Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes

Autores
Byrne Prudente, Tomas Eduardo; Mauro, Diandra; Puig, Julieta; Altuna, Facundo Ignacio; Da Ros, Tatiana; Hoppe, Cristina Elena
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Films of a vitrimer based on the reaction between diglycidylether of bisphenol A and glutaric acid in the presence of 1-methylimidazole were processed using a solvent-based technique. The curing schedule was divided into two steps: first, a soluble linear polymer was formed through the reaction of the diacid and the diepoxide, and then the crosslinking was induced at a higher temperature via transesterification reactions. This epoxy–acid vitrimer was modified with multi-walled carbon nanotubes (MWCNTs) functionalized with β-hydroxyesters, produced by a robust and straightforward strategy based on a two-phase reaction between oxidized MWCNTs and phenylglycidylether. Nanocomposite vitrimer films were obtained by drop casting a dispersion of the functionalized MWCNTs in the linear polymer/cyclohexanone solution, followed by a thermal treatment. A high degree of dispersion of the carbon nanostructures was attained thanks to the β-hydroxyester functionalization when compared with oxidized MWCNTs. Nanocomposite films showed a significant photothermal effect (reaching 200 ◦C or above in 30 s) upon NIR light irradiation (850 nm) from a single LED (500 mW/cm2 ). The released heat was used to activate the shape memory effect and weld and heal the vitrimer matrix, proving the success of this easy strategy for the generation of remotely activated carbon-based vitrimer nanocomposites.
Fil: Byrne Prudente, Tomas Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Mauro, Diandra. Università degli Studi di Trieste; Italia
Fil: Puig, Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Altuna, Facundo Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Da Ros, Tatiana. Università degli Studi di Trieste; Italia
Fil: Hoppe, Cristina Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
multi-walled carbon nanotubes (MWCNTs)
epoxy vitrimers
NIR photothermal effect
remote activation
shape memory
self-healing
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/239345
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/239345
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon NanotubesByrne Prudente, Tomas EduardoMauro, DiandraPuig, JulietaAltuna, Facundo IgnacioDa Ros, TatianaHoppe, Cristina Elenamulti-walled carbon nanotubes (MWCNTs)epoxy vitrimersNIR photothermal effectremote activationshape memoryself-healinghttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Films of a vitrimer based on the reaction between diglycidylether of bisphenol A and glutaric acid in the presence of 1-methylimidazole were processed using a solvent-based technique. The curing schedule was divided into two steps: first, a soluble linear polymer was formed through the reaction of the diacid and the diepoxide, and then the crosslinking was induced at a higher temperature via transesterification reactions. This epoxy–acid vitrimer was modified with multi-walled carbon nanotubes (MWCNTs) functionalized with β-hydroxyesters, produced by a robust and straightforward strategy based on a two-phase reaction between oxidized MWCNTs and phenylglycidylether. Nanocomposite vitrimer films were obtained by drop casting a dispersion of the functionalized MWCNTs in the linear polymer/cyclohexanone solution, followed by a thermal treatment. A high degree of dispersion of the carbon nanostructures was attained thanks to the β-hydroxyester functionalization when compared with oxidized MWCNTs. Nanocomposite films showed a significant photothermal effect (reaching 200 ◦C or above in 30 s) upon NIR light irradiation (850 nm) from a single LED (500 mW/cm2 ). The released heat was used to activate the shape memory effect and weld and heal the vitrimer matrix, proving the success of this easy strategy for the generation of remotely activated carbon-based vitrimer nanocomposites.Fil: Byrne Prudente, Tomas Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Mauro, Diandra. Università degli Studi di Trieste; ItaliaFil: Puig, Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Altuna, Facundo Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Da Ros, Tatiana. Università degli Studi di Trieste; ItaliaFil: Hoppe, Cristina Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaMultidisciplinary Digital Publishing Institute2023-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/239345Byrne Prudente, Tomas Eduardo; Mauro, Diandra; Puig, Julieta; Altuna, Facundo Ignacio; Da Ros, Tatiana; et al.; Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes; Multidisciplinary Digital Publishing Institute; C; 9; 4; 12-2023; 1-212311-5629CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2311-5629/9/4/119info:eu-repo/semantics/altIdentifier/doi/10.3390/c9040119info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:38:18Zoai:ri.conicet.gov.ar:11336/239345instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:38:18.458CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes
title Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes
spellingShingle Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes
Byrne Prudente, Tomas Eduardo
multi-walled carbon nanotubes (MWCNTs)
epoxy vitrimers
NIR photothermal effect
remote activation
shape memory
self-healing
title_short Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes
title_full Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes
title_fullStr Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes
title_full_unstemmed Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes
title_sort Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes
dc.creator.none.fl_str_mv Byrne Prudente, Tomas Eduardo
Mauro, Diandra
Puig, Julieta
Altuna, Facundo Ignacio
Da Ros, Tatiana
Hoppe, Cristina Elena
author Byrne Prudente, Tomas Eduardo
author_facet Byrne Prudente, Tomas Eduardo
Mauro, Diandra
Puig, Julieta
Altuna, Facundo Ignacio
Da Ros, Tatiana
Hoppe, Cristina Elena
author_role author
author2 Mauro, Diandra
Puig, Julieta
Altuna, Facundo Ignacio
Da Ros, Tatiana
Hoppe, Cristina Elena
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv multi-walled carbon nanotubes (MWCNTs)
epoxy vitrimers
NIR photothermal effect
remote activation
shape memory
self-healing
topic multi-walled carbon nanotubes (MWCNTs)
epoxy vitrimers
NIR photothermal effect
remote activation
shape memory
self-healing
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Films of a vitrimer based on the reaction between diglycidylether of bisphenol A and glutaric acid in the presence of 1-methylimidazole were processed using a solvent-based technique. The curing schedule was divided into two steps: first, a soluble linear polymer was formed through the reaction of the diacid and the diepoxide, and then the crosslinking was induced at a higher temperature via transesterification reactions. This epoxy–acid vitrimer was modified with multi-walled carbon nanotubes (MWCNTs) functionalized with β-hydroxyesters, produced by a robust and straightforward strategy based on a two-phase reaction between oxidized MWCNTs and phenylglycidylether. Nanocomposite vitrimer films were obtained by drop casting a dispersion of the functionalized MWCNTs in the linear polymer/cyclohexanone solution, followed by a thermal treatment. A high degree of dispersion of the carbon nanostructures was attained thanks to the β-hydroxyester functionalization when compared with oxidized MWCNTs. Nanocomposite films showed a significant photothermal effect (reaching 200 ◦C or above in 30 s) upon NIR light irradiation (850 nm) from a single LED (500 mW/cm2 ). The released heat was used to activate the shape memory effect and weld and heal the vitrimer matrix, proving the success of this easy strategy for the generation of remotely activated carbon-based vitrimer nanocomposites.
Fil: Byrne Prudente, Tomas Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Mauro, Diandra. Università degli Studi di Trieste; Italia
Fil: Puig, Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Altuna, Facundo Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Da Ros, Tatiana. Università degli Studi di Trieste; Italia
Fil: Hoppe, Cristina Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description Films of a vitrimer based on the reaction between diglycidylether of bisphenol A and glutaric acid in the presence of 1-methylimidazole were processed using a solvent-based technique. The curing schedule was divided into two steps: first, a soluble linear polymer was formed through the reaction of the diacid and the diepoxide, and then the crosslinking was induced at a higher temperature via transesterification reactions. This epoxy–acid vitrimer was modified with multi-walled carbon nanotubes (MWCNTs) functionalized with β-hydroxyesters, produced by a robust and straightforward strategy based on a two-phase reaction between oxidized MWCNTs and phenylglycidylether. Nanocomposite vitrimer films were obtained by drop casting a dispersion of the functionalized MWCNTs in the linear polymer/cyclohexanone solution, followed by a thermal treatment. A high degree of dispersion of the carbon nanostructures was attained thanks to the β-hydroxyester functionalization when compared with oxidized MWCNTs. Nanocomposite films showed a significant photothermal effect (reaching 200 ◦C or above in 30 s) upon NIR light irradiation (850 nm) from a single LED (500 mW/cm2 ). The released heat was used to activate the shape memory effect and weld and heal the vitrimer matrix, proving the success of this easy strategy for the generation of remotely activated carbon-based vitrimer nanocomposites.
publishDate 2023
dc.date.none.fl_str_mv 2023-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/239345
Byrne Prudente, Tomas Eduardo; Mauro, Diandra; Puig, Julieta; Altuna, Facundo Ignacio; Da Ros, Tatiana; et al.; Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes; Multidisciplinary Digital Publishing Institute; C; 9; 4; 12-2023; 1-21
2311-5629
CONICET Digital
CONICET
url http://hdl.handle.net/11336/239345
identifier_str_mv Byrne Prudente, Tomas Eduardo; Mauro, Diandra; Puig, Julieta; Altuna, Facundo Ignacio; Da Ros, Tatiana; et al.; Synthesis and Processing of Near Infrared—Activated Vitrimer Nanocomposite Films Modified with β-Hydroxyester-Functionalized Multi-Walled Carbon Nanotubes; Multidisciplinary Digital Publishing Institute; C; 9; 4; 12-2023; 1-21
2311-5629
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2311-5629/9/4/119
info:eu-repo/semantics/altIdentifier/doi/10.3390/c9040119
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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