Sorption behavior of the MgH2-Mg2FeH6 hydride storage system synthesized by mechanical milling followed by sintering

Autores
Puszkiel, Julián Atilio; Gennari, Fabiana Cristina; Arneodo Larochette, Pierre Paul; Karimi, Fahim; Pistidda, Claudio; Gosalawit Utke, Rapee; Jepsen, Julian; Jensen, Torben R.; Gundlach, Carsten; Bellosta von Colbe, José; Klassen, Thomas; Dornheim, Martin
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The hydrogen sorption behavior of the Mg2FeH6eMgH2hydride system is investigated via in-situ synchrotron and laboratory powder X-ray diffraction (SR-PXD), differential scanning calorimetry (DSC), scanning electron microscopy (SEM), particle size distribution (PSD) and volumetric techniques. The Mg2FeH6eMgH2 hydride system is obtained by mechanical milling in argon atmosphere followed by sintering at high temperature and hydrogen pressure. In-situ SR-PXD results show that upon hydriding MgH2 is a precursor for Mg2FeH6 formation and remained as hydrided phase in the obtained material. Diffusion constraints preclude the further formation of Mg2FeH6. Upon dehydriding, our results suggest that MgH2 and Mg2FeH6 decompose independently in a narrow temperature range between 275 and 300 C. Moreover, the decomposition behavior of both hydrides in the Mg2FeH6eMgH2 hydride mixture is influenced by each other via dual synergetic-destabilizing effects. The final hydriding/dehydriding products and therefore the kinetic behavior of the Mg2FeH6eMgH2 hydride system exhibits a strong dependence on the temperature and pressure conditions.
Fil: Puszkiel, Julián Atilio. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; Argentina
Fil: Gennari, Fabiana Cristina. Comision Nacional de Energia Atomica. Gerencia de Area de Aplicaciones de la Tecnologia Nuclear. Gerencia de Investigacion Aplicada; . Universidad Nacional de Cuyo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Arneodo Larochette, Pierre Paul. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comision Nacional de Energia Atomica. Gerencia de Area de Aplicaciones de la Tecnologia Nuclear. Gerencia de Investigacion Aplicada; . Universidad Nacional de Cuyo; Argentina
Fil: Karimi, Fahim. Materials Technology. Institute of Materials Research; Alemania
Fil: Pistidda, Claudio. Materials Technology. Institute of Materials Research; Alemania
Fil: Gosalawit Utke, Rapee. Materials Technology. Institute of Materials Research; Alemania. Suranaree University of Technology. Institute of Science, School of Chemistry; Tailandia
Fil: Jepsen, Julian. Materials Technology. Institute of Materials Research; Alemania
Fil: Jensen, Torben R.. University of Aarhu. Center for Energy Materials, iNANO and Department of Chemistry; Dinamarca
Fil: Gundlach, Carsten. Lund University. MAX-lab; Suiza
Fil: Bellosta von Colbe, José. Materials Technology. Institute of Materials Research; Alemania
Fil: Klassen, Thomas. Materials Technology. Institute of Materials Research; Alemania
Fil: Dornheim, Martin. Materials Technology. Institute of Materials Research; Alemania
Materia
Hydrogen Storage
Reversibility
Complex Hydride
Milling
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/18903
Acceder
id CONICETDig_47ef210679dcd442b9b4d288eb0ff508
oai_identifier_str oai:ri.conicet.gov.ar:11336/18903
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Sorption behavior of the MgH2-Mg2FeH6 hydride storage system synthesized by mechanical milling followed by sinteringPuszkiel, Julián AtilioGennari, Fabiana CristinaArneodo Larochette, Pierre PaulKarimi, FahimPistidda, ClaudioGosalawit Utke, RapeeJepsen, JulianJensen, Torben R.Gundlach, CarstenBellosta von Colbe, JoséKlassen, ThomasDornheim, MartinHydrogen StorageReversibilityComplex HydrideMillinghttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The hydrogen sorption behavior of the Mg2FeH6eMgH2hydride system is investigated via in-situ synchrotron and laboratory powder X-ray diffraction (SR-PXD), differential scanning calorimetry (DSC), scanning electron microscopy (SEM), particle size distribution (PSD) and volumetric techniques. The Mg2FeH6eMgH2 hydride system is obtained by mechanical milling in argon atmosphere followed by sintering at high temperature and hydrogen pressure. In-situ SR-PXD results show that upon hydriding MgH2 is a precursor for Mg2FeH6 formation and remained as hydrided phase in the obtained material. Diffusion constraints preclude the further formation of Mg2FeH6. Upon dehydriding, our results suggest that MgH2 and Mg2FeH6 decompose independently in a narrow temperature range between 275 and 300 C. Moreover, the decomposition behavior of both hydrides in the Mg2FeH6eMgH2 hydride mixture is influenced by each other via dual synergetic-destabilizing effects. The final hydriding/dehydriding products and therefore the kinetic behavior of the Mg2FeH6eMgH2 hydride system exhibits a strong dependence on the temperature and pressure conditions.Fil: Puszkiel, Julián Atilio. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; ArgentinaFil: Gennari, Fabiana Cristina. Comision Nacional de Energia Atomica. Gerencia de Area de Aplicaciones de la Tecnologia Nuclear. Gerencia de Investigacion Aplicada; . Universidad Nacional de Cuyo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Arneodo Larochette, Pierre Paul. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comision Nacional de Energia Atomica. Gerencia de Area de Aplicaciones de la Tecnologia Nuclear. Gerencia de Investigacion Aplicada; . Universidad Nacional de Cuyo; ArgentinaFil: Karimi, Fahim. Materials Technology. Institute of Materials Research; AlemaniaFil: Pistidda, Claudio. Materials Technology. Institute of Materials Research; AlemaniaFil: Gosalawit Utke, Rapee. Materials Technology. Institute of Materials Research; Alemania. Suranaree University of Technology. Institute of Science, School of Chemistry; TailandiaFil: Jepsen, Julian. Materials Technology. Institute of Materials Research; AlemaniaFil: Jensen, Torben R.. University of Aarhu. Center for Energy Materials, iNANO and Department of Chemistry; DinamarcaFil: Gundlach, Carsten. Lund University. MAX-lab; SuizaFil: Bellosta von Colbe, José. Materials Technology. Institute of Materials Research; AlemaniaFil: Klassen, Thomas. Materials Technology. Institute of Materials Research; AlemaniaFil: Dornheim, Martin. Materials Technology. Institute of Materials Research; AlemaniaElsevier2013-11-13info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/18903Puszkiel, Julián Atilio; Gennari, Fabiana Cristina; Arneodo Larochette, Pierre Paul; Karimi, Fahim; Pistidda, Claudio; et al.; Sorption behavior of the MgH2-Mg2FeH6 hydride storage system synthesized by mechanical milling followed by sintering; Elsevier; International Journal Of Hydrogen Energy; 38; 34; 13-11-2013; 14618-146300360-3199enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2013.08.068info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0360319913020442info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:49:56Zoai:ri.conicet.gov.ar:11336/18903instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:49:56.606CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Sorption behavior of the MgH2-Mg2FeH6 hydride storage system synthesized by mechanical milling followed by sintering
title Sorption behavior of the MgH2-Mg2FeH6 hydride storage system synthesized by mechanical milling followed by sintering
spellingShingle Sorption behavior of the MgH2-Mg2FeH6 hydride storage system synthesized by mechanical milling followed by sintering
Puszkiel, Julián Atilio
Hydrogen Storage
Reversibility
Complex Hydride
Milling
title_short Sorption behavior of the MgH2-Mg2FeH6 hydride storage system synthesized by mechanical milling followed by sintering
title_full Sorption behavior of the MgH2-Mg2FeH6 hydride storage system synthesized by mechanical milling followed by sintering
title_fullStr Sorption behavior of the MgH2-Mg2FeH6 hydride storage system synthesized by mechanical milling followed by sintering
title_full_unstemmed Sorption behavior of the MgH2-Mg2FeH6 hydride storage system synthesized by mechanical milling followed by sintering
title_sort Sorption behavior of the MgH2-Mg2FeH6 hydride storage system synthesized by mechanical milling followed by sintering
dc.creator.none.fl_str_mv Puszkiel, Julián Atilio
Gennari, Fabiana Cristina
Arneodo Larochette, Pierre Paul
Karimi, Fahim
Pistidda, Claudio
Gosalawit Utke, Rapee
Jepsen, Julian
Jensen, Torben R.
Gundlach, Carsten
Bellosta von Colbe, José
Klassen, Thomas
Dornheim, Martin
author Puszkiel, Julián Atilio
author_facet Puszkiel, Julián Atilio
Gennari, Fabiana Cristina
Arneodo Larochette, Pierre Paul
Karimi, Fahim
Pistidda, Claudio
Gosalawit Utke, Rapee
Jepsen, Julian
Jensen, Torben R.
Gundlach, Carsten
Bellosta von Colbe, José
Klassen, Thomas
Dornheim, Martin
author_role author
author2 Gennari, Fabiana Cristina
Arneodo Larochette, Pierre Paul
Karimi, Fahim
Pistidda, Claudio
Gosalawit Utke, Rapee
Jepsen, Julian
Jensen, Torben R.
Gundlach, Carsten
Bellosta von Colbe, José
Klassen, Thomas
Dornheim, Martin
author2_role author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Hydrogen Storage
Reversibility
Complex Hydride
Milling
topic Hydrogen Storage
Reversibility
Complex Hydride
Milling
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The hydrogen sorption behavior of the Mg2FeH6eMgH2hydride system is investigated via in-situ synchrotron and laboratory powder X-ray diffraction (SR-PXD), differential scanning calorimetry (DSC), scanning electron microscopy (SEM), particle size distribution (PSD) and volumetric techniques. The Mg2FeH6eMgH2 hydride system is obtained by mechanical milling in argon atmosphere followed by sintering at high temperature and hydrogen pressure. In-situ SR-PXD results show that upon hydriding MgH2 is a precursor for Mg2FeH6 formation and remained as hydrided phase in the obtained material. Diffusion constraints preclude the further formation of Mg2FeH6. Upon dehydriding, our results suggest that MgH2 and Mg2FeH6 decompose independently in a narrow temperature range between 275 and 300 C. Moreover, the decomposition behavior of both hydrides in the Mg2FeH6eMgH2 hydride mixture is influenced by each other via dual synergetic-destabilizing effects. The final hydriding/dehydriding products and therefore the kinetic behavior of the Mg2FeH6eMgH2 hydride system exhibits a strong dependence on the temperature and pressure conditions.
Fil: Puszkiel, Julián Atilio. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; Argentina
Fil: Gennari, Fabiana Cristina. Comision Nacional de Energia Atomica. Gerencia de Area de Aplicaciones de la Tecnologia Nuclear. Gerencia de Investigacion Aplicada; . Universidad Nacional de Cuyo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Arneodo Larochette, Pierre Paul. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comision Nacional de Energia Atomica. Gerencia de Area de Aplicaciones de la Tecnologia Nuclear. Gerencia de Investigacion Aplicada; . Universidad Nacional de Cuyo; Argentina
Fil: Karimi, Fahim. Materials Technology. Institute of Materials Research; Alemania
Fil: Pistidda, Claudio. Materials Technology. Institute of Materials Research; Alemania
Fil: Gosalawit Utke, Rapee. Materials Technology. Institute of Materials Research; Alemania. Suranaree University of Technology. Institute of Science, School of Chemistry; Tailandia
Fil: Jepsen, Julian. Materials Technology. Institute of Materials Research; Alemania
Fil: Jensen, Torben R.. University of Aarhu. Center for Energy Materials, iNANO and Department of Chemistry; Dinamarca
Fil: Gundlach, Carsten. Lund University. MAX-lab; Suiza
Fil: Bellosta von Colbe, José. Materials Technology. Institute of Materials Research; Alemania
Fil: Klassen, Thomas. Materials Technology. Institute of Materials Research; Alemania
Fil: Dornheim, Martin. Materials Technology. Institute of Materials Research; Alemania
description The hydrogen sorption behavior of the Mg2FeH6eMgH2hydride system is investigated via in-situ synchrotron and laboratory powder X-ray diffraction (SR-PXD), differential scanning calorimetry (DSC), scanning electron microscopy (SEM), particle size distribution (PSD) and volumetric techniques. The Mg2FeH6eMgH2 hydride system is obtained by mechanical milling in argon atmosphere followed by sintering at high temperature and hydrogen pressure. In-situ SR-PXD results show that upon hydriding MgH2 is a precursor for Mg2FeH6 formation and remained as hydrided phase in the obtained material. Diffusion constraints preclude the further formation of Mg2FeH6. Upon dehydriding, our results suggest that MgH2 and Mg2FeH6 decompose independently in a narrow temperature range between 275 and 300 C. Moreover, the decomposition behavior of both hydrides in the Mg2FeH6eMgH2 hydride mixture is influenced by each other via dual synergetic-destabilizing effects. The final hydriding/dehydriding products and therefore the kinetic behavior of the Mg2FeH6eMgH2 hydride system exhibits a strong dependence on the temperature and pressure conditions.
publishDate 2013
dc.date.none.fl_str_mv 2013-11-13
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/18903
Puszkiel, Julián Atilio; Gennari, Fabiana Cristina; Arneodo Larochette, Pierre Paul; Karimi, Fahim; Pistidda, Claudio; et al.; Sorption behavior of the MgH2-Mg2FeH6 hydride storage system synthesized by mechanical milling followed by sintering; Elsevier; International Journal Of Hydrogen Energy; 38; 34; 13-11-2013; 14618-14630
0360-3199
url http://hdl.handle.net/11336/18903
identifier_str_mv Puszkiel, Julián Atilio; Gennari, Fabiana Cristina; Arneodo Larochette, Pierre Paul; Karimi, Fahim; Pistidda, Claudio; et al.; Sorption behavior of the MgH2-Mg2FeH6 hydride storage system synthesized by mechanical milling followed by sintering; Elsevier; International Journal Of Hydrogen Energy; 38; 34; 13-11-2013; 14618-14630
0360-3199
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2013.08.068
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0360319913020442
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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