Synthesis, Properties and Applications of Conducting Polymer Nano- Objects

Autores
Barbero, César Alfredo; Acevedo, Diego Fernando; Yslas, Edith Inés; Broglia, Martin Federico; Peralta, Damian Oscar; Frontera, Evelina; Rivero, Rebeca Edith; Rivarola, Claudia Rosana; Bertuzzi, Mabel Lucia; Rivarola, Viviana; Miras, Maria Cristina
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Two different approaches are used to produce conducting polymer nano-objects. One is a “top-down” approach which involves laser ablation of conducting polymer films using laser light interference patterns (direct laser interference patterning, DLIP) to produce various surface shapes, including nanowires and nanodots. Polyaniline(PANI) and polypyrrole (PPy) nanostructures could be easily produced by ablation of films, previously formed by in-situ polymerization of the aromatic monomers. The other is a “bottom-up” approach involving the controlled nucleation and growth during monomer polymerization. This is achieved by performing the polymerization at the interface of two immiscible solvents. Both kinds of nanomaterials are characterized using dynamic light scattering, TEM, EDAX, FTIR, UV-vis and fluorescence spectroscopy. The structures are studied by SEM-FIB, optical and fluorescence microscopy along with water contact angle. It is shown that nanometric sized structures can be made by both methods. The chemical structures are quite similar or identical to that of the bulk polymer. While PANI nanofibers are dispersed in acid media, due to the surface charge related with chain protonation, they agglomerate in neutral media. In the interest of biological applications, different soluble polymers are used to help disperse the nanofibers at neutral pH. Both the dispersing agent and PANI nanofibers have to be innocuous to biological cells and higher organisms, like frog larvae. The successful intake of PANI nanofibers into cancer line cells and frog larvae prompts its application as NIR radiation absorbers in photothermal or photoacoustic tumor therapy and/or tomography.
Fil: Barbero, César Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Acevedo, Diego Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Yslas, Edith Inés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Broglia, Martin Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Peralta, Damian Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Frontera, Evelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Rivero, Rebeca Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Rivarola, Claudia Rosana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Bertuzzi, Mabel Lucia. Universidad Nacional de Río Cuarto; Argentina
Fil: Rivarola, Viviana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Miras, Maria Cristina. Universidad Nacional de Río Cuarto; Argentina
Materia
NANOFIBERS
POLYANILINE
POLYPYRROLE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/253402
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Synthesis, Properties and Applications of Conducting Polymer Nano- ObjectsBarbero, César AlfredoAcevedo, Diego FernandoYslas, Edith InésBroglia, Martin FedericoPeralta, Damian OscarFrontera, EvelinaRivero, Rebeca EdithRivarola, Claudia RosanaBertuzzi, Mabel LuciaRivarola, VivianaMiras, Maria CristinaNANOFIBERSPOLYANILINEPOLYPYRROLEhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Two different approaches are used to produce conducting polymer nano-objects. One is a “top-down” approach which involves laser ablation of conducting polymer films using laser light interference patterns (direct laser interference patterning, DLIP) to produce various surface shapes, including nanowires and nanodots. Polyaniline(PANI) and polypyrrole (PPy) nanostructures could be easily produced by ablation of films, previously formed by in-situ polymerization of the aromatic monomers. The other is a “bottom-up” approach involving the controlled nucleation and growth during monomer polymerization. This is achieved by performing the polymerization at the interface of two immiscible solvents. Both kinds of nanomaterials are characterized using dynamic light scattering, TEM, EDAX, FTIR, UV-vis and fluorescence spectroscopy. The structures are studied by SEM-FIB, optical and fluorescence microscopy along with water contact angle. It is shown that nanometric sized structures can be made by both methods. The chemical structures are quite similar or identical to that of the bulk polymer. While PANI nanofibers are dispersed in acid media, due to the surface charge related with chain protonation, they agglomerate in neutral media. In the interest of biological applications, different soluble polymers are used to help disperse the nanofibers at neutral pH. Both the dispersing agent and PANI nanofibers have to be innocuous to biological cells and higher organisms, like frog larvae. The successful intake of PANI nanofibers into cancer line cells and frog larvae prompts its application as NIR radiation absorbers in photothermal or photoacoustic tumor therapy and/or tomography.Fil: Barbero, César Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; ArgentinaFil: Acevedo, Diego Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; ArgentinaFil: Yslas, Edith Inés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; ArgentinaFil: Broglia, Martin Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; ArgentinaFil: Peralta, Damian Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; ArgentinaFil: Frontera, Evelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; ArgentinaFil: Rivero, Rebeca Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; ArgentinaFil: Rivarola, Claudia Rosana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; ArgentinaFil: Bertuzzi, Mabel Lucia. Universidad Nacional de Río Cuarto; ArgentinaFil: Rivarola, Viviana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; ArgentinaFil: Miras, Maria Cristina. Universidad Nacional de Río Cuarto; ArgentinaTaylor & Francis Ltd2010-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/253402Barbero, César Alfredo; Acevedo, Diego Fernando; Yslas, Edith Inés; Broglia, Martin Federico; Peralta, Damian Oscar; et al.; Synthesis, Properties and Applications of Conducting Polymer Nano- Objects; Taylor & Francis Ltd; Molecular Crystals and Liquid Crystals - (Print); 521; 1; 5-2010; 214-2281542-1406CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/full/10.1080/15421401003720074info:eu-repo/semantics/altIdentifier/doi/10.1080/15421401003720074info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:43:26Zoai:ri.conicet.gov.ar:11336/253402instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:43:27.282CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis, Properties and Applications of Conducting Polymer Nano- Objects
title Synthesis, Properties and Applications of Conducting Polymer Nano- Objects
spellingShingle Synthesis, Properties and Applications of Conducting Polymer Nano- Objects
Barbero, César Alfredo
NANOFIBERS
POLYANILINE
POLYPYRROLE
title_short Synthesis, Properties and Applications of Conducting Polymer Nano- Objects
title_full Synthesis, Properties and Applications of Conducting Polymer Nano- Objects
title_fullStr Synthesis, Properties and Applications of Conducting Polymer Nano- Objects
title_full_unstemmed Synthesis, Properties and Applications of Conducting Polymer Nano- Objects
title_sort Synthesis, Properties and Applications of Conducting Polymer Nano- Objects
dc.creator.none.fl_str_mv Barbero, César Alfredo
Acevedo, Diego Fernando
Yslas, Edith Inés
Broglia, Martin Federico
Peralta, Damian Oscar
Frontera, Evelina
Rivero, Rebeca Edith
Rivarola, Claudia Rosana
Bertuzzi, Mabel Lucia
Rivarola, Viviana
Miras, Maria Cristina
author Barbero, César Alfredo
author_facet Barbero, César Alfredo
Acevedo, Diego Fernando
Yslas, Edith Inés
Broglia, Martin Federico
Peralta, Damian Oscar
Frontera, Evelina
Rivero, Rebeca Edith
Rivarola, Claudia Rosana
Bertuzzi, Mabel Lucia
Rivarola, Viviana
Miras, Maria Cristina
author_role author
author2 Acevedo, Diego Fernando
Yslas, Edith Inés
Broglia, Martin Federico
Peralta, Damian Oscar
Frontera, Evelina
Rivero, Rebeca Edith
Rivarola, Claudia Rosana
Bertuzzi, Mabel Lucia
Rivarola, Viviana
Miras, Maria Cristina
author2_role author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv NANOFIBERS
POLYANILINE
POLYPYRROLE
topic NANOFIBERS
POLYANILINE
POLYPYRROLE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Two different approaches are used to produce conducting polymer nano-objects. One is a “top-down” approach which involves laser ablation of conducting polymer films using laser light interference patterns (direct laser interference patterning, DLIP) to produce various surface shapes, including nanowires and nanodots. Polyaniline(PANI) and polypyrrole (PPy) nanostructures could be easily produced by ablation of films, previously formed by in-situ polymerization of the aromatic monomers. The other is a “bottom-up” approach involving the controlled nucleation and growth during monomer polymerization. This is achieved by performing the polymerization at the interface of two immiscible solvents. Both kinds of nanomaterials are characterized using dynamic light scattering, TEM, EDAX, FTIR, UV-vis and fluorescence spectroscopy. The structures are studied by SEM-FIB, optical and fluorescence microscopy along with water contact angle. It is shown that nanometric sized structures can be made by both methods. The chemical structures are quite similar or identical to that of the bulk polymer. While PANI nanofibers are dispersed in acid media, due to the surface charge related with chain protonation, they agglomerate in neutral media. In the interest of biological applications, different soluble polymers are used to help disperse the nanofibers at neutral pH. Both the dispersing agent and PANI nanofibers have to be innocuous to biological cells and higher organisms, like frog larvae. The successful intake of PANI nanofibers into cancer line cells and frog larvae prompts its application as NIR radiation absorbers in photothermal or photoacoustic tumor therapy and/or tomography.
Fil: Barbero, César Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Acevedo, Diego Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Yslas, Edith Inés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Broglia, Martin Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Peralta, Damian Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Frontera, Evelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Rivero, Rebeca Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Rivarola, Claudia Rosana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Bertuzzi, Mabel Lucia. Universidad Nacional de Río Cuarto; Argentina
Fil: Rivarola, Viviana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto; Argentina
Fil: Miras, Maria Cristina. Universidad Nacional de Río Cuarto; Argentina
description Two different approaches are used to produce conducting polymer nano-objects. One is a “top-down” approach which involves laser ablation of conducting polymer films using laser light interference patterns (direct laser interference patterning, DLIP) to produce various surface shapes, including nanowires and nanodots. Polyaniline(PANI) and polypyrrole (PPy) nanostructures could be easily produced by ablation of films, previously formed by in-situ polymerization of the aromatic monomers. The other is a “bottom-up” approach involving the controlled nucleation and growth during monomer polymerization. This is achieved by performing the polymerization at the interface of two immiscible solvents. Both kinds of nanomaterials are characterized using dynamic light scattering, TEM, EDAX, FTIR, UV-vis and fluorescence spectroscopy. The structures are studied by SEM-FIB, optical and fluorescence microscopy along with water contact angle. It is shown that nanometric sized structures can be made by both methods. The chemical structures are quite similar or identical to that of the bulk polymer. While PANI nanofibers are dispersed in acid media, due to the surface charge related with chain protonation, they agglomerate in neutral media. In the interest of biological applications, different soluble polymers are used to help disperse the nanofibers at neutral pH. Both the dispersing agent and PANI nanofibers have to be innocuous to biological cells and higher organisms, like frog larvae. The successful intake of PANI nanofibers into cancer line cells and frog larvae prompts its application as NIR radiation absorbers in photothermal or photoacoustic tumor therapy and/or tomography.
publishDate 2010
dc.date.none.fl_str_mv 2010-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/253402
Barbero, César Alfredo; Acevedo, Diego Fernando; Yslas, Edith Inés; Broglia, Martin Federico; Peralta, Damian Oscar; et al.; Synthesis, Properties and Applications of Conducting Polymer Nano- Objects; Taylor & Francis Ltd; Molecular Crystals and Liquid Crystals - (Print); 521; 1; 5-2010; 214-228
1542-1406
CONICET Digital
CONICET
url http://hdl.handle.net/11336/253402
identifier_str_mv Barbero, César Alfredo; Acevedo, Diego Fernando; Yslas, Edith Inés; Broglia, Martin Federico; Peralta, Damian Oscar; et al.; Synthesis, Properties and Applications of Conducting Polymer Nano- Objects; Taylor & Francis Ltd; Molecular Crystals and Liquid Crystals - (Print); 521; 1; 5-2010; 214-228
1542-1406
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/full/10.1080/15421401003720074
info:eu-repo/semantics/altIdentifier/doi/10.1080/15421401003720074
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
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dc.publisher.none.fl_str_mv Taylor & Francis Ltd
publisher.none.fl_str_mv Taylor & Francis Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
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instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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