Acid sites development on Cr3+/SiO2 catalysts obtained by the sol-gel method and hydrothermal treatment: Effect of calcination temperature
- Autores
- Cuesta Zapata, Pablo Martín; Parentis, Monica Liliana; Gonzo, Elio Emilio; Bonini, Norberto Alejandro
- Año de publicación
- 2013
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Cr/SiO2 catalysts (4-8% Cr, w/w), obtained from Cr(III) salts and tetraethylortosilicate (TEOS), were prepared by the sol-gel method. After TEOS hydrolysis in ammoniacal solution (pH: 9.5), the gel was treated under hydrothermal conditions at 120-220 C. The solids were characterized by N 2 sorptometry, TG-DTA, DRUV-vis, XRD, and FTIR. In vacuum or N 2 atmosphere, Cr3+ ions were stable up to 450 C. However, calcination in air promotes the partial oxidation of Cr3+ to Cr 6+ as the temperature increases from 200 to 450 C. The amount of Cr6+ formed depends on the temperature of the hydrothermal treatment. 2,6-Lutidine adsorption allows to determine the evolution, with respect to calcination temperature, of both Lewis and Brönsted acid centers. Cr 3+ ions were related to the presence of Lewis sites, and Cr 6+ ions to the development of weak Brönsted acid sites. Accordingly, the 2-propanol dehydration reaction rate shows an increase when the catalysts are treated in N2 at 450 C, while catalysts calcined in air develop a lower acidity. The dehydration reaction is attributed to the presence of Lewis acid centers.
Fil: Cuesta Zapata, Pablo Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
Fil: Parentis, Monica Liliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
Fil: Gonzo, Elio Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
Fil: Bonini, Norberto Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina - Materia
-
Cr/Sio2
Sol-Gel
2,6-Lutidine
Druv-Vis - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/84140
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CONICET Digital (CONICET) |
spelling |
Acid sites development on Cr3+/SiO2 catalysts obtained by the sol-gel method and hydrothermal treatment: Effect of calcination temperatureCuesta Zapata, Pablo MartínParentis, Monica LilianaGonzo, Elio EmilioBonini, Norberto AlejandroCr/Sio2Sol-Gel2,6-LutidineDruv-Vishttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Cr/SiO2 catalysts (4-8% Cr, w/w), obtained from Cr(III) salts and tetraethylortosilicate (TEOS), were prepared by the sol-gel method. After TEOS hydrolysis in ammoniacal solution (pH: 9.5), the gel was treated under hydrothermal conditions at 120-220 C. The solids were characterized by N 2 sorptometry, TG-DTA, DRUV-vis, XRD, and FTIR. In vacuum or N 2 atmosphere, Cr3+ ions were stable up to 450 C. However, calcination in air promotes the partial oxidation of Cr3+ to Cr 6+ as the temperature increases from 200 to 450 C. The amount of Cr6+ formed depends on the temperature of the hydrothermal treatment. 2,6-Lutidine adsorption allows to determine the evolution, with respect to calcination temperature, of both Lewis and Brönsted acid centers. Cr 3+ ions were related to the presence of Lewis sites, and Cr 6+ ions to the development of weak Brönsted acid sites. Accordingly, the 2-propanol dehydration reaction rate shows an increase when the catalysts are treated in N2 at 450 C, while catalysts calcined in air develop a lower acidity. The dehydration reaction is attributed to the presence of Lewis acid centers.Fil: Cuesta Zapata, Pablo Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; ArgentinaFil: Parentis, Monica Liliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; ArgentinaFil: Gonzo, Elio Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; ArgentinaFil: Bonini, Norberto Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; ArgentinaElsevier Science2013-04-24info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/84140Cuesta Zapata, Pablo Martín; Parentis, Monica Liliana; Gonzo, Elio Emilio; Bonini, Norberto Alejandro; Acid sites development on Cr3+/SiO2 catalysts obtained by the sol-gel method and hydrothermal treatment: Effect of calcination temperature; Elsevier Science; Applied Catalysis A: General; 457; 24-4-2013; 26-330926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2013.02.028info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X13001191info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:51:56Zoai:ri.conicet.gov.ar:11336/84140instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:51:56.865CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Acid sites development on Cr3+/SiO2 catalysts obtained by the sol-gel method and hydrothermal treatment: Effect of calcination temperature |
title |
Acid sites development on Cr3+/SiO2 catalysts obtained by the sol-gel method and hydrothermal treatment: Effect of calcination temperature |
spellingShingle |
Acid sites development on Cr3+/SiO2 catalysts obtained by the sol-gel method and hydrothermal treatment: Effect of calcination temperature Cuesta Zapata, Pablo Martín Cr/Sio2 Sol-Gel 2,6-Lutidine Druv-Vis |
title_short |
Acid sites development on Cr3+/SiO2 catalysts obtained by the sol-gel method and hydrothermal treatment: Effect of calcination temperature |
title_full |
Acid sites development on Cr3+/SiO2 catalysts obtained by the sol-gel method and hydrothermal treatment: Effect of calcination temperature |
title_fullStr |
Acid sites development on Cr3+/SiO2 catalysts obtained by the sol-gel method and hydrothermal treatment: Effect of calcination temperature |
title_full_unstemmed |
Acid sites development on Cr3+/SiO2 catalysts obtained by the sol-gel method and hydrothermal treatment: Effect of calcination temperature |
title_sort |
Acid sites development on Cr3+/SiO2 catalysts obtained by the sol-gel method and hydrothermal treatment: Effect of calcination temperature |
dc.creator.none.fl_str_mv |
Cuesta Zapata, Pablo Martín Parentis, Monica Liliana Gonzo, Elio Emilio Bonini, Norberto Alejandro |
author |
Cuesta Zapata, Pablo Martín |
author_facet |
Cuesta Zapata, Pablo Martín Parentis, Monica Liliana Gonzo, Elio Emilio Bonini, Norberto Alejandro |
author_role |
author |
author2 |
Parentis, Monica Liliana Gonzo, Elio Emilio Bonini, Norberto Alejandro |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Cr/Sio2 Sol-Gel 2,6-Lutidine Druv-Vis |
topic |
Cr/Sio2 Sol-Gel 2,6-Lutidine Druv-Vis |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 https://purl.org/becyt/ford/2.10 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Cr/SiO2 catalysts (4-8% Cr, w/w), obtained from Cr(III) salts and tetraethylortosilicate (TEOS), were prepared by the sol-gel method. After TEOS hydrolysis in ammoniacal solution (pH: 9.5), the gel was treated under hydrothermal conditions at 120-220 C. The solids were characterized by N 2 sorptometry, TG-DTA, DRUV-vis, XRD, and FTIR. In vacuum or N 2 atmosphere, Cr3+ ions were stable up to 450 C. However, calcination in air promotes the partial oxidation of Cr3+ to Cr 6+ as the temperature increases from 200 to 450 C. The amount of Cr6+ formed depends on the temperature of the hydrothermal treatment. 2,6-Lutidine adsorption allows to determine the evolution, with respect to calcination temperature, of both Lewis and Brönsted acid centers. Cr 3+ ions were related to the presence of Lewis sites, and Cr 6+ ions to the development of weak Brönsted acid sites. Accordingly, the 2-propanol dehydration reaction rate shows an increase when the catalysts are treated in N2 at 450 C, while catalysts calcined in air develop a lower acidity. The dehydration reaction is attributed to the presence of Lewis acid centers. Fil: Cuesta Zapata, Pablo Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina Fil: Parentis, Monica Liliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina Fil: Gonzo, Elio Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina Fil: Bonini, Norberto Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina |
description |
Cr/SiO2 catalysts (4-8% Cr, w/w), obtained from Cr(III) salts and tetraethylortosilicate (TEOS), were prepared by the sol-gel method. After TEOS hydrolysis in ammoniacal solution (pH: 9.5), the gel was treated under hydrothermal conditions at 120-220 C. The solids were characterized by N 2 sorptometry, TG-DTA, DRUV-vis, XRD, and FTIR. In vacuum or N 2 atmosphere, Cr3+ ions were stable up to 450 C. However, calcination in air promotes the partial oxidation of Cr3+ to Cr 6+ as the temperature increases from 200 to 450 C. The amount of Cr6+ formed depends on the temperature of the hydrothermal treatment. 2,6-Lutidine adsorption allows to determine the evolution, with respect to calcination temperature, of both Lewis and Brönsted acid centers. Cr 3+ ions were related to the presence of Lewis sites, and Cr 6+ ions to the development of weak Brönsted acid sites. Accordingly, the 2-propanol dehydration reaction rate shows an increase when the catalysts are treated in N2 at 450 C, while catalysts calcined in air develop a lower acidity. The dehydration reaction is attributed to the presence of Lewis acid centers. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-04-24 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/84140 Cuesta Zapata, Pablo Martín; Parentis, Monica Liliana; Gonzo, Elio Emilio; Bonini, Norberto Alejandro; Acid sites development on Cr3+/SiO2 catalysts obtained by the sol-gel method and hydrothermal treatment: Effect of calcination temperature; Elsevier Science; Applied Catalysis A: General; 457; 24-4-2013; 26-33 0926-860X CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/84140 |
identifier_str_mv |
Cuesta Zapata, Pablo Martín; Parentis, Monica Liliana; Gonzo, Elio Emilio; Bonini, Norberto Alejandro; Acid sites development on Cr3+/SiO2 catalysts obtained by the sol-gel method and hydrothermal treatment: Effect of calcination temperature; Elsevier Science; Applied Catalysis A: General; 457; 24-4-2013; 26-33 0926-860X CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2013.02.028 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X13001191 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844613594840301568 |
score |
13.070432 |