UV absorption cross-sections of a series of vinyl ethers

Autores
Nieto Gligorovski, L. I; Gligorovsky, S.; Romano, Rosana Mariel; Della Vedova, Carlos Omar; Zetsch, C.
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
UV absorption cross-sections of six vinyl ethers (ethyl vinyl ether, 1,4-butanediol divinyl ether, isobutyl vinyl ether, cyclohexyl vinyl ether, 4-hydroxybutylvinyl ether and diethyleneglycol divinyl ether) have been determined in the gas phase between 190 and 230 nm at 303 ± 2 K and pressures up to the corresponding saturation vapor pressures. The main band maxima of the vinyl ethers are below 200 nm with values under 8 × 10-17 cm2 molecule-1. The absorption vanishes above 225 nm with values of σ smaller than 1 × 10-21 cm2 molecule-1. Weak, overlaying vibrational progressions with spacings of 1400 cm-1 are observed for the alkyl vinyl ethers and are less pronounced for vinyl ethers with an extra O atom. Shifts of the positions and intensities are discussed on the basis of the differences in the chemical structure of this series. © 2009 Elsevier B.V. All rights reserved.
Fil: Nieto Gligorovski, L. I. University of Bayreuth; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Gligorovsky, S.. Universités d’Aix-Marseille; Francia. Centre National de la Recherche Scientifique; Francia
Fil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Della Vedova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Zetsch, C.. Fraunhofer Institute For Toxicology And Experimental Medicine Item; Alemania. University of Bayreuth; Alemania
Materia
ABSORPTION CROSS-SECTION
OLEFINS
OSCILLATOR STRENGTH
VINYL ETHERS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/181326
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/181326
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling UV absorption cross-sections of a series of vinyl ethersNieto Gligorovski, L. IGligorovsky, S.Romano, Rosana MarielDella Vedova, Carlos OmarZetsch, C.ABSORPTION CROSS-SECTIONOLEFINSOSCILLATOR STRENGTHVINYL ETHERShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1UV absorption cross-sections of six vinyl ethers (ethyl vinyl ether, 1,4-butanediol divinyl ether, isobutyl vinyl ether, cyclohexyl vinyl ether, 4-hydroxybutylvinyl ether and diethyleneglycol divinyl ether) have been determined in the gas phase between 190 and 230 nm at 303 ± 2 K and pressures up to the corresponding saturation vapor pressures. The main band maxima of the vinyl ethers are below 200 nm with values under 8 × 10-17 cm2 molecule-1. The absorption vanishes above 225 nm with values of σ smaller than 1 × 10-21 cm2 molecule-1. Weak, overlaying vibrational progressions with spacings of 1400 cm-1 are observed for the alkyl vinyl ethers and are less pronounced for vinyl ethers with an extra O atom. Shifts of the positions and intensities are discussed on the basis of the differences in the chemical structure of this series. © 2009 Elsevier B.V. All rights reserved.Fil: Nieto Gligorovski, L. I. University of Bayreuth; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Gligorovsky, S.. Universités d’Aix-Marseille; Francia. Centre National de la Recherche Scientifique; FranciaFil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Della Vedova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Zetsch, C.. Fraunhofer Institute For Toxicology And Experimental Medicine Item; Alemania. University of Bayreuth; AlemaniaElsevier Science SA2009-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/181326Nieto Gligorovski, L. I; Gligorovsky, S.; Romano, Rosana Mariel; Della Vedova, Carlos Omar; Zetsch, C.; UV absorption cross-sections of a series of vinyl ethers; Elsevier Science SA; Journal of Photochemistry and Photobiology A: Chemistry; 204; 1; 12-2009; 46-511010-6030CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1010603009000781info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jphotochem.2009.02.003info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T12:01:11Zoai:ri.conicet.gov.ar:11336/181326instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 12:01:11.575CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv UV absorption cross-sections of a series of vinyl ethers
title UV absorption cross-sections of a series of vinyl ethers
spellingShingle UV absorption cross-sections of a series of vinyl ethers
Nieto Gligorovski, L. I
ABSORPTION CROSS-SECTION
OLEFINS
OSCILLATOR STRENGTH
VINYL ETHERS
title_short UV absorption cross-sections of a series of vinyl ethers
title_full UV absorption cross-sections of a series of vinyl ethers
title_fullStr UV absorption cross-sections of a series of vinyl ethers
title_full_unstemmed UV absorption cross-sections of a series of vinyl ethers
title_sort UV absorption cross-sections of a series of vinyl ethers
dc.creator.none.fl_str_mv Nieto Gligorovski, L. I
Gligorovsky, S.
Romano, Rosana Mariel
Della Vedova, Carlos Omar
Zetsch, C.
author Nieto Gligorovski, L. I
author_facet Nieto Gligorovski, L. I
Gligorovsky, S.
Romano, Rosana Mariel
Della Vedova, Carlos Omar
Zetsch, C.
author_role author
author2 Gligorovsky, S.
Romano, Rosana Mariel
Della Vedova, Carlos Omar
Zetsch, C.
author2_role author
author
author
author
dc.subject.none.fl_str_mv ABSORPTION CROSS-SECTION
OLEFINS
OSCILLATOR STRENGTH
VINYL ETHERS
topic ABSORPTION CROSS-SECTION
OLEFINS
OSCILLATOR STRENGTH
VINYL ETHERS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv UV absorption cross-sections of six vinyl ethers (ethyl vinyl ether, 1,4-butanediol divinyl ether, isobutyl vinyl ether, cyclohexyl vinyl ether, 4-hydroxybutylvinyl ether and diethyleneglycol divinyl ether) have been determined in the gas phase between 190 and 230 nm at 303 ± 2 K and pressures up to the corresponding saturation vapor pressures. The main band maxima of the vinyl ethers are below 200 nm with values under 8 × 10-17 cm2 molecule-1. The absorption vanishes above 225 nm with values of σ smaller than 1 × 10-21 cm2 molecule-1. Weak, overlaying vibrational progressions with spacings of 1400 cm-1 are observed for the alkyl vinyl ethers and are less pronounced for vinyl ethers with an extra O atom. Shifts of the positions and intensities are discussed on the basis of the differences in the chemical structure of this series. © 2009 Elsevier B.V. All rights reserved.
Fil: Nieto Gligorovski, L. I. University of Bayreuth; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Gligorovsky, S.. Universités d’Aix-Marseille; Francia. Centre National de la Recherche Scientifique; Francia
Fil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Della Vedova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Zetsch, C.. Fraunhofer Institute For Toxicology And Experimental Medicine Item; Alemania. University of Bayreuth; Alemania
description UV absorption cross-sections of six vinyl ethers (ethyl vinyl ether, 1,4-butanediol divinyl ether, isobutyl vinyl ether, cyclohexyl vinyl ether, 4-hydroxybutylvinyl ether and diethyleneglycol divinyl ether) have been determined in the gas phase between 190 and 230 nm at 303 ± 2 K and pressures up to the corresponding saturation vapor pressures. The main band maxima of the vinyl ethers are below 200 nm with values under 8 × 10-17 cm2 molecule-1. The absorption vanishes above 225 nm with values of σ smaller than 1 × 10-21 cm2 molecule-1. Weak, overlaying vibrational progressions with spacings of 1400 cm-1 are observed for the alkyl vinyl ethers and are less pronounced for vinyl ethers with an extra O atom. Shifts of the positions and intensities are discussed on the basis of the differences in the chemical structure of this series. © 2009 Elsevier B.V. All rights reserved.
publishDate 2009
dc.date.none.fl_str_mv 2009-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/181326
Nieto Gligorovski, L. I; Gligorovsky, S.; Romano, Rosana Mariel; Della Vedova, Carlos Omar; Zetsch, C.; UV absorption cross-sections of a series of vinyl ethers; Elsevier Science SA; Journal of Photochemistry and Photobiology A: Chemistry; 204; 1; 12-2009; 46-51
1010-6030
CONICET Digital
CONICET
url http://hdl.handle.net/11336/181326
identifier_str_mv Nieto Gligorovski, L. I; Gligorovsky, S.; Romano, Rosana Mariel; Della Vedova, Carlos Omar; Zetsch, C.; UV absorption cross-sections of a series of vinyl ethers; Elsevier Science SA; Journal of Photochemistry and Photobiology A: Chemistry; 204; 1; 12-2009; 46-51
1010-6030
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1010603009000781
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jphotochem.2009.02.003
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science SA
publisher.none.fl_str_mv Elsevier Science SA
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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