Advances in the study of supercooled water

Autores
Gallo, Paola Vanesa; Bachler, Johannes; Bove, Livia Eleonora; Böhmer, Roland; Camisasca, Gaia; Coronas, Luis Enrique; Corti, Horacio Roberto; de Almeida Ribeiro, Ingrid; de Koning Maurice; Franzese, Giancarlo; Fuentes Landete, Violeta; Gainaru, Catalin; Loerting, Thomas; Montes de Oca, Joan Manuel; Poole, Peter; Rovere, Mauro; Sciortino, Francesco; Tonauer, María Christina; Appignanesi, Gustavo Adrian
Año de publicación
2021
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this review, we report recent progress in the field of supercooled water. Due to its uniqueness, water presents numerous anomalies with respect to most simple liquids, showing polyamorphism both in the liquid and in the glassy state. We first describe the thermodynamic scenarios hypothesized for the supercooled region and in particular among them the liquid–liquid critical point scenario that has so far received more experimental evidence. We then review the most recent structural indicators, the two-state model picture of water, and the importance of cooperative effects related to the fact that water is a hydrogen-bonded network liquid. We show throughout the review that water’s peculiar properties come into play also when water is in solution, confined, and close to biological molecules. Concerning dynamics, upon mild supercooling water behaves as a fragile glass former following the mode coupling theory, and it turns into a strong glass former upon further cooling. Connections between the slow dynamics and the thermodynamics are discussed. The translational relaxation times of density fluctuations show in fact the fragile-to-strong crossover connected to the thermodynamics arising from the existence of two liquids. When considering also rotations, additional crossovers come to play. Mobility–viscosity decoupling is also discussed in supercooled water and aqueous solutions. Finally, the polyamorphism of glassy water is considered through experimental and simulation results both in bulk and in salty aqueous solutions. Grains and grain boundaries are also discussed.
Fil: Gallo, Paola Vanesa. Università Roma Tre III; Italia
Fil: Bachler, Johannes. Universidad de Innsbruck; Austria
Fil: Bove, Livia Eleonora. Università degli studi di Roma "La Sapienza"; Italia. Université Pierre et Marie Curie; Francia
Fil: Böhmer, Roland. Universität Dortmund; Alemania
Fil: Camisasca, Gaia. Università Roma Tre III; Italia
Fil: Coronas, Luis Enrique. Universidad de Barcelona; España
Fil: Corti, Horacio Roberto. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: de Almeida Ribeiro, Ingrid. Universidade Estadual de Campinas; Brasil
Fil: de Koning Maurice. Universidade Estadual de Campinas; Brasil
Fil: Franzese, Giancarlo. Universidad de Barcelona; España
Fil: Fuentes Landete, Violeta. Universidad de Innsbruck; Austria
Fil: Gainaru, Catalin. Universität Dortmund; Alemania
Fil: Loerting, Thomas. Universidad de Innsbruck; Austria
Fil: Montes de Oca, Joan Manuel. University of Chicago; Estados Unidos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Poole, Peter. Saint Francis Xavier University; Canadá
Fil: Rovere, Mauro. Università Roma Tre III; Italia
Fil: Sciortino, Francesco. Università di Roma; Italia
Fil: Tonauer, María Christina. Universidad de Innsbruck; Austria
Fil: Appignanesi, Gustavo Adrian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Materia
water
supercooled
structure
dynamics
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/169418
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Advances in the study of supercooled waterGallo, Paola VanesaBachler, JohannesBove, Livia EleonoraBöhmer, RolandCamisasca, GaiaCoronas, Luis EnriqueCorti, Horacio Robertode Almeida Ribeiro, Ingridde Koning MauriceFranzese, GiancarloFuentes Landete, VioletaGainaru, CatalinLoerting, ThomasMontes de Oca, Joan ManuelPoole, PeterRovere, MauroSciortino, FrancescoTonauer, María ChristinaAppignanesi, Gustavo Adrianwatersupercooledstructuredynamicshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this review, we report recent progress in the field of supercooled water. Due to its uniqueness, water presents numerous anomalies with respect to most simple liquids, showing polyamorphism both in the liquid and in the glassy state. We first describe the thermodynamic scenarios hypothesized for the supercooled region and in particular among them the liquid–liquid critical point scenario that has so far received more experimental evidence. We then review the most recent structural indicators, the two-state model picture of water, and the importance of cooperative effects related to the fact that water is a hydrogen-bonded network liquid. We show throughout the review that water’s peculiar properties come into play also when water is in solution, confined, and close to biological molecules. Concerning dynamics, upon mild supercooling water behaves as a fragile glass former following the mode coupling theory, and it turns into a strong glass former upon further cooling. Connections between the slow dynamics and the thermodynamics are discussed. The translational relaxation times of density fluctuations show in fact the fragile-to-strong crossover connected to the thermodynamics arising from the existence of two liquids. When considering also rotations, additional crossovers come to play. Mobility–viscosity decoupling is also discussed in supercooled water and aqueous solutions. Finally, the polyamorphism of glassy water is considered through experimental and simulation results both in bulk and in salty aqueous solutions. Grains and grain boundaries are also discussed.Fil: Gallo, Paola Vanesa. Università Roma Tre III; ItaliaFil: Bachler, Johannes. Universidad de Innsbruck; AustriaFil: Bove, Livia Eleonora. Università degli studi di Roma "La Sapienza"; Italia. Université Pierre et Marie Curie; FranciaFil: Böhmer, Roland. Universität Dortmund; AlemaniaFil: Camisasca, Gaia. Università Roma Tre III; ItaliaFil: Coronas, Luis Enrique. Universidad de Barcelona; EspañaFil: Corti, Horacio Roberto. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: de Almeida Ribeiro, Ingrid. Universidade Estadual de Campinas; BrasilFil: de Koning Maurice. Universidade Estadual de Campinas; BrasilFil: Franzese, Giancarlo. Universidad de Barcelona; EspañaFil: Fuentes Landete, Violeta. Universidad de Innsbruck; AustriaFil: Gainaru, Catalin. Universität Dortmund; AlemaniaFil: Loerting, Thomas. Universidad de Innsbruck; AustriaFil: Montes de Oca, Joan Manuel. University of Chicago; Estados Unidos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Poole, Peter. Saint Francis Xavier University; CanadáFil: Rovere, Mauro. Università Roma Tre III; ItaliaFil: Sciortino, Francesco. Università di Roma; ItaliaFil: Tonauer, María Christina. Universidad de Innsbruck; AustriaFil: Appignanesi, Gustavo Adrian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaSpringer2021-11-26info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/169418Gallo, Paola Vanesa; Bachler, Johannes; Bove, Livia Eleonora; Böhmer, Roland; Camisasca, Gaia; et al.; Advances in the study of supercooled water; Springer; European Physical Journal E; 44; 11; 26-11-2021; 1-361292-8941CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1140/epje/s10189-021-00139-1info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1140/epje/s10189-021-00139-1info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:18:55Zoai:ri.conicet.gov.ar:11336/169418instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:18:55.676CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Advances in the study of supercooled water
title Advances in the study of supercooled water
spellingShingle Advances in the study of supercooled water
Gallo, Paola Vanesa
water
supercooled
structure
dynamics
title_short Advances in the study of supercooled water
title_full Advances in the study of supercooled water
title_fullStr Advances in the study of supercooled water
title_full_unstemmed Advances in the study of supercooled water
title_sort Advances in the study of supercooled water
dc.creator.none.fl_str_mv Gallo, Paola Vanesa
Bachler, Johannes
Bove, Livia Eleonora
Böhmer, Roland
Camisasca, Gaia
Coronas, Luis Enrique
Corti, Horacio Roberto
de Almeida Ribeiro, Ingrid
de Koning Maurice
Franzese, Giancarlo
Fuentes Landete, Violeta
Gainaru, Catalin
Loerting, Thomas
Montes de Oca, Joan Manuel
Poole, Peter
Rovere, Mauro
Sciortino, Francesco
Tonauer, María Christina
Appignanesi, Gustavo Adrian
author Gallo, Paola Vanesa
author_facet Gallo, Paola Vanesa
Bachler, Johannes
Bove, Livia Eleonora
Böhmer, Roland
Camisasca, Gaia
Coronas, Luis Enrique
Corti, Horacio Roberto
de Almeida Ribeiro, Ingrid
de Koning Maurice
Franzese, Giancarlo
Fuentes Landete, Violeta
Gainaru, Catalin
Loerting, Thomas
Montes de Oca, Joan Manuel
Poole, Peter
Rovere, Mauro
Sciortino, Francesco
Tonauer, María Christina
Appignanesi, Gustavo Adrian
author_role author
author2 Bachler, Johannes
Bove, Livia Eleonora
Böhmer, Roland
Camisasca, Gaia
Coronas, Luis Enrique
Corti, Horacio Roberto
de Almeida Ribeiro, Ingrid
de Koning Maurice
Franzese, Giancarlo
Fuentes Landete, Violeta
Gainaru, Catalin
Loerting, Thomas
Montes de Oca, Joan Manuel
Poole, Peter
Rovere, Mauro
Sciortino, Francesco
Tonauer, María Christina
Appignanesi, Gustavo Adrian
author2_role author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv water
supercooled
structure
dynamics
topic water
supercooled
structure
dynamics
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this review, we report recent progress in the field of supercooled water. Due to its uniqueness, water presents numerous anomalies with respect to most simple liquids, showing polyamorphism both in the liquid and in the glassy state. We first describe the thermodynamic scenarios hypothesized for the supercooled region and in particular among them the liquid–liquid critical point scenario that has so far received more experimental evidence. We then review the most recent structural indicators, the two-state model picture of water, and the importance of cooperative effects related to the fact that water is a hydrogen-bonded network liquid. We show throughout the review that water’s peculiar properties come into play also when water is in solution, confined, and close to biological molecules. Concerning dynamics, upon mild supercooling water behaves as a fragile glass former following the mode coupling theory, and it turns into a strong glass former upon further cooling. Connections between the slow dynamics and the thermodynamics are discussed. The translational relaxation times of density fluctuations show in fact the fragile-to-strong crossover connected to the thermodynamics arising from the existence of two liquids. When considering also rotations, additional crossovers come to play. Mobility–viscosity decoupling is also discussed in supercooled water and aqueous solutions. Finally, the polyamorphism of glassy water is considered through experimental and simulation results both in bulk and in salty aqueous solutions. Grains and grain boundaries are also discussed.
Fil: Gallo, Paola Vanesa. Università Roma Tre III; Italia
Fil: Bachler, Johannes. Universidad de Innsbruck; Austria
Fil: Bove, Livia Eleonora. Università degli studi di Roma "La Sapienza"; Italia. Université Pierre et Marie Curie; Francia
Fil: Böhmer, Roland. Universität Dortmund; Alemania
Fil: Camisasca, Gaia. Università Roma Tre III; Italia
Fil: Coronas, Luis Enrique. Universidad de Barcelona; España
Fil: Corti, Horacio Roberto. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: de Almeida Ribeiro, Ingrid. Universidade Estadual de Campinas; Brasil
Fil: de Koning Maurice. Universidade Estadual de Campinas; Brasil
Fil: Franzese, Giancarlo. Universidad de Barcelona; España
Fil: Fuentes Landete, Violeta. Universidad de Innsbruck; Austria
Fil: Gainaru, Catalin. Universität Dortmund; Alemania
Fil: Loerting, Thomas. Universidad de Innsbruck; Austria
Fil: Montes de Oca, Joan Manuel. University of Chicago; Estados Unidos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Poole, Peter. Saint Francis Xavier University; Canadá
Fil: Rovere, Mauro. Università Roma Tre III; Italia
Fil: Sciortino, Francesco. Università di Roma; Italia
Fil: Tonauer, María Christina. Universidad de Innsbruck; Austria
Fil: Appignanesi, Gustavo Adrian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
description In this review, we report recent progress in the field of supercooled water. Due to its uniqueness, water presents numerous anomalies with respect to most simple liquids, showing polyamorphism both in the liquid and in the glassy state. We first describe the thermodynamic scenarios hypothesized for the supercooled region and in particular among them the liquid–liquid critical point scenario that has so far received more experimental evidence. We then review the most recent structural indicators, the two-state model picture of water, and the importance of cooperative effects related to the fact that water is a hydrogen-bonded network liquid. We show throughout the review that water’s peculiar properties come into play also when water is in solution, confined, and close to biological molecules. Concerning dynamics, upon mild supercooling water behaves as a fragile glass former following the mode coupling theory, and it turns into a strong glass former upon further cooling. Connections between the slow dynamics and the thermodynamics are discussed. The translational relaxation times of density fluctuations show in fact the fragile-to-strong crossover connected to the thermodynamics arising from the existence of two liquids. When considering also rotations, additional crossovers come to play. Mobility–viscosity decoupling is also discussed in supercooled water and aqueous solutions. Finally, the polyamorphism of glassy water is considered through experimental and simulation results both in bulk and in salty aqueous solutions. Grains and grain boundaries are also discussed.
publishDate 2021
dc.date.none.fl_str_mv 2021-11-26
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/169418
Gallo, Paola Vanesa; Bachler, Johannes; Bove, Livia Eleonora; Böhmer, Roland; Camisasca, Gaia; et al.; Advances in the study of supercooled water; Springer; European Physical Journal E; 44; 11; 26-11-2021; 1-36
1292-8941
CONICET Digital
CONICET
url http://hdl.handle.net/11336/169418
identifier_str_mv Gallo, Paola Vanesa; Bachler, Johannes; Bove, Livia Eleonora; Böhmer, Roland; Camisasca, Gaia; et al.; Advances in the study of supercooled water; Springer; European Physical Journal E; 44; 11; 26-11-2021; 1-36
1292-8941
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1140/epje/s10189-021-00139-1
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1140/epje/s10189-021-00139-1
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.48226

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