Important double bond effect on the aggregation behavior of an alkenyl succinic acid derivative
- Autores
- Silva, Oscar Fernando; Hoyos, Maria Rita Micaela; Fernández, Mariana Adela
- Año de publicación
- 2016
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The aggregation behavior of 2-(2-decenyl) succinic acid (C10SA) in alkaline aqueous media was extensively studied and found interesting properties. The CMC (critical micelle concentration) is lower than expected for a compound with two carboxylate groups and an alkenyl chain of 10–12 carbon atoms. We identified that among the factors that affect the CMC, the double bond and the arrangement of the carbonyl group play a crucial role. They favor an ease packing of the head group of the surfactant resulting in a reduction of their mutual repulsion in the micelle. This particular conformation influences the solubilization/aggregation behavior and is responsible of the high tendency to self-assembly forming micelles of spherical shape and small size. An important feature of C10SA molecules is their ability to orient the carboxyl groups in a way that allow them been packed in the aggregates and this property may be of interest for many future applications.
Fil: Silva, Oscar Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Hoyos, Maria Rita Micaela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Fernández, Mariana Adela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina - Materia
-
Aggregation
Alkenyl Succinic Acid
Langmuir Monolayers
Micelles - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/54166
Ver los metadatos del registro completo
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Important double bond effect on the aggregation behavior of an alkenyl succinic acid derivativeSilva, Oscar FernandoHoyos, Maria Rita MicaelaFernández, Mariana AdelaAggregationAlkenyl Succinic AcidLangmuir MonolayersMicelleshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The aggregation behavior of 2-(2-decenyl) succinic acid (C10SA) in alkaline aqueous media was extensively studied and found interesting properties. The CMC (critical micelle concentration) is lower than expected for a compound with two carboxylate groups and an alkenyl chain of 10–12 carbon atoms. We identified that among the factors that affect the CMC, the double bond and the arrangement of the carbonyl group play a crucial role. They favor an ease packing of the head group of the surfactant resulting in a reduction of their mutual repulsion in the micelle. This particular conformation influences the solubilization/aggregation behavior and is responsible of the high tendency to self-assembly forming micelles of spherical shape and small size. An important feature of C10SA molecules is their ability to orient the carboxyl groups in a way that allow them been packed in the aggregates and this property may be of interest for many future applications.Fil: Silva, Oscar Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Hoyos, Maria Rita Micaela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Fernández, Mariana Adela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaElsevier Science2016-10-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/54166Silva, Oscar Fernando; Hoyos, Maria Rita Micaela; Fernández, Mariana Adela; Important double bond effect on the aggregation behavior of an alkenyl succinic acid derivative; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 507; 1-10-2016; 134-1400927-7757CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0927775716306203info:eu-repo/semantics/altIdentifier/doi/10.1016/j.colsurfa.2016.07.098info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:49:08Zoai:ri.conicet.gov.ar:11336/54166instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:49:08.879CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Important double bond effect on the aggregation behavior of an alkenyl succinic acid derivative |
title |
Important double bond effect on the aggregation behavior of an alkenyl succinic acid derivative |
spellingShingle |
Important double bond effect on the aggregation behavior of an alkenyl succinic acid derivative Silva, Oscar Fernando Aggregation Alkenyl Succinic Acid Langmuir Monolayers Micelles |
title_short |
Important double bond effect on the aggregation behavior of an alkenyl succinic acid derivative |
title_full |
Important double bond effect on the aggregation behavior of an alkenyl succinic acid derivative |
title_fullStr |
Important double bond effect on the aggregation behavior of an alkenyl succinic acid derivative |
title_full_unstemmed |
Important double bond effect on the aggregation behavior of an alkenyl succinic acid derivative |
title_sort |
Important double bond effect on the aggregation behavior of an alkenyl succinic acid derivative |
dc.creator.none.fl_str_mv |
Silva, Oscar Fernando Hoyos, Maria Rita Micaela Fernández, Mariana Adela |
author |
Silva, Oscar Fernando |
author_facet |
Silva, Oscar Fernando Hoyos, Maria Rita Micaela Fernández, Mariana Adela |
author_role |
author |
author2 |
Hoyos, Maria Rita Micaela Fernández, Mariana Adela |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Aggregation Alkenyl Succinic Acid Langmuir Monolayers Micelles |
topic |
Aggregation Alkenyl Succinic Acid Langmuir Monolayers Micelles |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The aggregation behavior of 2-(2-decenyl) succinic acid (C10SA) in alkaline aqueous media was extensively studied and found interesting properties. The CMC (critical micelle concentration) is lower than expected for a compound with two carboxylate groups and an alkenyl chain of 10–12 carbon atoms. We identified that among the factors that affect the CMC, the double bond and the arrangement of the carbonyl group play a crucial role. They favor an ease packing of the head group of the surfactant resulting in a reduction of their mutual repulsion in the micelle. This particular conformation influences the solubilization/aggregation behavior and is responsible of the high tendency to self-assembly forming micelles of spherical shape and small size. An important feature of C10SA molecules is their ability to orient the carboxyl groups in a way that allow them been packed in the aggregates and this property may be of interest for many future applications. Fil: Silva, Oscar Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina Fil: Hoyos, Maria Rita Micaela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina Fil: Fernández, Mariana Adela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina |
description |
The aggregation behavior of 2-(2-decenyl) succinic acid (C10SA) in alkaline aqueous media was extensively studied and found interesting properties. The CMC (critical micelle concentration) is lower than expected for a compound with two carboxylate groups and an alkenyl chain of 10–12 carbon atoms. We identified that among the factors that affect the CMC, the double bond and the arrangement of the carbonyl group play a crucial role. They favor an ease packing of the head group of the surfactant resulting in a reduction of their mutual repulsion in the micelle. This particular conformation influences the solubilization/aggregation behavior and is responsible of the high tendency to self-assembly forming micelles of spherical shape and small size. An important feature of C10SA molecules is their ability to orient the carboxyl groups in a way that allow them been packed in the aggregates and this property may be of interest for many future applications. |
publishDate |
2016 |
dc.date.none.fl_str_mv |
2016-10-01 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/54166 Silva, Oscar Fernando; Hoyos, Maria Rita Micaela; Fernández, Mariana Adela; Important double bond effect on the aggregation behavior of an alkenyl succinic acid derivative; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 507; 1-10-2016; 134-140 0927-7757 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/54166 |
identifier_str_mv |
Silva, Oscar Fernando; Hoyos, Maria Rita Micaela; Fernández, Mariana Adela; Important double bond effect on the aggregation behavior of an alkenyl succinic acid derivative; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 507; 1-10-2016; 134-140 0927-7757 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0927775716306203 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.colsurfa.2016.07.098 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613523176423424 |
score |
13.070432 |