Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes
- Autores
- Byrne Prudente, Tomas Eduardo; Mauro, Diandra; Puig, Julieta; Altuna, Facundo Ignacio; Da Ros, Tatiana; Hoppe, Cristina Elena
- Año de publicación
- 2023
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Films of a vitrimer based on the reaction between diglycidylether of bisphenol A and glutaric acid in the presence of 1-methylimidazole were processed using a solvent-based technique. The curing schedule was divided into two steps: first, a soluble linear polymer was formed through the reaction of the diacid and the diepoxide, and then the crosslinking was induced at a higher temperature via transesterification reactions. This epoxy–acid vitrimer was modified with multi-walled carbon nanotubes (MWCNTs) functionalized with β-hydroxyesters, produced by a robust and straightforward strategy based on a two-phase reaction between oxidized MWCNTs and phenylglycidylether. Nanocomposite vitrimer films were obtained by drop casting a dispersion of the functionalized MWCNTs in the linear polymer/cyclohexanone solution, followed by a thermal treatment. A high degree of dispersion of the carbon nanostructures was attained thanks to the β-hydroxyester functionalization when compared with oxidized MWCNTs. Nanocomposite films showed a significant photothermal effect (reaching 200 ◦C or above in 30 s) upon NIR light irradiation (850 nm) from a single LED (500 mW/cm2 ). The released heat was used to activate the shape memory effect and weld and heal the vitrimer matrix, proving the success of this easy strategy for the generation of remotely activated carbon-based vitrimer nanocomposites.
Fil: Byrne Prudente, Tomas Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Mauro, Diandra. Università degli Studi di Trieste; Italia
Fil: Puig, Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Altuna, Facundo Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Da Ros, Tatiana. Università degli Studi di Trieste; Italia
Fil: Hoppe, Cristina Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina - Materia
-
multi-walled carbon nanotubes (MWCNTs)
epoxy vitrimers
NIR photothermal effect
remote activation
shape memory
self-healing - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/239345
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Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon NanotubesByrne Prudente, Tomas EduardoMauro, DiandraPuig, JulietaAltuna, Facundo IgnacioDa Ros, TatianaHoppe, Cristina Elenamulti-walled carbon nanotubes (MWCNTs)epoxy vitrimersNIR photothermal effectremote activationshape memoryself-healinghttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Films of a vitrimer based on the reaction between diglycidylether of bisphenol A and glutaric acid in the presence of 1-methylimidazole were processed using a solvent-based technique. The curing schedule was divided into two steps: first, a soluble linear polymer was formed through the reaction of the diacid and the diepoxide, and then the crosslinking was induced at a higher temperature via transesterification reactions. This epoxy–acid vitrimer was modified with multi-walled carbon nanotubes (MWCNTs) functionalized with β-hydroxyesters, produced by a robust and straightforward strategy based on a two-phase reaction between oxidized MWCNTs and phenylglycidylether. Nanocomposite vitrimer films were obtained by drop casting a dispersion of the functionalized MWCNTs in the linear polymer/cyclohexanone solution, followed by a thermal treatment. A high degree of dispersion of the carbon nanostructures was attained thanks to the β-hydroxyester functionalization when compared with oxidized MWCNTs. Nanocomposite films showed a significant photothermal effect (reaching 200 ◦C or above in 30 s) upon NIR light irradiation (850 nm) from a single LED (500 mW/cm2 ). The released heat was used to activate the shape memory effect and weld and heal the vitrimer matrix, proving the success of this easy strategy for the generation of remotely activated carbon-based vitrimer nanocomposites.Fil: Byrne Prudente, Tomas Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Mauro, Diandra. Università degli Studi di Trieste; ItaliaFil: Puig, Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Altuna, Facundo Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Da Ros, Tatiana. Università degli Studi di Trieste; ItaliaFil: Hoppe, Cristina Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaMultidisciplinary Digital Publishing Institute2023-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/239345Byrne Prudente, Tomas Eduardo; Mauro, Diandra; Puig, Julieta; Altuna, Facundo Ignacio; Da Ros, Tatiana; et al.; Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes; Multidisciplinary Digital Publishing Institute; C; 9; 4; 12-2023; 1-212311-5629CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2311-5629/9/4/119info:eu-repo/semantics/altIdentifier/doi/10.3390/c9040119info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:08:28Zoai:ri.conicet.gov.ar:11336/239345instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:08:28.414CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes |
title |
Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes |
spellingShingle |
Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes Byrne Prudente, Tomas Eduardo multi-walled carbon nanotubes (MWCNTs) epoxy vitrimers NIR photothermal effect remote activation shape memory self-healing |
title_short |
Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes |
title_full |
Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes |
title_fullStr |
Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes |
title_full_unstemmed |
Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes |
title_sort |
Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes |
dc.creator.none.fl_str_mv |
Byrne Prudente, Tomas Eduardo Mauro, Diandra Puig, Julieta Altuna, Facundo Ignacio Da Ros, Tatiana Hoppe, Cristina Elena |
author |
Byrne Prudente, Tomas Eduardo |
author_facet |
Byrne Prudente, Tomas Eduardo Mauro, Diandra Puig, Julieta Altuna, Facundo Ignacio Da Ros, Tatiana Hoppe, Cristina Elena |
author_role |
author |
author2 |
Mauro, Diandra Puig, Julieta Altuna, Facundo Ignacio Da Ros, Tatiana Hoppe, Cristina Elena |
author2_role |
author author author author author |
dc.subject.none.fl_str_mv |
multi-walled carbon nanotubes (MWCNTs) epoxy vitrimers NIR photothermal effect remote activation shape memory self-healing |
topic |
multi-walled carbon nanotubes (MWCNTs) epoxy vitrimers NIR photothermal effect remote activation shape memory self-healing |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Films of a vitrimer based on the reaction between diglycidylether of bisphenol A and glutaric acid in the presence of 1-methylimidazole were processed using a solvent-based technique. The curing schedule was divided into two steps: first, a soluble linear polymer was formed through the reaction of the diacid and the diepoxide, and then the crosslinking was induced at a higher temperature via transesterification reactions. This epoxy–acid vitrimer was modified with multi-walled carbon nanotubes (MWCNTs) functionalized with β-hydroxyesters, produced by a robust and straightforward strategy based on a two-phase reaction between oxidized MWCNTs and phenylglycidylether. Nanocomposite vitrimer films were obtained by drop casting a dispersion of the functionalized MWCNTs in the linear polymer/cyclohexanone solution, followed by a thermal treatment. A high degree of dispersion of the carbon nanostructures was attained thanks to the β-hydroxyester functionalization when compared with oxidized MWCNTs. Nanocomposite films showed a significant photothermal effect (reaching 200 ◦C or above in 30 s) upon NIR light irradiation (850 nm) from a single LED (500 mW/cm2 ). The released heat was used to activate the shape memory effect and weld and heal the vitrimer matrix, proving the success of this easy strategy for the generation of remotely activated carbon-based vitrimer nanocomposites. Fil: Byrne Prudente, Tomas Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Mauro, Diandra. Università degli Studi di Trieste; Italia Fil: Puig, Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Altuna, Facundo Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Da Ros, Tatiana. Università degli Studi di Trieste; Italia Fil: Hoppe, Cristina Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina |
description |
Films of a vitrimer based on the reaction between diglycidylether of bisphenol A and glutaric acid in the presence of 1-methylimidazole were processed using a solvent-based technique. The curing schedule was divided into two steps: first, a soluble linear polymer was formed through the reaction of the diacid and the diepoxide, and then the crosslinking was induced at a higher temperature via transesterification reactions. This epoxy–acid vitrimer was modified with multi-walled carbon nanotubes (MWCNTs) functionalized with β-hydroxyesters, produced by a robust and straightforward strategy based on a two-phase reaction between oxidized MWCNTs and phenylglycidylether. Nanocomposite vitrimer films were obtained by drop casting a dispersion of the functionalized MWCNTs in the linear polymer/cyclohexanone solution, followed by a thermal treatment. A high degree of dispersion of the carbon nanostructures was attained thanks to the β-hydroxyester functionalization when compared with oxidized MWCNTs. Nanocomposite films showed a significant photothermal effect (reaching 200 ◦C or above in 30 s) upon NIR light irradiation (850 nm) from a single LED (500 mW/cm2 ). The released heat was used to activate the shape memory effect and weld and heal the vitrimer matrix, proving the success of this easy strategy for the generation of remotely activated carbon-based vitrimer nanocomposites. |
publishDate |
2023 |
dc.date.none.fl_str_mv |
2023-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/239345 Byrne Prudente, Tomas Eduardo; Mauro, Diandra; Puig, Julieta; Altuna, Facundo Ignacio; Da Ros, Tatiana; et al.; Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes; Multidisciplinary Digital Publishing Institute; C; 9; 4; 12-2023; 1-21 2311-5629 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/239345 |
identifier_str_mv |
Byrne Prudente, Tomas Eduardo; Mauro, Diandra; Puig, Julieta; Altuna, Facundo Ignacio; Da Ros, Tatiana; et al.; Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes; Multidisciplinary Digital Publishing Institute; C; 9; 4; 12-2023; 1-21 2311-5629 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2311-5629/9/4/119 info:eu-repo/semantics/altIdentifier/doi/10.3390/c9040119 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Multidisciplinary Digital Publishing Institute |
publisher.none.fl_str_mv |
Multidisciplinary Digital Publishing Institute |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613952425689088 |
score |
13.070432 |