Plasmon enhanced light absorption in aluminium@Hematite core shell hybrid nanocylinders: the critical role of length

Autores
Encina, Ezequiel Roberto; Passarelli, Nicolás; Coronado, Eduardo A.
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The light absorption as well as the near field enhancements properties of Al@α-Fe2O3 core shell hybrid nanocylinders (HNs) have been systematically studied by means of Discrete Dipole Approximation simulations. The Al@α-Fe2O3 HNs consist of a right circular cylinder Al core, wrapped by a circular section of an α-Fe2O3 shell, both having the same finite length L. A general and useful methodology has been implemented to assess separately the partial contributions to the absorption spectrum of each component of the Al@α-Fe2O3 HN. The employed methodology can be applied not only to those HNs studied here but also to any other nanostructure with arbitrary geometry and several components providing relevant information not accessible through standard spectroscopic techniques. The absorption spectra have been employed to calculate the absorbed photon flux ϕ within the α-Fe2O3 shell. According to the HN size, plasmon enhanced light absorption in the α-Fe2O3 shell of the Al@α-Fe2O3 HNs is evidenced, which is attributed to a plasmon-induced energy transfer mechanism based on near field enhancements. The effect of the HN length on the absorbed photon flux ϕ is an important issue that has not been addressed yet, as only infinitely long HN has been considered in previous studies. It is demonstrated that the HN length L has a crucial influence on the absorbed photon flux ϕ, as it is the main structural parameter that allows us to tune the dipole plasmon resonance of the Al core into the visible region. Furthermore, it is shown that Al cores lead to larger ϕ values than the typical plasmonic metals Ag and Au. The results presented in this work point out that the HN length should be explicitly taken into account for an optimum design of core shell hybrid cylindrical nanostructures with enhanced or improved photoactive properties.
Fil: Encina, Ezequiel Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Passarelli, Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Coronado, Eduardo A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
HYBRID NANOSTRUCTURES
PLASMONIC
LIGHT ABSORPTION
IRON OXIDES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/62322
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/62322
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Plasmon enhanced light absorption in aluminium@Hematite core shell hybrid nanocylinders: the critical role of lengthEncina, Ezequiel RobertoPassarelli, NicolásCoronado, Eduardo A.HYBRID NANOSTRUCTURESPLASMONICLIGHT ABSORPTIONIRON OXIDEShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The light absorption as well as the near field enhancements properties of Al@α-Fe2O3 core shell hybrid nanocylinders (HNs) have been systematically studied by means of Discrete Dipole Approximation simulations. The Al@α-Fe2O3 HNs consist of a right circular cylinder Al core, wrapped by a circular section of an α-Fe2O3 shell, both having the same finite length L. A general and useful methodology has been implemented to assess separately the partial contributions to the absorption spectrum of each component of the Al@α-Fe2O3 HN. The employed methodology can be applied not only to those HNs studied here but also to any other nanostructure with arbitrary geometry and several components providing relevant information not accessible through standard spectroscopic techniques. The absorption spectra have been employed to calculate the absorbed photon flux ϕ within the α-Fe2O3 shell. According to the HN size, plasmon enhanced light absorption in the α-Fe2O3 shell of the Al@α-Fe2O3 HNs is evidenced, which is attributed to a plasmon-induced energy transfer mechanism based on near field enhancements. The effect of the HN length on the absorbed photon flux ϕ is an important issue that has not been addressed yet, as only infinitely long HN has been considered in previous studies. It is demonstrated that the HN length L has a crucial influence on the absorbed photon flux ϕ, as it is the main structural parameter that allows us to tune the dipole plasmon resonance of the Al core into the visible region. Furthermore, it is shown that Al cores lead to larger ϕ values than the typical plasmonic metals Ag and Au. The results presented in this work point out that the HN length should be explicitly taken into account for an optimum design of core shell hybrid cylindrical nanostructures with enhanced or improved photoactive properties.Fil: Encina, Ezequiel Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Passarelli, Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Coronado, Eduardo A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaRoyal Society of Chemistry2017-01-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/62322Encina, Ezequiel Roberto; Passarelli, Nicolás; Coronado, Eduardo A.; Plasmon enhanced light absorption in aluminium@Hematite core shell hybrid nanocylinders: the critical role of length; Royal Society of Chemistry; RSC Advances; 7; 5; 12-1-2017; 2857-28682046-20692046-2069CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/Content/ArticleLanding/2017/RA/C6RA27594Jinfo:eu-repo/semantics/altIdentifier/doi/10.1039/c6ra27594jinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T12:16:45Zoai:ri.conicet.gov.ar:11336/62322instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 12:16:46.086CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Plasmon enhanced light absorption in aluminium@Hematite core shell hybrid nanocylinders: the critical role of length
title Plasmon enhanced light absorption in aluminium@Hematite core shell hybrid nanocylinders: the critical role of length
spellingShingle Plasmon enhanced light absorption in aluminium@Hematite core shell hybrid nanocylinders: the critical role of length
Encina, Ezequiel Roberto
HYBRID NANOSTRUCTURES
PLASMONIC
LIGHT ABSORPTION
IRON OXIDES
title_short Plasmon enhanced light absorption in aluminium@Hematite core shell hybrid nanocylinders: the critical role of length
title_full Plasmon enhanced light absorption in aluminium@Hematite core shell hybrid nanocylinders: the critical role of length
title_fullStr Plasmon enhanced light absorption in aluminium@Hematite core shell hybrid nanocylinders: the critical role of length
title_full_unstemmed Plasmon enhanced light absorption in aluminium@Hematite core shell hybrid nanocylinders: the critical role of length
title_sort Plasmon enhanced light absorption in aluminium@Hematite core shell hybrid nanocylinders: the critical role of length
dc.creator.none.fl_str_mv Encina, Ezequiel Roberto
Passarelli, Nicolás
Coronado, Eduardo A.
author Encina, Ezequiel Roberto
author_facet Encina, Ezequiel Roberto
Passarelli, Nicolás
Coronado, Eduardo A.
author_role author
author2 Passarelli, Nicolás
Coronado, Eduardo A.
author2_role author
author
dc.subject.none.fl_str_mv HYBRID NANOSTRUCTURES
PLASMONIC
LIGHT ABSORPTION
IRON OXIDES
topic HYBRID NANOSTRUCTURES
PLASMONIC
LIGHT ABSORPTION
IRON OXIDES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The light absorption as well as the near field enhancements properties of Al@α-Fe2O3 core shell hybrid nanocylinders (HNs) have been systematically studied by means of Discrete Dipole Approximation simulations. The Al@α-Fe2O3 HNs consist of a right circular cylinder Al core, wrapped by a circular section of an α-Fe2O3 shell, both having the same finite length L. A general and useful methodology has been implemented to assess separately the partial contributions to the absorption spectrum of each component of the Al@α-Fe2O3 HN. The employed methodology can be applied not only to those HNs studied here but also to any other nanostructure with arbitrary geometry and several components providing relevant information not accessible through standard spectroscopic techniques. The absorption spectra have been employed to calculate the absorbed photon flux ϕ within the α-Fe2O3 shell. According to the HN size, plasmon enhanced light absorption in the α-Fe2O3 shell of the Al@α-Fe2O3 HNs is evidenced, which is attributed to a plasmon-induced energy transfer mechanism based on near field enhancements. The effect of the HN length on the absorbed photon flux ϕ is an important issue that has not been addressed yet, as only infinitely long HN has been considered in previous studies. It is demonstrated that the HN length L has a crucial influence on the absorbed photon flux ϕ, as it is the main structural parameter that allows us to tune the dipole plasmon resonance of the Al core into the visible region. Furthermore, it is shown that Al cores lead to larger ϕ values than the typical plasmonic metals Ag and Au. The results presented in this work point out that the HN length should be explicitly taken into account for an optimum design of core shell hybrid cylindrical nanostructures with enhanced or improved photoactive properties.
Fil: Encina, Ezequiel Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Passarelli, Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Coronado, Eduardo A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description The light absorption as well as the near field enhancements properties of Al@α-Fe2O3 core shell hybrid nanocylinders (HNs) have been systematically studied by means of Discrete Dipole Approximation simulations. The Al@α-Fe2O3 HNs consist of a right circular cylinder Al core, wrapped by a circular section of an α-Fe2O3 shell, both having the same finite length L. A general and useful methodology has been implemented to assess separately the partial contributions to the absorption spectrum of each component of the Al@α-Fe2O3 HN. The employed methodology can be applied not only to those HNs studied here but also to any other nanostructure with arbitrary geometry and several components providing relevant information not accessible through standard spectroscopic techniques. The absorption spectra have been employed to calculate the absorbed photon flux ϕ within the α-Fe2O3 shell. According to the HN size, plasmon enhanced light absorption in the α-Fe2O3 shell of the Al@α-Fe2O3 HNs is evidenced, which is attributed to a plasmon-induced energy transfer mechanism based on near field enhancements. The effect of the HN length on the absorbed photon flux ϕ is an important issue that has not been addressed yet, as only infinitely long HN has been considered in previous studies. It is demonstrated that the HN length L has a crucial influence on the absorbed photon flux ϕ, as it is the main structural parameter that allows us to tune the dipole plasmon resonance of the Al core into the visible region. Furthermore, it is shown that Al cores lead to larger ϕ values than the typical plasmonic metals Ag and Au. The results presented in this work point out that the HN length should be explicitly taken into account for an optimum design of core shell hybrid cylindrical nanostructures with enhanced or improved photoactive properties.
publishDate 2017
dc.date.none.fl_str_mv 2017-01-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/62322
Encina, Ezequiel Roberto; Passarelli, Nicolás; Coronado, Eduardo A.; Plasmon enhanced light absorption in aluminium@Hematite core shell hybrid nanocylinders: the critical role of length; Royal Society of Chemistry; RSC Advances; 7; 5; 12-1-2017; 2857-2868
2046-2069
2046-2069
CONICET Digital
CONICET
url http://hdl.handle.net/11336/62322
identifier_str_mv Encina, Ezequiel Roberto; Passarelli, Nicolás; Coronado, Eduardo A.; Plasmon enhanced light absorption in aluminium@Hematite core shell hybrid nanocylinders: the critical role of length; Royal Society of Chemistry; RSC Advances; 7; 5; 12-1-2017; 2857-2868
2046-2069
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/Content/ArticleLanding/2017/RA/C6RA27594J
info:eu-repo/semantics/altIdentifier/doi/10.1039/c6ra27594j
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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