Study of binary lead‑tin alloys using a new procedure based on calibration-free laser induced breakdown spectroscopy

Autores
Urbina Medina, Ivan Alexander; Carneiro, Deborah D.; Rocha, Suellen; Farías, Eliel Eleutério; Bredice, Fausto Osvaldo; Palleschi, Vincenzo
Año de publicación
2020
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The objective of this work is to present a novel procedure based on the time resolved Boltzmann plot, and theCalibration-free Laser Induced Breakdown Spectroscopy techniques, to determine the composition of the samplesby exploiting the temporal evolution of the spectral lines generated in the laser-produced plasma. As an exampleof the application of this procedure, Laser Induced Breakdown Spectroscopy spectra were acquired on binarylead – tin alloys of different composition at several delay times, from 1 to 4 μs with a step of 0.5 μs after the onsetof the plasma.The matrix change of the alloys was studied through the determination of the constants that characterize thetemporal evolution of plasma. The effects of self-absorption were also taken into account and compensated. Theapplication of the proposed method allowed us to determine the concentrations of lead (Pb) and tin (Sn) in thealloys with an error lower than 5%.
Fil: Urbina Medina, Ivan Alexander. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones Ópticas. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones Ópticas. Universidad Nacional de La Plata. Centro de Investigaciones Ópticas; Argentina
Fil: Carneiro, Deborah D.. Universidad Federal de Roraima; Brasil. Centro Universitário Estácio da Amazônia; Brasil
Fil: Rocha, Suellen. Universidad Federal de Roraima; Brasil
Fil: Farías, Eliel Eleutério. Universidad Federal de Roraima; Brasil
Fil: Bredice, Fausto Osvaldo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones Ópticas. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones Ópticas. Universidad Nacional de La Plata. Centro de Investigaciones Ópticas; Argentina
Fil: Palleschi, Vincenzo. Consiglio Nazionale delle Ricerche; Italia
Materia
LIBS
Calibration free LIBS
3D Boltzmann plot
Temporal evolution
Pb-Sn alloys
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/236473
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Study of binary lead‑tin alloys using a new procedure based on calibration-free laser induced breakdown spectroscopyUrbina Medina, Ivan AlexanderCarneiro, Deborah D.Rocha, SuellenFarías, Eliel EleutérioBredice, Fausto OsvaldoPalleschi, VincenzoLIBSCalibration free LIBS3D Boltzmann plotTemporal evolutionPb-Sn alloyshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The objective of this work is to present a novel procedure based on the time resolved Boltzmann plot, and theCalibration-free Laser Induced Breakdown Spectroscopy techniques, to determine the composition of the samplesby exploiting the temporal evolution of the spectral lines generated in the laser-produced plasma. As an exampleof the application of this procedure, Laser Induced Breakdown Spectroscopy spectra were acquired on binarylead – tin alloys of different composition at several delay times, from 1 to 4 μs with a step of 0.5 μs after the onsetof the plasma.The matrix change of the alloys was studied through the determination of the constants that characterize thetemporal evolution of plasma. The effects of self-absorption were also taken into account and compensated. Theapplication of the proposed method allowed us to determine the concentrations of lead (Pb) and tin (Sn) in thealloys with an error lower than 5%.Fil: Urbina Medina, Ivan Alexander. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones Ópticas. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones Ópticas. Universidad Nacional de La Plata. Centro de Investigaciones Ópticas; ArgentinaFil: Carneiro, Deborah D.. Universidad Federal de Roraima; Brasil. Centro Universitário Estácio da Amazônia; BrasilFil: Rocha, Suellen. Universidad Federal de Roraima; BrasilFil: Farías, Eliel Eleutério. Universidad Federal de Roraima; BrasilFil: Bredice, Fausto Osvaldo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones Ópticas. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones Ópticas. Universidad Nacional de La Plata. Centro de Investigaciones Ópticas; ArgentinaFil: Palleschi, Vincenzo. Consiglio Nazionale delle Ricerche; ItaliaPergamon-Elsevier Science Ltd2020-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/236473Urbina Medina, Ivan Alexander; Carneiro, Deborah D.; Rocha, Suellen; Farías, Eliel Eleutério; Bredice, Fausto Osvaldo; et al.; Study of binary lead‑tin alloys using a new procedure based on calibration-free laser induced breakdown spectroscopy; Pergamon-Elsevier Science Ltd; Spectrochimica Acta Part B: Atomic Spectroscopy; 170; 105902; 8-2020; 1-220584-8547CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.sab.2020.105902info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0584854719305646info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:41:13Zoai:ri.conicet.gov.ar:11336/236473instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:41:13.531CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Study of binary lead‑tin alloys using a new procedure based on calibration-free laser induced breakdown spectroscopy
title Study of binary lead‑tin alloys using a new procedure based on calibration-free laser induced breakdown spectroscopy
spellingShingle Study of binary lead‑tin alloys using a new procedure based on calibration-free laser induced breakdown spectroscopy
Urbina Medina, Ivan Alexander
LIBS
Calibration free LIBS
3D Boltzmann plot
Temporal evolution
Pb-Sn alloys
title_short Study of binary lead‑tin alloys using a new procedure based on calibration-free laser induced breakdown spectroscopy
title_full Study of binary lead‑tin alloys using a new procedure based on calibration-free laser induced breakdown spectroscopy
title_fullStr Study of binary lead‑tin alloys using a new procedure based on calibration-free laser induced breakdown spectroscopy
title_full_unstemmed Study of binary lead‑tin alloys using a new procedure based on calibration-free laser induced breakdown spectroscopy
title_sort Study of binary lead‑tin alloys using a new procedure based on calibration-free laser induced breakdown spectroscopy
dc.creator.none.fl_str_mv Urbina Medina, Ivan Alexander
Carneiro, Deborah D.
Rocha, Suellen
Farías, Eliel Eleutério
Bredice, Fausto Osvaldo
Palleschi, Vincenzo
author Urbina Medina, Ivan Alexander
author_facet Urbina Medina, Ivan Alexander
Carneiro, Deborah D.
Rocha, Suellen
Farías, Eliel Eleutério
Bredice, Fausto Osvaldo
Palleschi, Vincenzo
author_role author
author2 Carneiro, Deborah D.
Rocha, Suellen
Farías, Eliel Eleutério
Bredice, Fausto Osvaldo
Palleschi, Vincenzo
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv LIBS
Calibration free LIBS
3D Boltzmann plot
Temporal evolution
Pb-Sn alloys
topic LIBS
Calibration free LIBS
3D Boltzmann plot
Temporal evolution
Pb-Sn alloys
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The objective of this work is to present a novel procedure based on the time resolved Boltzmann plot, and theCalibration-free Laser Induced Breakdown Spectroscopy techniques, to determine the composition of the samplesby exploiting the temporal evolution of the spectral lines generated in the laser-produced plasma. As an exampleof the application of this procedure, Laser Induced Breakdown Spectroscopy spectra were acquired on binarylead – tin alloys of different composition at several delay times, from 1 to 4 μs with a step of 0.5 μs after the onsetof the plasma.The matrix change of the alloys was studied through the determination of the constants that characterize thetemporal evolution of plasma. The effects of self-absorption were also taken into account and compensated. Theapplication of the proposed method allowed us to determine the concentrations of lead (Pb) and tin (Sn) in thealloys with an error lower than 5%.
Fil: Urbina Medina, Ivan Alexander. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones Ópticas. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones Ópticas. Universidad Nacional de La Plata. Centro de Investigaciones Ópticas; Argentina
Fil: Carneiro, Deborah D.. Universidad Federal de Roraima; Brasil. Centro Universitário Estácio da Amazônia; Brasil
Fil: Rocha, Suellen. Universidad Federal de Roraima; Brasil
Fil: Farías, Eliel Eleutério. Universidad Federal de Roraima; Brasil
Fil: Bredice, Fausto Osvaldo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones Ópticas. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones Ópticas. Universidad Nacional de La Plata. Centro de Investigaciones Ópticas; Argentina
Fil: Palleschi, Vincenzo. Consiglio Nazionale delle Ricerche; Italia
description The objective of this work is to present a novel procedure based on the time resolved Boltzmann plot, and theCalibration-free Laser Induced Breakdown Spectroscopy techniques, to determine the composition of the samplesby exploiting the temporal evolution of the spectral lines generated in the laser-produced plasma. As an exampleof the application of this procedure, Laser Induced Breakdown Spectroscopy spectra were acquired on binarylead – tin alloys of different composition at several delay times, from 1 to 4 μs with a step of 0.5 μs after the onsetof the plasma.The matrix change of the alloys was studied through the determination of the constants that characterize thetemporal evolution of plasma. The effects of self-absorption were also taken into account and compensated. Theapplication of the proposed method allowed us to determine the concentrations of lead (Pb) and tin (Sn) in thealloys with an error lower than 5%.
publishDate 2020
dc.date.none.fl_str_mv 2020-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/236473
Urbina Medina, Ivan Alexander; Carneiro, Deborah D.; Rocha, Suellen; Farías, Eliel Eleutério; Bredice, Fausto Osvaldo; et al.; Study of binary lead‑tin alloys using a new procedure based on calibration-free laser induced breakdown spectroscopy; Pergamon-Elsevier Science Ltd; Spectrochimica Acta Part B: Atomic Spectroscopy; 170; 105902; 8-2020; 1-22
0584-8547
CONICET Digital
CONICET
url http://hdl.handle.net/11336/236473
identifier_str_mv Urbina Medina, Ivan Alexander; Carneiro, Deborah D.; Rocha, Suellen; Farías, Eliel Eleutério; Bredice, Fausto Osvaldo; et al.; Study of binary lead‑tin alloys using a new procedure based on calibration-free laser induced breakdown spectroscopy; Pergamon-Elsevier Science Ltd; Spectrochimica Acta Part B: Atomic Spectroscopy; 170; 105902; 8-2020; 1-22
0584-8547
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.sab.2020.105902
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0584854719305646
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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