Molecular Hybrid Photocatalysts for CO2 Photoreduction by Hybridization of Molecular Catalysts and Photoactive Covalent Organic Frameworks – A Review

Autores
Li, Wen-Jing; Ma, Fan; Aramburu Troselj, Bruno Martín; Wang, Jia Wei; Ouyang, Gangfeng
Año de publicación
2025
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Photocatalytic reduction of CO2 to obtain storable fuels isan effective way to fix and utilize greenhouse gas CO2, ultimately achieving a carbon free energy cycle. The core of this goal lies the development of efficient, sustainable, and economically practical catalysts and light absorbers. Currently, hybrid photocatalytic systems that immobilize molecular catalysts on covalent organicframeworks (COFs) are of intensified interest, as this strategy enables the simultaneous exploitation of the catalytic properties of high-performance molecular catalysts, together with the durability of heterogeneous semiconductors, based on the readily available synthetic tunability of both components. This review focuses on the significant progress and challenges that have been overcome for the photocatalytic CO2 reduction reaction, mediated by COFs hybridized with molecular catalysts, aiming to provide strong guidance for innovative utilization towards sustainable photocatalytic CO2 reduction in the future.
Fil: Li, Wen-Jing. Sun Yat-sen University; China
Fil: Ma, Fan. Sun Yat-sen University; China
Fil: Aramburu Troselj, Bruno Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Wang, Jia Wei. Sun Yat-sen University; China
Fil: Ouyang, Gangfeng. Sun Yat-sen University; China
Materia
CO2 photoreduction
Molecular catalysts
Photocatalysis
Covalent organic framework
Molecular hybrid materials
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/279991
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Molecular Hybrid Photocatalysts for CO2 Photoreduction by Hybridization of Molecular Catalysts and Photoactive Covalent Organic Frameworks – A ReviewLi, Wen-JingMa, FanAramburu Troselj, Bruno MartínWang, Jia WeiOuyang, GangfengCO2 photoreductionMolecular catalystsPhotocatalysisCovalent organic frameworkMolecular hybrid materialshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Photocatalytic reduction of CO2 to obtain storable fuels isan effective way to fix and utilize greenhouse gas CO2, ultimately achieving a carbon free energy cycle. The core of this goal lies the development of efficient, sustainable, and economically practical catalysts and light absorbers. Currently, hybrid photocatalytic systems that immobilize molecular catalysts on covalent organicframeworks (COFs) are of intensified interest, as this strategy enables the simultaneous exploitation of the catalytic properties of high-performance molecular catalysts, together with the durability of heterogeneous semiconductors, based on the readily available synthetic tunability of both components. This review focuses on the significant progress and challenges that have been overcome for the photocatalytic CO2 reduction reaction, mediated by COFs hybridized with molecular catalysts, aiming to provide strong guidance for innovative utilization towards sustainable photocatalytic CO2 reduction in the future.Fil: Li, Wen-Jing. Sun Yat-sen University; ChinaFil: Ma, Fan. Sun Yat-sen University; ChinaFil: Aramburu Troselj, Bruno Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Wang, Jia Wei. Sun Yat-sen University; ChinaFil: Ouyang, Gangfeng. Sun Yat-sen University; ChinaWiley VCH Verlag2025-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/279991Li, Wen-Jing; Ma, Fan; Aramburu Troselj, Bruno Martín; Wang, Jia Wei; Ouyang, Gangfeng; Molecular Hybrid Photocatalysts for CO2 Photoreduction by Hybridization of Molecular Catalysts and Photoactive Covalent Organic Frameworks – A Review; Wiley VCH Verlag; Chemistry- A European Journal; 31; 31; 4-2025; 1-140947-6539CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202404388info:eu-repo/semantics/altIdentifier/doi/10.1002/chem.202404388info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2026-03-31T15:25:06Zoai:ri.conicet.gov.ar:11336/279991instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982026-03-31 15:25:06.47CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Molecular Hybrid Photocatalysts for CO2 Photoreduction by Hybridization of Molecular Catalysts and Photoactive Covalent Organic Frameworks – A Review
title Molecular Hybrid Photocatalysts for CO2 Photoreduction by Hybridization of Molecular Catalysts and Photoactive Covalent Organic Frameworks – A Review
spellingShingle Molecular Hybrid Photocatalysts for CO2 Photoreduction by Hybridization of Molecular Catalysts and Photoactive Covalent Organic Frameworks – A Review
Li, Wen-Jing
CO2 photoreduction
Molecular catalysts
Photocatalysis
Covalent organic framework
Molecular hybrid materials
title_short Molecular Hybrid Photocatalysts for CO2 Photoreduction by Hybridization of Molecular Catalysts and Photoactive Covalent Organic Frameworks – A Review
title_full Molecular Hybrid Photocatalysts for CO2 Photoreduction by Hybridization of Molecular Catalysts and Photoactive Covalent Organic Frameworks – A Review
title_fullStr Molecular Hybrid Photocatalysts for CO2 Photoreduction by Hybridization of Molecular Catalysts and Photoactive Covalent Organic Frameworks – A Review
title_full_unstemmed Molecular Hybrid Photocatalysts for CO2 Photoreduction by Hybridization of Molecular Catalysts and Photoactive Covalent Organic Frameworks – A Review
title_sort Molecular Hybrid Photocatalysts for CO2 Photoreduction by Hybridization of Molecular Catalysts and Photoactive Covalent Organic Frameworks – A Review
dc.creator.none.fl_str_mv Li, Wen-Jing
Ma, Fan
Aramburu Troselj, Bruno Martín
Wang, Jia Wei
Ouyang, Gangfeng
author Li, Wen-Jing
author_facet Li, Wen-Jing
Ma, Fan
Aramburu Troselj, Bruno Martín
Wang, Jia Wei
Ouyang, Gangfeng
author_role author
author2 Ma, Fan
Aramburu Troselj, Bruno Martín
Wang, Jia Wei
Ouyang, Gangfeng
author2_role author
author
author
author
dc.subject.none.fl_str_mv CO2 photoreduction
Molecular catalysts
Photocatalysis
Covalent organic framework
Molecular hybrid materials
topic CO2 photoreduction
Molecular catalysts
Photocatalysis
Covalent organic framework
Molecular hybrid materials
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Photocatalytic reduction of CO2 to obtain storable fuels isan effective way to fix and utilize greenhouse gas CO2, ultimately achieving a carbon free energy cycle. The core of this goal lies the development of efficient, sustainable, and economically practical catalysts and light absorbers. Currently, hybrid photocatalytic systems that immobilize molecular catalysts on covalent organicframeworks (COFs) are of intensified interest, as this strategy enables the simultaneous exploitation of the catalytic properties of high-performance molecular catalysts, together with the durability of heterogeneous semiconductors, based on the readily available synthetic tunability of both components. This review focuses on the significant progress and challenges that have been overcome for the photocatalytic CO2 reduction reaction, mediated by COFs hybridized with molecular catalysts, aiming to provide strong guidance for innovative utilization towards sustainable photocatalytic CO2 reduction in the future.
Fil: Li, Wen-Jing. Sun Yat-sen University; China
Fil: Ma, Fan. Sun Yat-sen University; China
Fil: Aramburu Troselj, Bruno Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Wang, Jia Wei. Sun Yat-sen University; China
Fil: Ouyang, Gangfeng. Sun Yat-sen University; China
description Photocatalytic reduction of CO2 to obtain storable fuels isan effective way to fix and utilize greenhouse gas CO2, ultimately achieving a carbon free energy cycle. The core of this goal lies the development of efficient, sustainable, and economically practical catalysts and light absorbers. Currently, hybrid photocatalytic systems that immobilize molecular catalysts on covalent organicframeworks (COFs) are of intensified interest, as this strategy enables the simultaneous exploitation of the catalytic properties of high-performance molecular catalysts, together with the durability of heterogeneous semiconductors, based on the readily available synthetic tunability of both components. This review focuses on the significant progress and challenges that have been overcome for the photocatalytic CO2 reduction reaction, mediated by COFs hybridized with molecular catalysts, aiming to provide strong guidance for innovative utilization towards sustainable photocatalytic CO2 reduction in the future.
publishDate 2025
dc.date.none.fl_str_mv 2025-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/279991
Li, Wen-Jing; Ma, Fan; Aramburu Troselj, Bruno Martín; Wang, Jia Wei; Ouyang, Gangfeng; Molecular Hybrid Photocatalysts for CO2 Photoreduction by Hybridization of Molecular Catalysts and Photoactive Covalent Organic Frameworks – A Review; Wiley VCH Verlag; Chemistry- A European Journal; 31; 31; 4-2025; 1-14
0947-6539
CONICET Digital
CONICET
url http://hdl.handle.net/11336/279991
identifier_str_mv Li, Wen-Jing; Ma, Fan; Aramburu Troselj, Bruno Martín; Wang, Jia Wei; Ouyang, Gangfeng; Molecular Hybrid Photocatalysts for CO2 Photoreduction by Hybridization of Molecular Catalysts and Photoactive Covalent Organic Frameworks – A Review; Wiley VCH Verlag; Chemistry- A European Journal; 31; 31; 4-2025; 1-14
0947-6539
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202404388
info:eu-repo/semantics/altIdentifier/doi/10.1002/chem.202404388
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.822162

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