Pt and Pd on activated carbon for oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid

Autores
Sanabria, Lyda; Lederhos, Cecilia Rosa; Quiroga, Monica Esther; Cubillos Lobo, Jairo Antonio; Rojas, Agustin Hugo; Martinez, Jose
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The liquid phase transformation of 5-hydroxymethylfurfuraldehyde (5-HMF) towards 2,5-furandicarboxylicacid (2,5-FDCA) using Pt and Pd catalysts supported on activated carbon and with the presence of CaCO3 andNaOH, is reported. The catalysts were characterized using different techniques, such as: H2 chemisorptionat room temperature, X ray photoelectronic spectroscopy (XPS) and thermogravimetric analysis (TGA).The results indicate that the particle size followed the order: PtCl/C < PdCl/C < PdN/C, which is closelyrelated to the catalytic behavior. It was found that the metal particles are present in the Pd0 and Pt0 form.PtCl/C was most active catalyst using CaCO3 as weak base.
Fil: Sanabria, Lyda. Universidad Pedagógica y Tecnológica de Colombia Uptc; Colombia
Fil: Lederhos, Cecilia Rosa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Quiroga, Monica Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Cubillos Lobo, Jairo Antonio. Universidad Pedagógica y Tecnológica de Colombia Uptc; Colombia
Fil: Rojas, Agustin Hugo. Universidad Pedagógica y Tecnológica de Colombia Uptc; Colombia
Fil: Martinez, Jose. Universidad Pedagógica y Tecnológica de Colombia Uptc; Colombia
Materia
Ácido 2,5-furandicarboxilico
carbón activado
oxidación aeróbica
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/44141
Acceder
id CONICETDig_4c6278d9d187ec3a31bad41815b25cf3
oai_identifier_str oai:ri.conicet.gov.ar:11336/44141
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Pt and Pd on activated carbon for oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acidSanabria, LydaLederhos, Cecilia RosaQuiroga, Monica EstherCubillos Lobo, Jairo AntonioRojas, Agustin HugoMartinez, JoseÁcido 2,5-furandicarboxilicocarbón activadooxidación aeróbicahttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The liquid phase transformation of 5-hydroxymethylfurfuraldehyde (5-HMF) towards 2,5-furandicarboxylicacid (2,5-FDCA) using Pt and Pd catalysts supported on activated carbon and with the presence of CaCO3 andNaOH, is reported. The catalysts were characterized using different techniques, such as: H2 chemisorptionat room temperature, X ray photoelectronic spectroscopy (XPS) and thermogravimetric analysis (TGA).The results indicate that the particle size followed the order: PtCl/C < PdCl/C < PdN/C, which is closelyrelated to the catalytic behavior. It was found that the metal particles are present in the Pd0 and Pt0 form.PtCl/C was most active catalyst using CaCO3 as weak base.Fil: Sanabria, Lyda. Universidad Pedagógica y Tecnológica de Colombia Uptc; ColombiaFil: Lederhos, Cecilia Rosa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Quiroga, Monica Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Cubillos Lobo, Jairo Antonio. Universidad Pedagógica y Tecnológica de Colombia Uptc; ColombiaFil: Rojas, Agustin Hugo. Universidad Pedagógica y Tecnológica de Colombia Uptc; ColombiaFil: Martinez, Jose. Universidad Pedagógica y Tecnológica de Colombia Uptc; ColombiaUniversidad del Valle. Facultad de Ingeniería2017-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/44141Sanabria, Lyda; Lederhos, Cecilia Rosa; Quiroga, Monica Esther; Cubillos Lobo, Jairo Antonio; Rojas, Agustin Hugo; et al.; Pt and Pd on activated carbon for oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid; Universidad del Valle. Facultad de Ingeniería; Ingeniería y Competitividad; 19; 2; 9-2017; 36-420123-3033CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://revistaingenieria.univalle.edu.co/index.php/ingenieria_y_competitividad/article/view/5291info:eu-repo/semantics/altIdentifier/doi/10.25100/iyc.v19i2.5291info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T12:02:11Zoai:ri.conicet.gov.ar:11336/44141instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 12:02:11.615CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Pt and Pd on activated carbon for oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid
title Pt and Pd on activated carbon for oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid
spellingShingle Pt and Pd on activated carbon for oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid
Sanabria, Lyda
Ácido 2,5-furandicarboxilico
carbón activado
oxidación aeróbica
title_short Pt and Pd on activated carbon for oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid
title_full Pt and Pd on activated carbon for oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid
title_fullStr Pt and Pd on activated carbon for oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid
title_full_unstemmed Pt and Pd on activated carbon for oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid
title_sort Pt and Pd on activated carbon for oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid
dc.creator.none.fl_str_mv Sanabria, Lyda
Lederhos, Cecilia Rosa
Quiroga, Monica Esther
Cubillos Lobo, Jairo Antonio
Rojas, Agustin Hugo
Martinez, Jose
author Sanabria, Lyda
author_facet Sanabria, Lyda
Lederhos, Cecilia Rosa
Quiroga, Monica Esther
Cubillos Lobo, Jairo Antonio
Rojas, Agustin Hugo
Martinez, Jose
author_role author
author2 Lederhos, Cecilia Rosa
Quiroga, Monica Esther
Cubillos Lobo, Jairo Antonio
Rojas, Agustin Hugo
Martinez, Jose
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Ácido 2,5-furandicarboxilico
carbón activado
oxidación aeróbica
topic Ácido 2,5-furandicarboxilico
carbón activado
oxidación aeróbica
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The liquid phase transformation of 5-hydroxymethylfurfuraldehyde (5-HMF) towards 2,5-furandicarboxylicacid (2,5-FDCA) using Pt and Pd catalysts supported on activated carbon and with the presence of CaCO3 andNaOH, is reported. The catalysts were characterized using different techniques, such as: H2 chemisorptionat room temperature, X ray photoelectronic spectroscopy (XPS) and thermogravimetric analysis (TGA).The results indicate that the particle size followed the order: PtCl/C < PdCl/C < PdN/C, which is closelyrelated to the catalytic behavior. It was found that the metal particles are present in the Pd0 and Pt0 form.PtCl/C was most active catalyst using CaCO3 as weak base.
Fil: Sanabria, Lyda. Universidad Pedagógica y Tecnológica de Colombia Uptc; Colombia
Fil: Lederhos, Cecilia Rosa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Quiroga, Monica Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Cubillos Lobo, Jairo Antonio. Universidad Pedagógica y Tecnológica de Colombia Uptc; Colombia
Fil: Rojas, Agustin Hugo. Universidad Pedagógica y Tecnológica de Colombia Uptc; Colombia
Fil: Martinez, Jose. Universidad Pedagógica y Tecnológica de Colombia Uptc; Colombia
description The liquid phase transformation of 5-hydroxymethylfurfuraldehyde (5-HMF) towards 2,5-furandicarboxylicacid (2,5-FDCA) using Pt and Pd catalysts supported on activated carbon and with the presence of CaCO3 andNaOH, is reported. The catalysts were characterized using different techniques, such as: H2 chemisorptionat room temperature, X ray photoelectronic spectroscopy (XPS) and thermogravimetric analysis (TGA).The results indicate that the particle size followed the order: PtCl/C < PdCl/C < PdN/C, which is closelyrelated to the catalytic behavior. It was found that the metal particles are present in the Pd0 and Pt0 form.PtCl/C was most active catalyst using CaCO3 as weak base.
publishDate 2017
dc.date.none.fl_str_mv 2017-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/44141
Sanabria, Lyda; Lederhos, Cecilia Rosa; Quiroga, Monica Esther; Cubillos Lobo, Jairo Antonio; Rojas, Agustin Hugo; et al.; Pt and Pd on activated carbon for oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid; Universidad del Valle. Facultad de Ingeniería; Ingeniería y Competitividad; 19; 2; 9-2017; 36-42
0123-3033
CONICET Digital
CONICET
url http://hdl.handle.net/11336/44141
identifier_str_mv Sanabria, Lyda; Lederhos, Cecilia Rosa; Quiroga, Monica Esther; Cubillos Lobo, Jairo Antonio; Rojas, Agustin Hugo; et al.; Pt and Pd on activated carbon for oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid; Universidad del Valle. Facultad de Ingeniería; Ingeniería y Competitividad; 19; 2; 9-2017; 36-42
0123-3033
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://revistaingenieria.univalle.edu.co/index.php/ingenieria_y_competitividad/article/view/5291
info:eu-repo/semantics/altIdentifier/doi/10.25100/iyc.v19i2.5291
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Universidad del Valle. Facultad de Ingeniería
publisher.none.fl_str_mv Universidad del Valle. Facultad de Ingeniería
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846782357031354368
score 12.982451

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