Crystal structure, physicochemical properties, Hirshfeld surface analysis and antibacterial activity assays of transition metal complexes of 6-methoxyquinoline
- Autores
- Villa Perez, Cristian; Ortega, I.C.; Vélez Macías, Andrea; Payán, A. M.; Echeverría, Gustavo Alberto; Soria, Delia Beatriz; Valencia Uribe, Gloria Cristina
- Año de publicación
- 2018
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Five monomeric complexes of Co(ii), Cu(ii), Ni(ii), Zn(ii) and Ag(i) with 6-methoxyquinoline (6-MeOQ) as ligand have been prepared, and their crystal structures have been determined by single X-ray diffractions. The Cu(ii), Ni(ii) and Zn(ii) complexes are formulated as M(6-MeOQ) 2 Cl 2 , completing MN 2 Cl 2 coordination spheres. On the other hand, Co(ii) and Ag(i) compounds are ionic with formulae [Ag(6-MeOQ) 2 ] + NO 3 - and H(6-MeOQ) + [Co(6-MeOQ)Cl 3 ] - (where H(6-MeOQ) + is the protonated ligand). Hirshfeld surface analysis was employed to study the intermolecular interactions in the crystal lattices and from these studies it was found that π-stacking contacts play an important role. Besides, the complexes have been characterized by FTIR, UV-visible and emission spectroscopies. The singlet oxygen production and fluorescence quantum yields were measured for all the complexes employing steady-state methodologies. Finally, the antibacterial activity of the complexes was screened against both Gram-positive and Gram-negative bacteria.
Fil: Villa Perez, Cristian. Facultad de Ciencias Exactas, Universidad Nacional de la Plata; Argentina
Fil: Ortega, I.C.. Universidad Nacional de Colombia; Colombia
Fil: Vélez Macías, Andrea. Universidad Nacional de Colombia; Colombia
Fil: Payán, A. M.. Universidad Nacional de Colombia; Colombia
Fil: Echeverría, Gustavo Alberto. Facultad de Ciencias Exactas, Universidad Nacional de la Plata; Argentina
Fil: Soria, Delia Beatriz. Facultad de Ciencias Exactas, Universidad Nacional de la Plata; Argentina
Fil: Valencia Uribe, Gloria Cristina. Universidad Nacional de Colombia; Colombia - Materia
-
Synthesis of Complexes
Singlet Oxygen Generation
Quantum Yields
Antibacterial activity - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
.jpg)
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/87542
Ver los metadatos del registro completo
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Crystal structure, physicochemical properties, Hirshfeld surface analysis and antibacterial activity assays of transition metal complexes of 6-methoxyquinolineVilla Perez, CristianOrtega, I.C.Vélez Macías, AndreaPayán, A. M.Echeverría, Gustavo AlbertoSoria, Delia BeatrizValencia Uribe, Gloria CristinaSynthesis of ComplexesSinglet Oxygen GenerationQuantum YieldsAntibacterial activityhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Five monomeric complexes of Co(ii), Cu(ii), Ni(ii), Zn(ii) and Ag(i) with 6-methoxyquinoline (6-MeOQ) as ligand have been prepared, and their crystal structures have been determined by single X-ray diffractions. The Cu(ii), Ni(ii) and Zn(ii) complexes are formulated as M(6-MeOQ) 2 Cl 2 , completing MN 2 Cl 2 coordination spheres. On the other hand, Co(ii) and Ag(i) compounds are ionic with formulae [Ag(6-MeOQ) 2 ] + NO 3 - and H(6-MeOQ) + [Co(6-MeOQ)Cl 3 ] - (where H(6-MeOQ) + is the protonated ligand). Hirshfeld surface analysis was employed to study the intermolecular interactions in the crystal lattices and from these studies it was found that π-stacking contacts play an important role. Besides, the complexes have been characterized by FTIR, UV-visible and emission spectroscopies. The singlet oxygen production and fluorescence quantum yields were measured for all the complexes employing steady-state methodologies. Finally, the antibacterial activity of the complexes was screened against both Gram-positive and Gram-negative bacteria.Fil: Villa Perez, Cristian. Facultad de Ciencias Exactas, Universidad Nacional de la Plata; ArgentinaFil: Ortega, I.C.. Universidad Nacional de Colombia; ColombiaFil: Vélez Macías, Andrea. Universidad Nacional de Colombia; ColombiaFil: Payán, A. M.. Universidad Nacional de Colombia; ColombiaFil: Echeverría, Gustavo Alberto. Facultad de Ciencias Exactas, Universidad Nacional de la Plata; ArgentinaFil: Soria, Delia Beatriz. Facultad de Ciencias Exactas, Universidad Nacional de la Plata; ArgentinaFil: Valencia Uribe, Gloria Cristina. Universidad Nacional de Colombia; ColombiaRoyal Society of Chemistry2018-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/87542Villa Perez, Cristian; Ortega, I.C.; Vélez Macías, Andrea; Payán, A. M.; Echeverría, Gustavo Alberto; et al.; Crystal structure, physicochemical properties, Hirshfeld surface analysis and antibacterial activity assays of transition metal complexes of 6-methoxyquinoline; Royal Society of Chemistry; New Journal of Chemistry; 42; 9; 4-2018; 7166-71761144-0546CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/c8nj00661jinfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2018/NJ/C8NJ00661J#!divAbstractinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2026-02-06T12:37:57Zoai:ri.conicet.gov.ar:11336/87542instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982026-02-06 12:37:57.882CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
| dc.title.none.fl_str_mv |
Crystal structure, physicochemical properties, Hirshfeld surface analysis and antibacterial activity assays of transition metal complexes of 6-methoxyquinoline |
| title |
Crystal structure, physicochemical properties, Hirshfeld surface analysis and antibacterial activity assays of transition metal complexes of 6-methoxyquinoline |
| spellingShingle |
Crystal structure, physicochemical properties, Hirshfeld surface analysis and antibacterial activity assays of transition metal complexes of 6-methoxyquinoline Villa Perez, Cristian Synthesis of Complexes Singlet Oxygen Generation Quantum Yields Antibacterial activity |
| title_short |
Crystal structure, physicochemical properties, Hirshfeld surface analysis and antibacterial activity assays of transition metal complexes of 6-methoxyquinoline |
| title_full |
Crystal structure, physicochemical properties, Hirshfeld surface analysis and antibacterial activity assays of transition metal complexes of 6-methoxyquinoline |
| title_fullStr |
Crystal structure, physicochemical properties, Hirshfeld surface analysis and antibacterial activity assays of transition metal complexes of 6-methoxyquinoline |
| title_full_unstemmed |
Crystal structure, physicochemical properties, Hirshfeld surface analysis and antibacterial activity assays of transition metal complexes of 6-methoxyquinoline |
| title_sort |
Crystal structure, physicochemical properties, Hirshfeld surface analysis and antibacterial activity assays of transition metal complexes of 6-methoxyquinoline |
| dc.creator.none.fl_str_mv |
Villa Perez, Cristian Ortega, I.C. Vélez Macías, Andrea Payán, A. M. Echeverría, Gustavo Alberto Soria, Delia Beatriz Valencia Uribe, Gloria Cristina |
| author |
Villa Perez, Cristian |
| author_facet |
Villa Perez, Cristian Ortega, I.C. Vélez Macías, Andrea Payán, A. M. Echeverría, Gustavo Alberto Soria, Delia Beatriz Valencia Uribe, Gloria Cristina |
| author_role |
author |
| author2 |
Ortega, I.C. Vélez Macías, Andrea Payán, A. M. Echeverría, Gustavo Alberto Soria, Delia Beatriz Valencia Uribe, Gloria Cristina |
| author2_role |
author author author author author author |
| dc.subject.none.fl_str_mv |
Synthesis of Complexes Singlet Oxygen Generation Quantum Yields Antibacterial activity |
| topic |
Synthesis of Complexes Singlet Oxygen Generation Quantum Yields Antibacterial activity |
| purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| dc.description.none.fl_txt_mv |
Five monomeric complexes of Co(ii), Cu(ii), Ni(ii), Zn(ii) and Ag(i) with 6-methoxyquinoline (6-MeOQ) as ligand have been prepared, and their crystal structures have been determined by single X-ray diffractions. The Cu(ii), Ni(ii) and Zn(ii) complexes are formulated as M(6-MeOQ) 2 Cl 2 , completing MN 2 Cl 2 coordination spheres. On the other hand, Co(ii) and Ag(i) compounds are ionic with formulae [Ag(6-MeOQ) 2 ] + NO 3 - and H(6-MeOQ) + [Co(6-MeOQ)Cl 3 ] - (where H(6-MeOQ) + is the protonated ligand). Hirshfeld surface analysis was employed to study the intermolecular interactions in the crystal lattices and from these studies it was found that π-stacking contacts play an important role. Besides, the complexes have been characterized by FTIR, UV-visible and emission spectroscopies. The singlet oxygen production and fluorescence quantum yields were measured for all the complexes employing steady-state methodologies. Finally, the antibacterial activity of the complexes was screened against both Gram-positive and Gram-negative bacteria. Fil: Villa Perez, Cristian. Facultad de Ciencias Exactas, Universidad Nacional de la Plata; Argentina Fil: Ortega, I.C.. Universidad Nacional de Colombia; Colombia Fil: Vélez Macías, Andrea. Universidad Nacional de Colombia; Colombia Fil: Payán, A. M.. Universidad Nacional de Colombia; Colombia Fil: Echeverría, Gustavo Alberto. Facultad de Ciencias Exactas, Universidad Nacional de la Plata; Argentina Fil: Soria, Delia Beatriz. Facultad de Ciencias Exactas, Universidad Nacional de la Plata; Argentina Fil: Valencia Uribe, Gloria Cristina. Universidad Nacional de Colombia; Colombia |
| description |
Five monomeric complexes of Co(ii), Cu(ii), Ni(ii), Zn(ii) and Ag(i) with 6-methoxyquinoline (6-MeOQ) as ligand have been prepared, and their crystal structures have been determined by single X-ray diffractions. The Cu(ii), Ni(ii) and Zn(ii) complexes are formulated as M(6-MeOQ) 2 Cl 2 , completing MN 2 Cl 2 coordination spheres. On the other hand, Co(ii) and Ag(i) compounds are ionic with formulae [Ag(6-MeOQ) 2 ] + NO 3 - and H(6-MeOQ) + [Co(6-MeOQ)Cl 3 ] - (where H(6-MeOQ) + is the protonated ligand). Hirshfeld surface analysis was employed to study the intermolecular interactions in the crystal lattices and from these studies it was found that π-stacking contacts play an important role. Besides, the complexes have been characterized by FTIR, UV-visible and emission spectroscopies. The singlet oxygen production and fluorescence quantum yields were measured for all the complexes employing steady-state methodologies. Finally, the antibacterial activity of the complexes was screened against both Gram-positive and Gram-negative bacteria. |
| publishDate |
2018 |
| dc.date.none.fl_str_mv |
2018-04 |
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info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
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article |
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publishedVersion |
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http://hdl.handle.net/11336/87542 Villa Perez, Cristian; Ortega, I.C.; Vélez Macías, Andrea; Payán, A. M.; Echeverría, Gustavo Alberto; et al.; Crystal structure, physicochemical properties, Hirshfeld surface analysis and antibacterial activity assays of transition metal complexes of 6-methoxyquinoline; Royal Society of Chemistry; New Journal of Chemistry; 42; 9; 4-2018; 7166-7176 1144-0546 CONICET Digital CONICET |
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http://hdl.handle.net/11336/87542 |
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Villa Perez, Cristian; Ortega, I.C.; Vélez Macías, Andrea; Payán, A. M.; Echeverría, Gustavo Alberto; et al.; Crystal structure, physicochemical properties, Hirshfeld surface analysis and antibacterial activity assays of transition metal complexes of 6-methoxyquinoline; Royal Society of Chemistry; New Journal of Chemistry; 42; 9; 4-2018; 7166-7176 1144-0546 CONICET Digital CONICET |
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eng |
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eng |
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info:eu-repo/semantics/altIdentifier/doi/10.1039/c8nj00661j info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2018/NJ/C8NJ00661J#!divAbstract |
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openAccess |
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Royal Society of Chemistry |
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Royal Society of Chemistry |
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dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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