Ultrasound leaching - dispersive liquid-liquid microextraction based on solidification of floating organic droplet for determination of polybrominated diphenyl ethers in sediment s...

Autores
Lana, Nerina Belén; Berton, Paula; Covaci, Adrian; Atencio, Adrian Gonzalo; Ciocco, Nestor Fernando; Altamirano, Jorgelina Cecilia
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Ultrasound leaching–dispersive liquid–liquid microextraction using solidification of floating organic droplet (USL–DLLME-SFO) technique is proposed for extraction and isolation of polybrominated diphenyl ethers (PBDEs) from sediment and further determination by gas chromatography–tandem mass spectrometry (GC–MS/MS). Parameters that affect the efficiency of the procedure were investigated by a full factorial (2k) screening design. Variables showing significant effects on the analytical responses were considered within a further central composite design (CCD). The optimization assays have led to following protocol: ultrasound assisted lixiviation of 1 g sediment was carried out by using 1.2 mL MeOH. Further, the analytes were isolated from 0.4 mL of the extract using the DLLME-SFO technique. The microextraction was performed using 0.1 mL MeOH, 22 mg 1-dodecanol, 1 mL NaCl solution 6.15 M and 4.4 mL ultrapure water as dispersive and extracting solvents, medium ionic strength and dispersant bulk, respectively. Under optimum conditions, the method exhibits good performance in terms of linearity and precision (RSD < 9.2%), with recoveries above 71% and limits of detection (LODs) within the range 0.5–1.8 pg g-1 dry weight (d.w.). Method validation was demonstrated through the analysis of environmental sediment samples in which PBDEs were detected and quantified. The presence of BDE-47, -100, -99 and -153 was reported within the concentration range of Fil: Lana, Nerina Belén. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Científico Tecnológico Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales; Argentina
Fil: Berton, Paula. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales. Laboratorio de Química Analítica para Investigación y Desarrollo; Argentina
Fil: Covaci, Adrian. Universiteitsplein. University of Antwerp. Toxicological Centre; Bélgica
Fil: Atencio, Adrian Gonzalo. Ministerio de Relaciones Exteriores, Comercio Interno y Culto. Dirección Nacional del Antártico. Instituto Antártico Argentino; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mendoza; Argentina
Fil: Ciocco, Nestor Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mendoza. Instituto Argentino de Investigaciones de Zonas Aridas; Argentina. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Altamirano, Jorgelina Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Científico Tecnológico Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales; Argentina. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; Argentina
Materia
Polybrominated Diphenyl Ethers
Microextraction By Solidification of Floating Organic Droplet
Sediment
Gas Chromatography-Mass Spectrometry
Dispersive Liquid-Liquid Microextraction
Experimental Desing
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5746
Acceder
id CONICETDig_4700f3f810e854cdb1f9a6cf2ee7e5e5
oai_identifier_str oai:ri.conicet.gov.ar:11336/5746
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Ultrasound leaching - dispersive liquid-liquid microextraction based on solidification of floating organic droplet for determination of polybrominated diphenyl ethers in sediment samples by gas chromatography-tandem mass spectrometryLana, Nerina BelénBerton, PaulaCovaci, AdrianAtencio, Adrian GonzaloCiocco, Nestor FernandoAltamirano, Jorgelina CeciliaPolybrominated Diphenyl EthersMicroextraction By Solidification of Floating Organic DropletSedimentGas Chromatography-Mass SpectrometryDispersive Liquid-Liquid MicroextractionExperimental Desinghttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Ultrasound leaching–dispersive liquid–liquid microextraction using solidification of floating organic droplet (USL–DLLME-SFO) technique is proposed for extraction and isolation of polybrominated diphenyl ethers (PBDEs) from sediment and further determination by gas chromatography–tandem mass spectrometry (GC–MS/MS). Parameters that affect the efficiency of the procedure were investigated by a full factorial (2k) screening design. Variables showing significant effects on the analytical responses were considered within a further central composite design (CCD). The optimization assays have led to following protocol: ultrasound assisted lixiviation of 1 g sediment was carried out by using 1.2 mL MeOH. Further, the analytes were isolated from 0.4 mL of the extract using the DLLME-SFO technique. The microextraction was performed using 0.1 mL MeOH, 22 mg 1-dodecanol, 1 mL NaCl solution 6.15 M and 4.4 mL ultrapure water as dispersive and extracting solvents, medium ionic strength and dispersant bulk, respectively. Under optimum conditions, the method exhibits good performance in terms of linearity and precision (RSD < 9.2%), with recoveries above 71% and limits of detection (LODs) within the range 0.5–1.8 pg g-1 dry weight (d.w.). Method validation was demonstrated through the analysis of environmental sediment samples in which PBDEs were detected and quantified. The presence of BDE-47, -100, -99 and -153 was reported within the concentration range of <LOD to 29 pg g-1 d.w. The proposed methodology constitutes a suitable approach for the analysis of PBDEs in complex solid samples requires minimum organic solvents consumption, sample manipulation, and increases sample throughput.Fil: Lana, Nerina Belén. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Científico Tecnológico Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales; ArgentinaFil: Berton, Paula. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales. Laboratorio de Química Analítica para Investigación y Desarrollo; ArgentinaFil: Covaci, Adrian. Universiteitsplein. University of Antwerp. Toxicological Centre; BélgicaFil: Atencio, Adrian Gonzalo. Ministerio de Relaciones Exteriores, Comercio Interno y Culto. Dirección Nacional del Antártico. Instituto Antártico Argentino; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mendoza; ArgentinaFil: Ciocco, Nestor Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mendoza. Instituto Argentino de Investigaciones de Zonas Aridas; Argentina. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; ArgentinaFil: Altamirano, Jorgelina Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Científico Tecnológico Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales; Argentina. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; ArgentinaElsevier2013-02-16info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5746Lana, Nerina Belén; Berton, Paula; Covaci, Adrian; Atencio, Adrian Gonzalo; Ciocco, Nestor Fernando; et al.; Ultrasound leaching - dispersive liquid-liquid microextraction based on solidification of floating organic droplet for determination of polybrominated diphenyl ethers in sediment samples by gas chromatography-tandem mass spectrometry; Elsevier; Journal Of Chromatography - A; 1285; 16-2-2013; 15-210021-9673enginfo:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0021967313003166info:eu-repo/semantics/altIdentifier/doi/10.1016/j.chroma.2013.02.027info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:22:56Zoai:ri.conicet.gov.ar:11336/5746instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:22:56.295CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Ultrasound leaching - dispersive liquid-liquid microextraction based on solidification of floating organic droplet for determination of polybrominated diphenyl ethers in sediment samples by gas chromatography-tandem mass spectrometry
title Ultrasound leaching - dispersive liquid-liquid microextraction based on solidification of floating organic droplet for determination of polybrominated diphenyl ethers in sediment samples by gas chromatography-tandem mass spectrometry
spellingShingle Ultrasound leaching - dispersive liquid-liquid microextraction based on solidification of floating organic droplet for determination of polybrominated diphenyl ethers in sediment samples by gas chromatography-tandem mass spectrometry
Lana, Nerina Belén
Polybrominated Diphenyl Ethers
Microextraction By Solidification of Floating Organic Droplet
Sediment
Gas Chromatography-Mass Spectrometry
Dispersive Liquid-Liquid Microextraction
Experimental Desing
title_short Ultrasound leaching - dispersive liquid-liquid microextraction based on solidification of floating organic droplet for determination of polybrominated diphenyl ethers in sediment samples by gas chromatography-tandem mass spectrometry
title_full Ultrasound leaching - dispersive liquid-liquid microextraction based on solidification of floating organic droplet for determination of polybrominated diphenyl ethers in sediment samples by gas chromatography-tandem mass spectrometry
title_fullStr Ultrasound leaching - dispersive liquid-liquid microextraction based on solidification of floating organic droplet for determination of polybrominated diphenyl ethers in sediment samples by gas chromatography-tandem mass spectrometry
title_full_unstemmed Ultrasound leaching - dispersive liquid-liquid microextraction based on solidification of floating organic droplet for determination of polybrominated diphenyl ethers in sediment samples by gas chromatography-tandem mass spectrometry
title_sort Ultrasound leaching - dispersive liquid-liquid microextraction based on solidification of floating organic droplet for determination of polybrominated diphenyl ethers in sediment samples by gas chromatography-tandem mass spectrometry
dc.creator.none.fl_str_mv Lana, Nerina Belén
Berton, Paula
Covaci, Adrian
Atencio, Adrian Gonzalo
Ciocco, Nestor Fernando
Altamirano, Jorgelina Cecilia
author Lana, Nerina Belén
author_facet Lana, Nerina Belén
Berton, Paula
Covaci, Adrian
Atencio, Adrian Gonzalo
Ciocco, Nestor Fernando
Altamirano, Jorgelina Cecilia
author_role author
author2 Berton, Paula
Covaci, Adrian
Atencio, Adrian Gonzalo
Ciocco, Nestor Fernando
Altamirano, Jorgelina Cecilia
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Polybrominated Diphenyl Ethers
Microextraction By Solidification of Floating Organic Droplet
Sediment
Gas Chromatography-Mass Spectrometry
Dispersive Liquid-Liquid Microextraction
Experimental Desing
topic Polybrominated Diphenyl Ethers
Microextraction By Solidification of Floating Organic Droplet
Sediment
Gas Chromatography-Mass Spectrometry
Dispersive Liquid-Liquid Microextraction
Experimental Desing
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Ultrasound leaching–dispersive liquid–liquid microextraction using solidification of floating organic droplet (USL–DLLME-SFO) technique is proposed for extraction and isolation of polybrominated diphenyl ethers (PBDEs) from sediment and further determination by gas chromatography–tandem mass spectrometry (GC–MS/MS). Parameters that affect the efficiency of the procedure were investigated by a full factorial (2k) screening design. Variables showing significant effects on the analytical responses were considered within a further central composite design (CCD). The optimization assays have led to following protocol: ultrasound assisted lixiviation of 1 g sediment was carried out by using 1.2 mL MeOH. Further, the analytes were isolated from 0.4 mL of the extract using the DLLME-SFO technique. The microextraction was performed using 0.1 mL MeOH, 22 mg 1-dodecanol, 1 mL NaCl solution 6.15 M and 4.4 mL ultrapure water as dispersive and extracting solvents, medium ionic strength and dispersant bulk, respectively. Under optimum conditions, the method exhibits good performance in terms of linearity and precision (RSD < 9.2%), with recoveries above 71% and limits of detection (LODs) within the range 0.5–1.8 pg g-1 dry weight (d.w.). Method validation was demonstrated through the analysis of environmental sediment samples in which PBDEs were detected and quantified. The presence of BDE-47, -100, -99 and -153 was reported within the concentration range of <LOD to 29 pg g-1 d.w. The proposed methodology constitutes a suitable approach for the analysis of PBDEs in complex solid samples requires minimum organic solvents consumption, sample manipulation, and increases sample throughput.
Fil: Lana, Nerina Belén. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Científico Tecnológico Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales; Argentina
Fil: Berton, Paula. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales. Laboratorio de Química Analítica para Investigación y Desarrollo; Argentina
Fil: Covaci, Adrian. Universiteitsplein. University of Antwerp. Toxicological Centre; Bélgica
Fil: Atencio, Adrian Gonzalo. Ministerio de Relaciones Exteriores, Comercio Interno y Culto. Dirección Nacional del Antártico. Instituto Antártico Argentino; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mendoza; Argentina
Fil: Ciocco, Nestor Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mendoza. Instituto Argentino de Investigaciones de Zonas Aridas; Argentina. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Altamirano, Jorgelina Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Científico Tecnológico Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales; Argentina. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; Argentina
description Ultrasound leaching–dispersive liquid–liquid microextraction using solidification of floating organic droplet (USL–DLLME-SFO) technique is proposed for extraction and isolation of polybrominated diphenyl ethers (PBDEs) from sediment and further determination by gas chromatography–tandem mass spectrometry (GC–MS/MS). Parameters that affect the efficiency of the procedure were investigated by a full factorial (2k) screening design. Variables showing significant effects on the analytical responses were considered within a further central composite design (CCD). The optimization assays have led to following protocol: ultrasound assisted lixiviation of 1 g sediment was carried out by using 1.2 mL MeOH. Further, the analytes were isolated from 0.4 mL of the extract using the DLLME-SFO technique. The microextraction was performed using 0.1 mL MeOH, 22 mg 1-dodecanol, 1 mL NaCl solution 6.15 M and 4.4 mL ultrapure water as dispersive and extracting solvents, medium ionic strength and dispersant bulk, respectively. Under optimum conditions, the method exhibits good performance in terms of linearity and precision (RSD < 9.2%), with recoveries above 71% and limits of detection (LODs) within the range 0.5–1.8 pg g-1 dry weight (d.w.). Method validation was demonstrated through the analysis of environmental sediment samples in which PBDEs were detected and quantified. The presence of BDE-47, -100, -99 and -153 was reported within the concentration range of <LOD to 29 pg g-1 d.w. The proposed methodology constitutes a suitable approach for the analysis of PBDEs in complex solid samples requires minimum organic solvents consumption, sample manipulation, and increases sample throughput.
publishDate 2013
dc.date.none.fl_str_mv 2013-02-16
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5746
Lana, Nerina Belén; Berton, Paula; Covaci, Adrian; Atencio, Adrian Gonzalo; Ciocco, Nestor Fernando; et al.; Ultrasound leaching - dispersive liquid-liquid microextraction based on solidification of floating organic droplet for determination of polybrominated diphenyl ethers in sediment samples by gas chromatography-tandem mass spectrometry; Elsevier; Journal Of Chromatography - A; 1285; 16-2-2013; 15-21
0021-9673
url http://hdl.handle.net/11336/5746
identifier_str_mv Lana, Nerina Belén; Berton, Paula; Covaci, Adrian; Atencio, Adrian Gonzalo; Ciocco, Nestor Fernando; et al.; Ultrasound leaching - dispersive liquid-liquid microextraction based on solidification of floating organic droplet for determination of polybrominated diphenyl ethers in sediment samples by gas chromatography-tandem mass spectrometry; Elsevier; Journal Of Chromatography - A; 1285; 16-2-2013; 15-21
0021-9673
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0021967313003166
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.chroma.2013.02.027
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.48226

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