Visible light absorption of TiO2 materials impregnated with tungstophosphoric acid ethanol–aqueous solution at different pH values. Evidence about the formation of a surface comple...
- Autores
- Rengifo Herrera, Julian Andres; Blanco, Mirta Noemi; Pizzio, Luis Rene
- Año de publicación
- 2013
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- TiO2 particles prepared by the sol-gel method were impregnated at different pH values (1.0, 2.0, 5.0 and 10.0) with a water-ethanol solution (50% V/V) of tungstophosphoric acid (TPA) (0.012 M). Similar preparation was carried out to synthesize TiO2 impregnated with [WO4] 2- (TiW). These materials were characterized by different techniques such as UV-vis diffuse reflectance spectroscopy (UV-vis DRS), magic angle spinning nuclear magnetic resonance of 31P (31P MAS NMR), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Fourier transform Raman spectroscopy (FT-Raman). Results revealed that TPA-TiO2 materials exhibit visible light absorption only when impregnation was done at pH 1.0 (TiTPA1) and 2.0 (TiTPA2). TiW powder did not show visible light absorption. XRD patterns show the presence of peaks at 2θ = 25.4 (1 0 1), 37.9 (0 0 4), 47.8 (2 0 0) and 54.3 associated to the anatase phase. Solid NMR, FT-IR and FT-Raman characterization showed that TiTPA1 and TiTPA2 samples contain Keggin ([PW12O40] 3-) and lacunary anions ([PW11O39] 7-) respectively. On the other hand, FT-Raman results revealed a blue shifting and broadening of the band at 141 cm-1 corresponding to anatase TiO2 and moreover, a broadening of bands at 900-1100 cm -1 attributed to Keggin structures of TPA. Both spectral changes could be related to the formation of a surface complex between the Keggin anion of TPA and TiO2 surfaces. This interaction should be responsible for visible light absorption
Fil: Rengifo Herrera, Julian Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Blanco, Mirta Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina - Materia
-
Composites
Nanostructures
Semiconductors
Optical Properties
Raman Spectroscopy - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/29095
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Visible light absorption of TiO2 materials impregnated with tungstophosphoric acid ethanol–aqueous solution at different pH values. Evidence about the formation of a surface complex between Keggin anion and TiO2 surfacesRengifo Herrera, Julian AndresBlanco, Mirta NoemiPizzio, Luis ReneCompositesNanostructuresSemiconductorsOptical PropertiesRaman Spectroscopyhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1TiO2 particles prepared by the sol-gel method were impregnated at different pH values (1.0, 2.0, 5.0 and 10.0) with a water-ethanol solution (50% V/V) of tungstophosphoric acid (TPA) (0.012 M). Similar preparation was carried out to synthesize TiO2 impregnated with [WO4] 2- (TiW). These materials were characterized by different techniques such as UV-vis diffuse reflectance spectroscopy (UV-vis DRS), magic angle spinning nuclear magnetic resonance of 31P (31P MAS NMR), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Fourier transform Raman spectroscopy (FT-Raman). Results revealed that TPA-TiO2 materials exhibit visible light absorption only when impregnation was done at pH 1.0 (TiTPA1) and 2.0 (TiTPA2). TiW powder did not show visible light absorption. XRD patterns show the presence of peaks at 2θ = 25.4 (1 0 1), 37.9 (0 0 4), 47.8 (2 0 0) and 54.3 associated to the anatase phase. Solid NMR, FT-IR and FT-Raman characterization showed that TiTPA1 and TiTPA2 samples contain Keggin ([PW12O40] 3-) and lacunary anions ([PW11O39] 7-) respectively. On the other hand, FT-Raman results revealed a blue shifting and broadening of the band at 141 cm-1 corresponding to anatase TiO2 and moreover, a broadening of bands at 900-1100 cm -1 attributed to Keggin structures of TPA. Both spectral changes could be related to the formation of a surface complex between the Keggin anion of TPA and TiO2 surfaces. This interaction should be responsible for visible light absorptionFil: Rengifo Herrera, Julian Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Blanco, Mirta Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaElsevier2013-10-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/29095Rengifo Herrera, Julian Andres; Blanco, Mirta Noemi; Pizzio, Luis Rene; Visible light absorption of TiO2 materials impregnated with tungstophosphoric acid ethanol–aqueous solution at different pH values. Evidence about the formation of a surface complex between Keggin anion and TiO2 surfaces; Elsevier; Materials Research Bulletin; 49; 8-10-2013; 618-6240025-5408CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0025540813008192info:eu-repo/semantics/altIdentifier/doi/10.1016/j.materresbull.2013.09.043info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:46:28Zoai:ri.conicet.gov.ar:11336/29095instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:46:28.884CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Visible light absorption of TiO2 materials impregnated with tungstophosphoric acid ethanol–aqueous solution at different pH values. Evidence about the formation of a surface complex between Keggin anion and TiO2 surfaces |
title |
Visible light absorption of TiO2 materials impregnated with tungstophosphoric acid ethanol–aqueous solution at different pH values. Evidence about the formation of a surface complex between Keggin anion and TiO2 surfaces |
spellingShingle |
Visible light absorption of TiO2 materials impregnated with tungstophosphoric acid ethanol–aqueous solution at different pH values. Evidence about the formation of a surface complex between Keggin anion and TiO2 surfaces Rengifo Herrera, Julian Andres Composites Nanostructures Semiconductors Optical Properties Raman Spectroscopy |
title_short |
Visible light absorption of TiO2 materials impregnated with tungstophosphoric acid ethanol–aqueous solution at different pH values. Evidence about the formation of a surface complex between Keggin anion and TiO2 surfaces |
title_full |
Visible light absorption of TiO2 materials impregnated with tungstophosphoric acid ethanol–aqueous solution at different pH values. Evidence about the formation of a surface complex between Keggin anion and TiO2 surfaces |
title_fullStr |
Visible light absorption of TiO2 materials impregnated with tungstophosphoric acid ethanol–aqueous solution at different pH values. Evidence about the formation of a surface complex between Keggin anion and TiO2 surfaces |
title_full_unstemmed |
Visible light absorption of TiO2 materials impregnated with tungstophosphoric acid ethanol–aqueous solution at different pH values. Evidence about the formation of a surface complex between Keggin anion and TiO2 surfaces |
title_sort |
Visible light absorption of TiO2 materials impregnated with tungstophosphoric acid ethanol–aqueous solution at different pH values. Evidence about the formation of a surface complex between Keggin anion and TiO2 surfaces |
dc.creator.none.fl_str_mv |
Rengifo Herrera, Julian Andres Blanco, Mirta Noemi Pizzio, Luis Rene |
author |
Rengifo Herrera, Julian Andres |
author_facet |
Rengifo Herrera, Julian Andres Blanco, Mirta Noemi Pizzio, Luis Rene |
author_role |
author |
author2 |
Blanco, Mirta Noemi Pizzio, Luis Rene |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Composites Nanostructures Semiconductors Optical Properties Raman Spectroscopy |
topic |
Composites Nanostructures Semiconductors Optical Properties Raman Spectroscopy |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
TiO2 particles prepared by the sol-gel method were impregnated at different pH values (1.0, 2.0, 5.0 and 10.0) with a water-ethanol solution (50% V/V) of tungstophosphoric acid (TPA) (0.012 M). Similar preparation was carried out to synthesize TiO2 impregnated with [WO4] 2- (TiW). These materials were characterized by different techniques such as UV-vis diffuse reflectance spectroscopy (UV-vis DRS), magic angle spinning nuclear magnetic resonance of 31P (31P MAS NMR), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Fourier transform Raman spectroscopy (FT-Raman). Results revealed that TPA-TiO2 materials exhibit visible light absorption only when impregnation was done at pH 1.0 (TiTPA1) and 2.0 (TiTPA2). TiW powder did not show visible light absorption. XRD patterns show the presence of peaks at 2θ = 25.4 (1 0 1), 37.9 (0 0 4), 47.8 (2 0 0) and 54.3 associated to the anatase phase. Solid NMR, FT-IR and FT-Raman characterization showed that TiTPA1 and TiTPA2 samples contain Keggin ([PW12O40] 3-) and lacunary anions ([PW11O39] 7-) respectively. On the other hand, FT-Raman results revealed a blue shifting and broadening of the band at 141 cm-1 corresponding to anatase TiO2 and moreover, a broadening of bands at 900-1100 cm -1 attributed to Keggin structures of TPA. Both spectral changes could be related to the formation of a surface complex between the Keggin anion of TPA and TiO2 surfaces. This interaction should be responsible for visible light absorption Fil: Rengifo Herrera, Julian Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina Fil: Blanco, Mirta Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina Fil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina |
description |
TiO2 particles prepared by the sol-gel method were impregnated at different pH values (1.0, 2.0, 5.0 and 10.0) with a water-ethanol solution (50% V/V) of tungstophosphoric acid (TPA) (0.012 M). Similar preparation was carried out to synthesize TiO2 impregnated with [WO4] 2- (TiW). These materials were characterized by different techniques such as UV-vis diffuse reflectance spectroscopy (UV-vis DRS), magic angle spinning nuclear magnetic resonance of 31P (31P MAS NMR), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Fourier transform Raman spectroscopy (FT-Raman). Results revealed that TPA-TiO2 materials exhibit visible light absorption only when impregnation was done at pH 1.0 (TiTPA1) and 2.0 (TiTPA2). TiW powder did not show visible light absorption. XRD patterns show the presence of peaks at 2θ = 25.4 (1 0 1), 37.9 (0 0 4), 47.8 (2 0 0) and 54.3 associated to the anatase phase. Solid NMR, FT-IR and FT-Raman characterization showed that TiTPA1 and TiTPA2 samples contain Keggin ([PW12O40] 3-) and lacunary anions ([PW11O39] 7-) respectively. On the other hand, FT-Raman results revealed a blue shifting and broadening of the band at 141 cm-1 corresponding to anatase TiO2 and moreover, a broadening of bands at 900-1100 cm -1 attributed to Keggin structures of TPA. Both spectral changes could be related to the formation of a surface complex between the Keggin anion of TPA and TiO2 surfaces. This interaction should be responsible for visible light absorption |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-10-08 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/29095 Rengifo Herrera, Julian Andres; Blanco, Mirta Noemi; Pizzio, Luis Rene; Visible light absorption of TiO2 materials impregnated with tungstophosphoric acid ethanol–aqueous solution at different pH values. Evidence about the formation of a surface complex between Keggin anion and TiO2 surfaces; Elsevier; Materials Research Bulletin; 49; 8-10-2013; 618-624 0025-5408 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/29095 |
identifier_str_mv |
Rengifo Herrera, Julian Andres; Blanco, Mirta Noemi; Pizzio, Luis Rene; Visible light absorption of TiO2 materials impregnated with tungstophosphoric acid ethanol–aqueous solution at different pH values. Evidence about the formation of a surface complex between Keggin anion and TiO2 surfaces; Elsevier; Materials Research Bulletin; 49; 8-10-2013; 618-624 0025-5408 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0025540813008192 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.materresbull.2013.09.043 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613451094163456 |
score |
13.070432 |