Two products one catalyst: Emulsifiers and biodiesel production combining enzymology, nanostructured materials engineering and simulation models

Autores
Ferrero, Gabriel Orlando; Sánchez Faba, Edgar Maximiliano; Eimer, Griselda Alejandra
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Crises are the driving force of the inventions that have led man to overcome himself. The challenge that concerns us today is to maintain our lifestyle with the energy expenditure involved. In the present work, it's proposed the production of emulsifiers such as monoglycerides (MG) and diglycerides (DG) and biodiesel (FAEE) from renewable sources using Pseudomonas fluorescens lipase immobilized over Ca modified mesoporous SBA-15 supports (LPF/Ca/SBA-15) as biocatalyst. Using a packed bed reactor thermostated at 37 °C, the catalyst was capable to convert sunflower oil and commercial ethanol (96 wt%) into FAEE (35.0 wt%), MG (12.2 wt%) and DG (43.2 wt%). From these results, a separation by vacuum distillation was simulated. A good separation of the biodiesel in the top of the column at approx. 325 °C and the emulsifiers in the bottom of the column at 484 °C, was obtained. Thus, from interdisciplinary technologies such as enzymology, nanostructured materials design and computer simulation, a project for the production and purification of two products, emulsifiers and biodiesel, with one catalyst is offered.
Fil: Ferrero, Gabriel Orlando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Sánchez Faba, Edgar Maximiliano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Materia
BIOCATALYSIS
BIODIESEL
EMULSIFIERS
SBA-15
COMMERCIAL ETHANOL
VACUUM DISTILLATION SIMULATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/88171
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/88171
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Two products one catalyst: Emulsifiers and biodiesel production combining enzymology, nanostructured materials engineering and simulation modelsFerrero, Gabriel OrlandoSánchez Faba, Edgar MaximilianoEimer, Griselda AlejandraBIOCATALYSISBIODIESELEMULSIFIERSSBA-15COMMERCIAL ETHANOLVACUUM DISTILLATION SIMULATIONhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Crises are the driving force of the inventions that have led man to overcome himself. The challenge that concerns us today is to maintain our lifestyle with the energy expenditure involved. In the present work, it's proposed the production of emulsifiers such as monoglycerides (MG) and diglycerides (DG) and biodiesel (FAEE) from renewable sources using Pseudomonas fluorescens lipase immobilized over Ca modified mesoporous SBA-15 supports (LPF/Ca/SBA-15) as biocatalyst. Using a packed bed reactor thermostated at 37 °C, the catalyst was capable to convert sunflower oil and commercial ethanol (96 wt%) into FAEE (35.0 wt%), MG (12.2 wt%) and DG (43.2 wt%). From these results, a separation by vacuum distillation was simulated. A good separation of the biodiesel in the top of the column at approx. 325 °C and the emulsifiers in the bottom of the column at 484 °C, was obtained. Thus, from interdisciplinary technologies such as enzymology, nanostructured materials design and computer simulation, a project for the production and purification of two products, emulsifiers and biodiesel, with one catalyst is offered.Fil: Ferrero, Gabriel Orlando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Sánchez Faba, Edgar Maximiliano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaElsevier Science Sa2018-09-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/88171Ferrero, Gabriel Orlando; Sánchez Faba, Edgar Maximiliano; Eimer, Griselda Alejandra; Two products one catalyst: Emulsifiers and biodiesel production combining enzymology, nanostructured materials engineering and simulation models; Elsevier Science Sa; Chemical Engineering Journal; 348; 15-9-2018; 960-9651385-8947CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1385894718308374?via%3Dihubinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2018.05.048info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:46:19Zoai:ri.conicet.gov.ar:11336/88171instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:46:19.845CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Two products one catalyst: Emulsifiers and biodiesel production combining enzymology, nanostructured materials engineering and simulation models
title Two products one catalyst: Emulsifiers and biodiesel production combining enzymology, nanostructured materials engineering and simulation models
spellingShingle Two products one catalyst: Emulsifiers and biodiesel production combining enzymology, nanostructured materials engineering and simulation models
Ferrero, Gabriel Orlando
BIOCATALYSIS
BIODIESEL
EMULSIFIERS
SBA-15
COMMERCIAL ETHANOL
VACUUM DISTILLATION SIMULATION
title_short Two products one catalyst: Emulsifiers and biodiesel production combining enzymology, nanostructured materials engineering and simulation models
title_full Two products one catalyst: Emulsifiers and biodiesel production combining enzymology, nanostructured materials engineering and simulation models
title_fullStr Two products one catalyst: Emulsifiers and biodiesel production combining enzymology, nanostructured materials engineering and simulation models
title_full_unstemmed Two products one catalyst: Emulsifiers and biodiesel production combining enzymology, nanostructured materials engineering and simulation models
title_sort Two products one catalyst: Emulsifiers and biodiesel production combining enzymology, nanostructured materials engineering and simulation models
dc.creator.none.fl_str_mv Ferrero, Gabriel Orlando
Sánchez Faba, Edgar Maximiliano
Eimer, Griselda Alejandra
author Ferrero, Gabriel Orlando
author_facet Ferrero, Gabriel Orlando
Sánchez Faba, Edgar Maximiliano
Eimer, Griselda Alejandra
author_role author
author2 Sánchez Faba, Edgar Maximiliano
Eimer, Griselda Alejandra
author2_role author
author
dc.subject.none.fl_str_mv BIOCATALYSIS
BIODIESEL
EMULSIFIERS
SBA-15
COMMERCIAL ETHANOL
VACUUM DISTILLATION SIMULATION
topic BIOCATALYSIS
BIODIESEL
EMULSIFIERS
SBA-15
COMMERCIAL ETHANOL
VACUUM DISTILLATION SIMULATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Crises are the driving force of the inventions that have led man to overcome himself. The challenge that concerns us today is to maintain our lifestyle with the energy expenditure involved. In the present work, it's proposed the production of emulsifiers such as monoglycerides (MG) and diglycerides (DG) and biodiesel (FAEE) from renewable sources using Pseudomonas fluorescens lipase immobilized over Ca modified mesoporous SBA-15 supports (LPF/Ca/SBA-15) as biocatalyst. Using a packed bed reactor thermostated at 37 °C, the catalyst was capable to convert sunflower oil and commercial ethanol (96 wt%) into FAEE (35.0 wt%), MG (12.2 wt%) and DG (43.2 wt%). From these results, a separation by vacuum distillation was simulated. A good separation of the biodiesel in the top of the column at approx. 325 °C and the emulsifiers in the bottom of the column at 484 °C, was obtained. Thus, from interdisciplinary technologies such as enzymology, nanostructured materials design and computer simulation, a project for the production and purification of two products, emulsifiers and biodiesel, with one catalyst is offered.
Fil: Ferrero, Gabriel Orlando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Sánchez Faba, Edgar Maximiliano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
description Crises are the driving force of the inventions that have led man to overcome himself. The challenge that concerns us today is to maintain our lifestyle with the energy expenditure involved. In the present work, it's proposed the production of emulsifiers such as monoglycerides (MG) and diglycerides (DG) and biodiesel (FAEE) from renewable sources using Pseudomonas fluorescens lipase immobilized over Ca modified mesoporous SBA-15 supports (LPF/Ca/SBA-15) as biocatalyst. Using a packed bed reactor thermostated at 37 °C, the catalyst was capable to convert sunflower oil and commercial ethanol (96 wt%) into FAEE (35.0 wt%), MG (12.2 wt%) and DG (43.2 wt%). From these results, a separation by vacuum distillation was simulated. A good separation of the biodiesel in the top of the column at approx. 325 °C and the emulsifiers in the bottom of the column at 484 °C, was obtained. Thus, from interdisciplinary technologies such as enzymology, nanostructured materials design and computer simulation, a project for the production and purification of two products, emulsifiers and biodiesel, with one catalyst is offered.
publishDate 2018
dc.date.none.fl_str_mv 2018-09-15
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/88171
Ferrero, Gabriel Orlando; Sánchez Faba, Edgar Maximiliano; Eimer, Griselda Alejandra; Two products one catalyst: Emulsifiers and biodiesel production combining enzymology, nanostructured materials engineering and simulation models; Elsevier Science Sa; Chemical Engineering Journal; 348; 15-9-2018; 960-965
1385-8947
CONICET Digital
CONICET
url http://hdl.handle.net/11336/88171
identifier_str_mv Ferrero, Gabriel Orlando; Sánchez Faba, Edgar Maximiliano; Eimer, Griselda Alejandra; Two products one catalyst: Emulsifiers and biodiesel production combining enzymology, nanostructured materials engineering and simulation models; Elsevier Science Sa; Chemical Engineering Journal; 348; 15-9-2018; 960-965
1385-8947
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1385894718308374?via%3Dihub
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2018.05.048
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613447483916288
score 13.070432

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