resistive Sensors by Chemical Functionalization
title_full Tuning the Molecular Sensitivity of Conductive Polymer Resistive Sensors by Chemical Functionalization
title_fullStr Tuning the Molecular Sensitivity of Conductive Polymer Resistive Sensors by Chemical Functionalization
title_full_unstemmed Tuning the Molecular Sensitivity of Conductive Polymer Resistive Sensors by Chemical Functionalization
title_sort Tuning the Molecular Sensitivity of Conductive Polymer Resistive Sensors by Chemical Functionalization
dc.creator.none.fl_str_mv Frontera, Evelina
Cavallo, Pablo César
Olejnik, Robert
Acevedo, Diego Fernando
Slobodian, Petr
Barbero, César Alfredo
Saha, Petr
author Frontera, Evelina
author_facet Frontera, Evelina
Cavallo, Pablo César
Olejnik, Robert
Acevedo, Diego Fernando
Slobodian, Petr
Barbero, César Alfredo
Saha, Petr
author_role author
author2 Cavallo, Pablo César
Olejnik, Robert
Acevedo, Diego Fernando
Slobodian, Petr
Barbero, César Alfredo
Saha, Petr
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Conductive Polymer
Functionalization
Resistive Gas Sensor
topic Conductive Polymer
Functionalization
Resistive Gas Sensor
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Polyaniline thin films are chemically functionalized by nucleophilic addition of thiols beareing different functional groups: carboxylic, amine, -dodecyl and sulfonic. The modification is tested using FTIR and XPS spectroscopy. Then, the films are used as resistive sensors for different volatile organic compounds in a static measuring system. The sensitivity of conducting polymers to alcohols and heptane is strongly affected by the chemical functionalization of the materials. Polyaniline show an increasing signal when the chain length of different alcohols is increased. The incorporation of hydrophilic groups on the PANI chains seems to maintain the trend. On the other hand, the polymer modified with a long alkyl chain (PANI-DOT) show negative response for methanol and the signal increases up to propanol to decrease for longer chains. PANI-DOT show the largest signal for heptane of all polymers tested. Therefore, the functional group attached to the conductive polymer chain can be used to tune the molecular sensitivity of the resistive sensor
Fil: Frontera, Evelina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Cavallo, Pablo César. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Olejnik, Robert. Tomas Bata University in Zlin; República Checa
Fil: Acevedo, Diego Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Slobodian, Petr. Tomas Bata University in Zlin; República Checa
Fil: Barbero, César Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Saha, Petr. Tomas Bata University in Zlin; República Checa
description Polyaniline thin films are chemically functionalized by nucleophilic addition of thiols beareing different functional groups: carboxylic, amine, -dodecyl and sulfonic. The modification is tested using FTIR and XPS spectroscopy. Then, the films are used as resistive sensors for different volatile organic compounds in a static measuring system. The sensitivity of conducting polymers to alcohols and heptane is strongly affected by the chemical functionalization of the materials. Polyaniline show an increasing signal when the chain length of different alcohols is increased. The incorporation of hydrophilic groups on the PANI chains seems to maintain the trend. On the other hand, the polymer modified with a long alkyl chain (PANI-DOT) show negative response for methanol and the signal increases up to propanol to decrease for longer chains. PANI-DOT show the largest signal for heptane of all polymers tested. Therefore, the functional group attached to the conductive polymer chain can be used to tune the molecular sensitivity of the resistive sensor
publishDate 2014
dc.date.none.fl_str_mv 2014-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/33977
Frontera, Evelina; Cavallo, Pablo César; Olejnik, Robert; Acevedo, Diego Fernando; Slobodian, Petr; et al.; Tuning the Molecular Sensitivity of Conductive Polymer Resistive Sensors by Chemical Functionalization; Evangelos Hristoforou and D.S. Vlachos; Key Engineering Materials; 605; 4-2014; 597-699
1013-9826
CONICET Digital
CONICET
url http://hdl.handle.net/11336/33977
identifier_str_mv Frontera, Evelina; Cavallo, Pablo César; Olejnik, Robert; Acevedo, Diego Fernando; Slobodian, Petr; et al.; Tuning the Molecular Sensitivity of Conductive Polymer Resistive Sensors by Chemical Functionalization; Evangelos Hristoforou and D.S. Vlachos; Key Engineering Materials; 605; 4-2014; 597-699
1013-9826
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.scientific.net/KEM.605.597
info:eu-repo/semantics/altIdentifier/doi/10.4028/www.scientific.net/KEM.605.597
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Evangelos Hristoforou and D.S. Vlachos
publisher.none.fl_str_mv Evangelos Hristoforou and D.S. Vlachos
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613380877320192
score 13.070432

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