Towards sustainable biofuel production: Design of a new biocatalyst to biodiesel synthesis from waste oil and commercial ethanol

Autores
Ferrero, Gabriel Orlando; Rojas, Hernan Javier; Argaraña, Carlos Enrique; Eimer, Griselda Alejandra
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The sustainable technologies to produce alternative energies as biofuel with focus on the harnessing of renewable sources and waste biomass is gradually gaining ground. Although the biodiesel is a very attractive biofuel its production from vegetable oils competes with the feed generation with the consequent socio-economic costs involved. Therefore, the reuse of waste oils appears as an alternative highly promising. However the high content of free fatty acid and water in this raw material difficult its use in the conventional processes employed in the actuality. In this work, we successfully develop hybrid catalysts based in Pseudomonas fluorescens lipase immobilized over Ca and Na modified mesoporous SBA-15 supports. The physic-chemical properties of the supports were determined by Small-angle X-ray Scattering (SAXS), Transmission Electron Microscopy (TEM), Scanning Electron Microscope (SEM), Infrared Spectroscopy (IR), Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP) and N2 adsorption measurements. These hybrid catalysts were capable to process waste oils, and even, commercial ethanol (96%) obtained from a fermentative process An optimum activity, with around 90% of FAEE yield, was achieved with lipase immobilized on Ca modified SBA-15 using 4% of water respect to oil, 1:4 oil/ethanol ratio, 400 mg/g of enzyme immobilized, at 37 °C and 180 oscillations/min. This catalyst could contribute to development of a more environmentally and economically viable process to biodiesel production.
Fil: Ferrero, Gabriel Orlando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Rojas, Hernan Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Transferencia Tecnológica de La Rioja. - Universidad Nacional de La Rioja. Centro Regional de Investigaciones Científicas y Transferencia Tecnológica de La Rioja. - Universidad Nacional de Catamarca. Centro Regional de Investigaciones Científicas y Transferencia Tecnológica de la Rioja. - Secretaria de Industria y Minería. Servicio Geológico Minero Argentino. Centro Regional de Investigaciones Científicas y Transferencia Tecnológica de La Rioja. - Provincia de La Rioja. Centro Regional de Investigaciones Científicas y Transferencia Tecnológica de La Rioja; Argentina
Fil: Argaraña, Carlos Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Química Biológica de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Centro de Investigaciones en Química Biológica de Córdoba; Argentina
Fil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Materia
Biodiesel
Enzymatic Immobilization
Sba-15
Soybean
Sunflower And Friyng Oils
Commercial Ethanol
Biocatalysis
Alternative Energies
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31971
Acceder
id CONICETDig_53e958b2a0d4c22380b1c13b0f3dee79
oai_identifier_str oai:ri.conicet.gov.ar:11336/31971
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Towards sustainable biofuel production: Design of a new biocatalyst to biodiesel synthesis from waste oil and commercial ethanolFerrero, Gabriel OrlandoRojas, Hernan JavierArgaraña, Carlos EnriqueEimer, Griselda AlejandraBiodieselEnzymatic ImmobilizationSba-15SoybeanSunflower And Friyng OilsCommercial EthanolBiocatalysisAlternative Energieshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The sustainable technologies to produce alternative energies as biofuel with focus on the harnessing of renewable sources and waste biomass is gradually gaining ground. Although the biodiesel is a very attractive biofuel its production from vegetable oils competes with the feed generation with the consequent socio-economic costs involved. Therefore, the reuse of waste oils appears as an alternative highly promising. However the high content of free fatty acid and water in this raw material difficult its use in the conventional processes employed in the actuality. In this work, we successfully develop hybrid catalysts based in Pseudomonas fluorescens lipase immobilized over Ca and Na modified mesoporous SBA-15 supports. The physic-chemical properties of the supports were determined by Small-angle X-ray Scattering (SAXS), Transmission Electron Microscopy (TEM), Scanning Electron Microscope (SEM), Infrared Spectroscopy (IR), Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP) and N2 adsorption measurements. These hybrid catalysts were capable to process waste oils, and even, commercial ethanol (96%) obtained from a fermentative process An optimum activity, with around 90% of FAEE yield, was achieved with lipase immobilized on Ca modified SBA-15 using 4% of water respect to oil, 1:4 oil/ethanol ratio, 400 mg/g of enzyme immobilized, at 37 °C and 180 oscillations/min. This catalyst could contribute to development of a more environmentally and economically viable process to biodiesel production.Fil: Ferrero, Gabriel Orlando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Rojas, Hernan Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Transferencia Tecnológica de La Rioja. - Universidad Nacional de La Rioja. Centro Regional de Investigaciones Científicas y Transferencia Tecnológica de La Rioja. - Universidad Nacional de Catamarca. Centro Regional de Investigaciones Científicas y Transferencia Tecnológica de la Rioja. - Secretaria de Industria y Minería. Servicio Geológico Minero Argentino. Centro Regional de Investigaciones Científicas y Transferencia Tecnológica de La Rioja. - Provincia de La Rioja. Centro Regional de Investigaciones Científicas y Transferencia Tecnológica de La Rioja; ArgentinaFil: Argaraña, Carlos Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Química Biológica de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Centro de Investigaciones en Química Biológica de Córdoba; ArgentinaFil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaElsevier2016-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31971Eimer, Griselda Alejandra; Argaraña, Carlos Enrique; Rojas, Hernan Javier; Ferrero, Gabriel Orlando; Towards sustainable biofuel production: Design of a new biocatalyst to biodiesel synthesis from waste oil and commercial ethanol; Elsevier; Journal Of Cleaner Production; 139; 8-2016; 495-5030959-6526CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jclepro.2016.08.047info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S095965261631191Xinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:46:45Zoai:ri.conicet.gov.ar:11336/31971instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:46:45.87CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Towards sustainable biofuel production: Design of a new biocatalyst to biodiesel synthesis from waste oil and commercial ethanol
title Towards sustainable biofuel production: Design of a new biocatalyst to biodiesel synthesis from waste oil and commercial ethanol
spellingShingle Towards sustainable biofuel production: Design of a new biocatalyst to biodiesel synthesis from waste oil and commercial ethanol
Ferrero, Gabriel Orlando
Biodiesel
Enzymatic Immobilization
Sba-15
Soybean
Sunflower And Friyng Oils
Commercial Ethanol
Biocatalysis
Alternative Energies
title_short Towards sustainable biofuel production: Design of a new biocatalyst to biodiesel synthesis from waste oil and commercial ethanol
title_full Towards sustainable biofuel production: Design of a new biocatalyst to biodiesel synthesis from waste oil and commercial ethanol
title_fullStr Towards sustainable biofuel production: Design of a new biocatalyst to biodiesel synthesis from waste oil and commercial ethanol
title_full_unstemmed Towards sustainable biofuel production: Design of a new biocatalyst to biodiesel synthesis from waste oil and commercial ethanol
title_sort Towards sustainable biofuel production: Design of a new biocatalyst to biodiesel synthesis from waste oil and commercial ethanol
dc.creator.none.fl_str_mv Ferrero, Gabriel Orlando
Rojas, Hernan Javier
Argaraña, Carlos Enrique
Eimer, Griselda Alejandra
author Ferrero, Gabriel Orlando
author_facet Ferrero, Gabriel Orlando
Rojas, Hernan Javier
Argaraña, Carlos Enrique
Eimer, Griselda Alejandra
author_role author
author2 Rojas, Hernan Javier
Argaraña, Carlos Enrique
Eimer, Griselda Alejandra
author2_role author
author
author
dc.subject.none.fl_str_mv Biodiesel
Enzymatic Immobilization
Sba-15
Soybean
Sunflower And Friyng Oils
Commercial Ethanol
Biocatalysis
Alternative Energies
topic Biodiesel
Enzymatic Immobilization
Sba-15
Soybean
Sunflower And Friyng Oils
Commercial Ethanol
Biocatalysis
Alternative Energies
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The sustainable technologies to produce alternative energies as biofuel with focus on the harnessing of renewable sources and waste biomass is gradually gaining ground. Although the biodiesel is a very attractive biofuel its production from vegetable oils competes with the feed generation with the consequent socio-economic costs involved. Therefore, the reuse of waste oils appears as an alternative highly promising. However the high content of free fatty acid and water in this raw material difficult its use in the conventional processes employed in the actuality. In this work, we successfully develop hybrid catalysts based in Pseudomonas fluorescens lipase immobilized over Ca and Na modified mesoporous SBA-15 supports. The physic-chemical properties of the supports were determined by Small-angle X-ray Scattering (SAXS), Transmission Electron Microscopy (TEM), Scanning Electron Microscope (SEM), Infrared Spectroscopy (IR), Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP) and N2 adsorption measurements. These hybrid catalysts were capable to process waste oils, and even, commercial ethanol (96%) obtained from a fermentative process An optimum activity, with around 90% of FAEE yield, was achieved with lipase immobilized on Ca modified SBA-15 using 4% of water respect to oil, 1:4 oil/ethanol ratio, 400 mg/g of enzyme immobilized, at 37 °C and 180 oscillations/min. This catalyst could contribute to development of a more environmentally and economically viable process to biodiesel production.
Fil: Ferrero, Gabriel Orlando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Rojas, Hernan Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Transferencia Tecnológica de La Rioja. - Universidad Nacional de La Rioja. Centro Regional de Investigaciones Científicas y Transferencia Tecnológica de La Rioja. - Universidad Nacional de Catamarca. Centro Regional de Investigaciones Científicas y Transferencia Tecnológica de la Rioja. - Secretaria de Industria y Minería. Servicio Geológico Minero Argentino. Centro Regional de Investigaciones Científicas y Transferencia Tecnológica de La Rioja. - Provincia de La Rioja. Centro Regional de Investigaciones Científicas y Transferencia Tecnológica de La Rioja; Argentina
Fil: Argaraña, Carlos Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Química Biológica de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Centro de Investigaciones en Química Biológica de Córdoba; Argentina
Fil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
description The sustainable technologies to produce alternative energies as biofuel with focus on the harnessing of renewable sources and waste biomass is gradually gaining ground. Although the biodiesel is a very attractive biofuel its production from vegetable oils competes with the feed generation with the consequent socio-economic costs involved. Therefore, the reuse of waste oils appears as an alternative highly promising. However the high content of free fatty acid and water in this raw material difficult its use in the conventional processes employed in the actuality. In this work, we successfully develop hybrid catalysts based in Pseudomonas fluorescens lipase immobilized over Ca and Na modified mesoporous SBA-15 supports. The physic-chemical properties of the supports were determined by Small-angle X-ray Scattering (SAXS), Transmission Electron Microscopy (TEM), Scanning Electron Microscope (SEM), Infrared Spectroscopy (IR), Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP) and N2 adsorption measurements. These hybrid catalysts were capable to process waste oils, and even, commercial ethanol (96%) obtained from a fermentative process An optimum activity, with around 90% of FAEE yield, was achieved with lipase immobilized on Ca modified SBA-15 using 4% of water respect to oil, 1:4 oil/ethanol ratio, 400 mg/g of enzyme immobilized, at 37 °C and 180 oscillations/min. This catalyst could contribute to development of a more environmentally and economically viable process to biodiesel production.
publishDate 2016
dc.date.none.fl_str_mv 2016-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31971
Eimer, Griselda Alejandra; Argaraña, Carlos Enrique; Rojas, Hernan Javier; Ferrero, Gabriel Orlando; Towards sustainable biofuel production: Design of a new biocatalyst to biodiesel synthesis from waste oil and commercial ethanol; Elsevier; Journal Of Cleaner Production; 139; 8-2016; 495-503
0959-6526
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31971
identifier_str_mv Eimer, Griselda Alejandra; Argaraña, Carlos Enrique; Rojas, Hernan Javier; Ferrero, Gabriel Orlando; Towards sustainable biofuel production: Design of a new biocatalyst to biodiesel synthesis from waste oil and commercial ethanol; Elsevier; Journal Of Cleaner Production; 139; 8-2016; 495-503
0959-6526
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jclepro.2016.08.047
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S095965261631191X
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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