Remote activation by green-light irradiation of shape memory epoxies containing gold nanoparticles

Autores
Leonardi, Agustina Belen; Puig, Julieta; Antonacci, Julian; Arenas, Gustavo Francisco; Zucchi, Ileana Alicia; Hoppe, Cristina Elena; Reven, Linda; Zhu, Liu; Toader, Violeta; Williams, Roberto Juan Jose
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Shape memory epoxies (SMEs) that can be remotely activated by the use of green light, are described. An epoxy matrix based on on diglycidylether of bisphenol A (DGEBA cured with a mixture of n-dodecylamine (DA) and m-xylylenediamine (MXDA), exhibits excellent shape memory properties as described in a previous paper (Leonardi et al., 2011). Au NPs with an average diameter close to 5 nm could be uniformly dispersed in this matrix using poly(ethylene oxide) (PEO) chains as stabilizer. These NPs showed a significant photothermal effect even at very low concentrations (0.01 wt% as metallic gold), when irradiated with a 532 nm laser at a power close to 2 W/cm2. Under these conditions, a bended bar (1.4-mm thickness) recovered its initial shape in a few seconds. This formulation may be used to build up devices with the necessary mechanical strength and with the possibility to produce shape recovery by remote activation using green light. A second example was analyzed employing an amphiphilic epoxy matrix to produce a uniform dispersion of Au NPs stabilized with dodecyl chains (average diameter close to 3 nm). A bar (1.4-mm thickness) of the SME with 0.04 wt% Au NPs (as metallic gold) showed a fast recovery of its initial shape by irradiation with a 532 nm laser at a power close to 2 W/cm2. This example shows the feasibility of adapting the epoxy chemistry to disperse Au NPs stabilized with different ligands and obtained through robust synthetic methods.
Fil: Leonardi, Agustina Belen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Puig, Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Antonacci, Julian. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Departamento de Física; Argentina
Fil: Arenas, Gustavo Francisco. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Departamento de Física; Argentina
Fil: Zucchi, Ileana Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Hoppe, Cristina Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Reven, Linda. McGill University; Canadá
Fil: Zhu, Liu. Peking University Shenzhen Graduate School; China
Fil: Toader, Violeta. McGill University; Canadá
Fil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Epoxy Nanocomposites
Gold Nanoparticles
Photothermal Effect
Remote Activation
Shape Memory Epoxies
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/39648
Acceder
id CONICETDig_49210a57a3c06196d53bb26a0696acbf
oai_identifier_str oai:ri.conicet.gov.ar:11336/39648
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Remote activation by green-light irradiation of shape memory epoxies containing gold nanoparticlesLeonardi, Agustina BelenPuig, JulietaAntonacci, JulianArenas, Gustavo FranciscoZucchi, Ileana AliciaHoppe, Cristina ElenaReven, LindaZhu, LiuToader, VioletaWilliams, Roberto Juan JoseEpoxy NanocompositesGold NanoparticlesPhotothermal EffectRemote ActivationShape Memory Epoxieshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Shape memory epoxies (SMEs) that can be remotely activated by the use of green light, are described. An epoxy matrix based on on diglycidylether of bisphenol A (DGEBA cured with a mixture of n-dodecylamine (DA) and m-xylylenediamine (MXDA), exhibits excellent shape memory properties as described in a previous paper (Leonardi et al., 2011). Au NPs with an average diameter close to 5 nm could be uniformly dispersed in this matrix using poly(ethylene oxide) (PEO) chains as stabilizer. These NPs showed a significant photothermal effect even at very low concentrations (0.01 wt% as metallic gold), when irradiated with a 532 nm laser at a power close to 2 W/cm2. Under these conditions, a bended bar (1.4-mm thickness) recovered its initial shape in a few seconds. This formulation may be used to build up devices with the necessary mechanical strength and with the possibility to produce shape recovery by remote activation using green light. A second example was analyzed employing an amphiphilic epoxy matrix to produce a uniform dispersion of Au NPs stabilized with dodecyl chains (average diameter close to 3 nm). A bar (1.4-mm thickness) of the SME with 0.04 wt% Au NPs (as metallic gold) showed a fast recovery of its initial shape by irradiation with a 532 nm laser at a power close to 2 W/cm2. This example shows the feasibility of adapting the epoxy chemistry to disperse Au NPs stabilized with different ligands and obtained through robust synthetic methods.Fil: Leonardi, Agustina Belen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Puig, Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Antonacci, Julian. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Departamento de Física; ArgentinaFil: Arenas, Gustavo Francisco. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Departamento de Física; ArgentinaFil: Zucchi, Ileana Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Hoppe, Cristina Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Reven, Linda. McGill University; CanadáFil: Zhu, Liu. Peking University Shenzhen Graduate School; ChinaFil: Toader, Violeta. McGill University; CanadáFil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaPergamon-Elsevier Science Ltd2015-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/39648Leonardi, Agustina Belen; Puig, Julieta; Antonacci, Julian; Arenas, Gustavo Francisco; Zucchi, Ileana Alicia; et al.; Remote activation by green-light irradiation of shape memory epoxies containing gold nanoparticles; Pergamon-Elsevier Science Ltd; European Polymer Journal; 71; 10-2015; 451-4600014-3057CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.eurpolymj.2015.08.024info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0014305715004413info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:19:07Zoai:ri.conicet.gov.ar:11336/39648instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:19:07.356CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Remote activation by green-light irradiation of shape memory epoxies containing gold nanoparticles
title Remote activation by green-light irradiation of shape memory epoxies containing gold nanoparticles
spellingShingle Remote activation by green-light irradiation of shape memory epoxies containing gold nanoparticles
Leonardi, Agustina Belen
Epoxy Nanocomposites
Gold Nanoparticles
Photothermal Effect
Remote Activation
Shape Memory Epoxies
title_short Remote activation by green-light irradiation of shape memory epoxies containing gold nanoparticles
title_full Remote activation by green-light irradiation of shape memory epoxies containing gold nanoparticles
title_fullStr Remote activation by green-light irradiation of shape memory epoxies containing gold nanoparticles
title_full_unstemmed Remote activation by green-light irradiation of shape memory epoxies containing gold nanoparticles
title_sort Remote activation by green-light irradiation of shape memory epoxies containing gold nanoparticles
dc.creator.none.fl_str_mv Leonardi, Agustina Belen
Puig, Julieta
Antonacci, Julian
Arenas, Gustavo Francisco
Zucchi, Ileana Alicia
Hoppe, Cristina Elena
Reven, Linda
Zhu, Liu
Toader, Violeta
Williams, Roberto Juan Jose
author Leonardi, Agustina Belen
author_facet Leonardi, Agustina Belen
Puig, Julieta
Antonacci, Julian
Arenas, Gustavo Francisco
Zucchi, Ileana Alicia
Hoppe, Cristina Elena
Reven, Linda
Zhu, Liu
Toader, Violeta
Williams, Roberto Juan Jose
author_role author
author2 Puig, Julieta
Antonacci, Julian
Arenas, Gustavo Francisco
Zucchi, Ileana Alicia
Hoppe, Cristina Elena
Reven, Linda
Zhu, Liu
Toader, Violeta
Williams, Roberto Juan Jose
author2_role author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Epoxy Nanocomposites
Gold Nanoparticles
Photothermal Effect
Remote Activation
Shape Memory Epoxies
topic Epoxy Nanocomposites
Gold Nanoparticles
Photothermal Effect
Remote Activation
Shape Memory Epoxies
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Shape memory epoxies (SMEs) that can be remotely activated by the use of green light, are described. An epoxy matrix based on on diglycidylether of bisphenol A (DGEBA cured with a mixture of n-dodecylamine (DA) and m-xylylenediamine (MXDA), exhibits excellent shape memory properties as described in a previous paper (Leonardi et al., 2011). Au NPs with an average diameter close to 5 nm could be uniformly dispersed in this matrix using poly(ethylene oxide) (PEO) chains as stabilizer. These NPs showed a significant photothermal effect even at very low concentrations (0.01 wt% as metallic gold), when irradiated with a 532 nm laser at a power close to 2 W/cm2. Under these conditions, a bended bar (1.4-mm thickness) recovered its initial shape in a few seconds. This formulation may be used to build up devices with the necessary mechanical strength and with the possibility to produce shape recovery by remote activation using green light. A second example was analyzed employing an amphiphilic epoxy matrix to produce a uniform dispersion of Au NPs stabilized with dodecyl chains (average diameter close to 3 nm). A bar (1.4-mm thickness) of the SME with 0.04 wt% Au NPs (as metallic gold) showed a fast recovery of its initial shape by irradiation with a 532 nm laser at a power close to 2 W/cm2. This example shows the feasibility of adapting the epoxy chemistry to disperse Au NPs stabilized with different ligands and obtained through robust synthetic methods.
Fil: Leonardi, Agustina Belen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Puig, Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Antonacci, Julian. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Departamento de Física; Argentina
Fil: Arenas, Gustavo Francisco. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Departamento de Física; Argentina
Fil: Zucchi, Ileana Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Hoppe, Cristina Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Reven, Linda. McGill University; Canadá
Fil: Zhu, Liu. Peking University Shenzhen Graduate School; China
Fil: Toader, Violeta. McGill University; Canadá
Fil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description Shape memory epoxies (SMEs) that can be remotely activated by the use of green light, are described. An epoxy matrix based on on diglycidylether of bisphenol A (DGEBA cured with a mixture of n-dodecylamine (DA) and m-xylylenediamine (MXDA), exhibits excellent shape memory properties as described in a previous paper (Leonardi et al., 2011). Au NPs with an average diameter close to 5 nm could be uniformly dispersed in this matrix using poly(ethylene oxide) (PEO) chains as stabilizer. These NPs showed a significant photothermal effect even at very low concentrations (0.01 wt% as metallic gold), when irradiated with a 532 nm laser at a power close to 2 W/cm2. Under these conditions, a bended bar (1.4-mm thickness) recovered its initial shape in a few seconds. This formulation may be used to build up devices with the necessary mechanical strength and with the possibility to produce shape recovery by remote activation using green light. A second example was analyzed employing an amphiphilic epoxy matrix to produce a uniform dispersion of Au NPs stabilized with dodecyl chains (average diameter close to 3 nm). A bar (1.4-mm thickness) of the SME with 0.04 wt% Au NPs (as metallic gold) showed a fast recovery of its initial shape by irradiation with a 532 nm laser at a power close to 2 W/cm2. This example shows the feasibility of adapting the epoxy chemistry to disperse Au NPs stabilized with different ligands and obtained through robust synthetic methods.
publishDate 2015
dc.date.none.fl_str_mv 2015-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/39648
Leonardi, Agustina Belen; Puig, Julieta; Antonacci, Julian; Arenas, Gustavo Francisco; Zucchi, Ileana Alicia; et al.; Remote activation by green-light irradiation of shape memory epoxies containing gold nanoparticles; Pergamon-Elsevier Science Ltd; European Polymer Journal; 71; 10-2015; 451-460
0014-3057
CONICET Digital
CONICET
url http://hdl.handle.net/11336/39648
identifier_str_mv Leonardi, Agustina Belen; Puig, Julieta; Antonacci, Julian; Arenas, Gustavo Francisco; Zucchi, Ileana Alicia; et al.; Remote activation by green-light irradiation of shape memory epoxies containing gold nanoparticles; Pergamon-Elsevier Science Ltd; European Polymer Journal; 71; 10-2015; 451-460
0014-3057
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.eurpolymj.2015.08.024
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0014305715004413
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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