Diameter distribution by deconvolution (DdD): Absorption spectra as a practical tool for semiconductor nanoparticle PSD determination

Autores
Onna, Diego Ariel; Perez Ipiña, Ignacio Martin; Fernández Casafuz, Agustina; Mayoral, Álvaro; Ibarra García, M. Ricardo; Aldabe, Sara Alfonsina; Martinez Ricci, Maria Luz
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Semiconductor nanoparticles (SNPs) are excellent candidates for various applications in fields like solar cells, light emitting diodes or sensors. Their size strongly determines their properties, thus characterizing their size is crucial for applications. In most cases, they are included in complex matrices which make it difficult to determine their average diameter and statistical distribution. In this work, we present a non-destructive, cheap and in situ procedure to calculate particle size distributions (PSDs) of SNPs in different media based on deconvolution of the absorbance spectrum with a database of the absorbance spectra of SNPs with different sizes. The method was validated against the SNP sizes obtained from transmission microscopy images, showing excellent agreement between both distributions. In particular, CdS SNPs embedded in mesoporous thin films were analyzed in detail. Additional composite systems were studied in order to extend the method to SNPs in polymers or bacteria, proving that it applies to several SNPs in diverse matrices. The PSDs obtained from the proposed method do not show any statistical difference with the one derived from TEM images. Finally, a web app that implements the methodology of this work has been developed.
Fil: Onna, Diego Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Perez Ipiña, Ignacio Martin. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Fernández Casafuz, Agustina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Mayoral, Álvaro. Shanghai Tech University; China. Universidad de Zaragoza; España
Fil: Ibarra García, M. Ricardo. Universidad de Zaragoza; España
Fil: Aldabe, Sara Alfonsina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Martinez Ricci, Maria Luz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Materia
Q-dots
size distribution
exciton
mesoporous oxides
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/121648
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Diameter distribution by deconvolution (DdD): Absorption spectra as a practical tool for semiconductor nanoparticle PSD determinationOnna, Diego ArielPerez Ipiña, Ignacio MartinFernández Casafuz, AgustinaMayoral, ÁlvaroIbarra García, M. RicardoAldabe, Sara AlfonsinaMartinez Ricci, Maria LuzQ-dotssize distributionexcitonmesoporous oxideshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Semiconductor nanoparticles (SNPs) are excellent candidates for various applications in fields like solar cells, light emitting diodes or sensors. Their size strongly determines their properties, thus characterizing their size is crucial for applications. In most cases, they are included in complex matrices which make it difficult to determine their average diameter and statistical distribution. In this work, we present a non-destructive, cheap and in situ procedure to calculate particle size distributions (PSDs) of SNPs in different media based on deconvolution of the absorbance spectrum with a database of the absorbance spectra of SNPs with different sizes. The method was validated against the SNP sizes obtained from transmission microscopy images, showing excellent agreement between both distributions. In particular, CdS SNPs embedded in mesoporous thin films were analyzed in detail. Additional composite systems were studied in order to extend the method to SNPs in polymers or bacteria, proving that it applies to several SNPs in diverse matrices. The PSDs obtained from the proposed method do not show any statistical difference with the one derived from TEM images. Finally, a web app that implements the methodology of this work has been developed.Fil: Onna, Diego Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Perez Ipiña, Ignacio Martin. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; ArgentinaFil: Fernández Casafuz, Agustina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; ArgentinaFil: Mayoral, Álvaro. Shanghai Tech University; China. Universidad de Zaragoza; EspañaFil: Ibarra García, M. Ricardo. Universidad de Zaragoza; EspañaFil: Aldabe, Sara Alfonsina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Martinez Ricci, Maria Luz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaRoyal Society of Chemistry2019-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/121648Onna, Diego Ariel; Perez Ipiña, Ignacio Martin; Fernández Casafuz, Agustina; Mayoral, Álvaro; Ibarra García, M. Ricardo; et al.; Diameter distribution by deconvolution (DdD): Absorption spectra as a practical tool for semiconductor nanoparticle PSD determination; Royal Society of Chemistry; Nanoscale Advances; 1; 9; 7-2019; 3499-35052516-0230CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://xlink.rsc.org/?DOI=C9NA00344Dinfo:eu-repo/semantics/altIdentifier/doi/10.1039/C9NA00344Dinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:35:48Zoai:ri.conicet.gov.ar:11336/121648instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:35:49.214CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Diameter distribution by deconvolution (DdD): Absorption spectra as a practical tool for semiconductor nanoparticle PSD determination
title Diameter distribution by deconvolution (DdD): Absorption spectra as a practical tool for semiconductor nanoparticle PSD determination
spellingShingle Diameter distribution by deconvolution (DdD): Absorption spectra as a practical tool for semiconductor nanoparticle PSD determination
Onna, Diego Ariel
Q-dots
size distribution
exciton
mesoporous oxides
title_short Diameter distribution by deconvolution (DdD): Absorption spectra as a practical tool for semiconductor nanoparticle PSD determination
title_full Diameter distribution by deconvolution (DdD): Absorption spectra as a practical tool for semiconductor nanoparticle PSD determination
title_fullStr Diameter distribution by deconvolution (DdD): Absorption spectra as a practical tool for semiconductor nanoparticle PSD determination
title_full_unstemmed Diameter distribution by deconvolution (DdD): Absorption spectra as a practical tool for semiconductor nanoparticle PSD determination
title_sort Diameter distribution by deconvolution (DdD): Absorption spectra as a practical tool for semiconductor nanoparticle PSD determination
dc.creator.none.fl_str_mv Onna, Diego Ariel
Perez Ipiña, Ignacio Martin
Fernández Casafuz, Agustina
Mayoral, Álvaro
Ibarra García, M. Ricardo
Aldabe, Sara Alfonsina
Martinez Ricci, Maria Luz
author Onna, Diego Ariel
author_facet Onna, Diego Ariel
Perez Ipiña, Ignacio Martin
Fernández Casafuz, Agustina
Mayoral, Álvaro
Ibarra García, M. Ricardo
Aldabe, Sara Alfonsina
Martinez Ricci, Maria Luz
author_role author
author2 Perez Ipiña, Ignacio Martin
Fernández Casafuz, Agustina
Mayoral, Álvaro
Ibarra García, M. Ricardo
Aldabe, Sara Alfonsina
Martinez Ricci, Maria Luz
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Q-dots
size distribution
exciton
mesoporous oxides
topic Q-dots
size distribution
exciton
mesoporous oxides
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Semiconductor nanoparticles (SNPs) are excellent candidates for various applications in fields like solar cells, light emitting diodes or sensors. Their size strongly determines their properties, thus characterizing their size is crucial for applications. In most cases, they are included in complex matrices which make it difficult to determine their average diameter and statistical distribution. In this work, we present a non-destructive, cheap and in situ procedure to calculate particle size distributions (PSDs) of SNPs in different media based on deconvolution of the absorbance spectrum with a database of the absorbance spectra of SNPs with different sizes. The method was validated against the SNP sizes obtained from transmission microscopy images, showing excellent agreement between both distributions. In particular, CdS SNPs embedded in mesoporous thin films were analyzed in detail. Additional composite systems were studied in order to extend the method to SNPs in polymers or bacteria, proving that it applies to several SNPs in diverse matrices. The PSDs obtained from the proposed method do not show any statistical difference with the one derived from TEM images. Finally, a web app that implements the methodology of this work has been developed.
Fil: Onna, Diego Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Perez Ipiña, Ignacio Martin. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Fernández Casafuz, Agustina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Mayoral, Álvaro. Shanghai Tech University; China. Universidad de Zaragoza; España
Fil: Ibarra García, M. Ricardo. Universidad de Zaragoza; España
Fil: Aldabe, Sara Alfonsina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Martinez Ricci, Maria Luz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
description Semiconductor nanoparticles (SNPs) are excellent candidates for various applications in fields like solar cells, light emitting diodes or sensors. Their size strongly determines their properties, thus characterizing their size is crucial for applications. In most cases, they are included in complex matrices which make it difficult to determine their average diameter and statistical distribution. In this work, we present a non-destructive, cheap and in situ procedure to calculate particle size distributions (PSDs) of SNPs in different media based on deconvolution of the absorbance spectrum with a database of the absorbance spectra of SNPs with different sizes. The method was validated against the SNP sizes obtained from transmission microscopy images, showing excellent agreement between both distributions. In particular, CdS SNPs embedded in mesoporous thin films were analyzed in detail. Additional composite systems were studied in order to extend the method to SNPs in polymers or bacteria, proving that it applies to several SNPs in diverse matrices. The PSDs obtained from the proposed method do not show any statistical difference with the one derived from TEM images. Finally, a web app that implements the methodology of this work has been developed.
publishDate 2019
dc.date.none.fl_str_mv 2019-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/121648
Onna, Diego Ariel; Perez Ipiña, Ignacio Martin; Fernández Casafuz, Agustina; Mayoral, Álvaro; Ibarra García, M. Ricardo; et al.; Diameter distribution by deconvolution (DdD): Absorption spectra as a practical tool for semiconductor nanoparticle PSD determination; Royal Society of Chemistry; Nanoscale Advances; 1; 9; 7-2019; 3499-3505
2516-0230
CONICET Digital
CONICET
url http://hdl.handle.net/11336/121648
identifier_str_mv Onna, Diego Ariel; Perez Ipiña, Ignacio Martin; Fernández Casafuz, Agustina; Mayoral, Álvaro; Ibarra García, M. Ricardo; et al.; Diameter distribution by deconvolution (DdD): Absorption spectra as a practical tool for semiconductor nanoparticle PSD determination; Royal Society of Chemistry; Nanoscale Advances; 1; 9; 7-2019; 3499-3505
2516-0230
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://xlink.rsc.org/?DOI=C9NA00344D
info:eu-repo/semantics/altIdentifier/doi/10.1039/C9NA00344D
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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