Acid-base dissociation constants of o-phthalic acid in acetonitrile/water mixtures over the (15 to 50) °C temperature range and related thermodynamic quantities
- Autores
- Gagliardi, Leonardo Gabriel; Castells, Cecilia Beatriz Marta; Rosés, Martí; Ràfols, Clara; Bosch, Elisabeth
- Año de publicación
- 2010
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Potassium hydrogen phthalate (KHP) is a primary titrimetric standard, and KHP solutions are also used as standards for pH reference values, in pure water or in hydrorganic solvent mixtures. However, the pH of these solutions can be affected by any shift in the pKa1 or pKa2 of the substance due to changes in the solvent composition or temperature. In this work, the two dissociation constants of o-phthalic acid were independently determined for different compositions of acetonitrile/water mixtures within the range from 0 % to 70 % by weight, in steps of 10 %, and at different temperatures from (15 to 50) °C, in steps of 5 °C. The dependence of ln Ka on the inverse of temperature has been examined by using statistical methods, and the corresponding ionization thermodynamic functions have been calculated for different acetonitrile compositions.
Fil: Gagliardi, Leonardo Gabriel. Universidad de Barcelona; España. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
Fil: Castells, Cecilia Beatriz Marta. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
Fil: Rosés, Martí. Universidad de Barcelona; España
Fil: Ràfols, Clara. Universidad de Barcelona; España
Fil: Bosch, Elisabeth. Universidad de Barcelona; España - Materia
-
DISSOCIATION CONSTANT
ACETONITRILE/WATER MIXTURES
PHTHALIC ACID
TEMPERATURA - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/95495
Ver los metadatos del registro completo
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Acid-base dissociation constants of o-phthalic acid in acetonitrile/water mixtures over the (15 to 50) °C temperature range and related thermodynamic quantitiesGagliardi, Leonardo GabrielCastells, Cecilia Beatriz MartaRosés, MartíRàfols, ClaraBosch, ElisabethDISSOCIATION CONSTANTACETONITRILE/WATER MIXTURESPHTHALIC ACIDTEMPERATURAhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Potassium hydrogen phthalate (KHP) is a primary titrimetric standard, and KHP solutions are also used as standards for pH reference values, in pure water or in hydrorganic solvent mixtures. However, the pH of these solutions can be affected by any shift in the pKa1 or pKa2 of the substance due to changes in the solvent composition or temperature. In this work, the two dissociation constants of o-phthalic acid were independently determined for different compositions of acetonitrile/water mixtures within the range from 0 % to 70 % by weight, in steps of 10 %, and at different temperatures from (15 to 50) °C, in steps of 5 °C. The dependence of ln Ka on the inverse of temperature has been examined by using statistical methods, and the corresponding ionization thermodynamic functions have been calculated for different acetonitrile compositions.Fil: Gagliardi, Leonardo Gabriel. Universidad de Barcelona; España. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: Castells, Cecilia Beatriz Marta. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: Rosés, Martí. Universidad de Barcelona; EspañaFil: Ràfols, Clara. Universidad de Barcelona; EspañaFil: Bosch, Elisabeth. Universidad de Barcelona; EspañaAmerican Chemical Society2010-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/95495Gagliardi, Leonardo Gabriel; Castells, Cecilia Beatriz Marta; Rosés, Martí; Ràfols, Clara; Bosch, Elisabeth; Acid-base dissociation constants of o-phthalic acid in acetonitrile/water mixtures over the (15 to 50) °C temperature range and related thermodynamic quantities; American Chemical Society; Journal of Chemical and Engineering Data; 55; 1; 1-2010; 85-910021-9568CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/je900273dinfo:eu-repo/semantics/altIdentifier/doi/10.1021/je900273dinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:29:50Zoai:ri.conicet.gov.ar:11336/95495instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:29:50.722CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Acid-base dissociation constants of o-phthalic acid in acetonitrile/water mixtures over the (15 to 50) °C temperature range and related thermodynamic quantities |
title |
Acid-base dissociation constants of o-phthalic acid in acetonitrile/water mixtures over the (15 to 50) °C temperature range and related thermodynamic quantities |
spellingShingle |
Acid-base dissociation constants of o-phthalic acid in acetonitrile/water mixtures over the (15 to 50) °C temperature range and related thermodynamic quantities Gagliardi, Leonardo Gabriel DISSOCIATION CONSTANT ACETONITRILE/WATER MIXTURES PHTHALIC ACID TEMPERATURA |
title_short |
Acid-base dissociation constants of o-phthalic acid in acetonitrile/water mixtures over the (15 to 50) °C temperature range and related thermodynamic quantities |
title_full |
Acid-base dissociation constants of o-phthalic acid in acetonitrile/water mixtures over the (15 to 50) °C temperature range and related thermodynamic quantities |
title_fullStr |
Acid-base dissociation constants of o-phthalic acid in acetonitrile/water mixtures over the (15 to 50) °C temperature range and related thermodynamic quantities |
title_full_unstemmed |
Acid-base dissociation constants of o-phthalic acid in acetonitrile/water mixtures over the (15 to 50) °C temperature range and related thermodynamic quantities |
title_sort |
Acid-base dissociation constants of o-phthalic acid in acetonitrile/water mixtures over the (15 to 50) °C temperature range and related thermodynamic quantities |
dc.creator.none.fl_str_mv |
Gagliardi, Leonardo Gabriel Castells, Cecilia Beatriz Marta Rosés, Martí Ràfols, Clara Bosch, Elisabeth |
author |
Gagliardi, Leonardo Gabriel |
author_facet |
Gagliardi, Leonardo Gabriel Castells, Cecilia Beatriz Marta Rosés, Martí Ràfols, Clara Bosch, Elisabeth |
author_role |
author |
author2 |
Castells, Cecilia Beatriz Marta Rosés, Martí Ràfols, Clara Bosch, Elisabeth |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
DISSOCIATION CONSTANT ACETONITRILE/WATER MIXTURES PHTHALIC ACID TEMPERATURA |
topic |
DISSOCIATION CONSTANT ACETONITRILE/WATER MIXTURES PHTHALIC ACID TEMPERATURA |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Potassium hydrogen phthalate (KHP) is a primary titrimetric standard, and KHP solutions are also used as standards for pH reference values, in pure water or in hydrorganic solvent mixtures. However, the pH of these solutions can be affected by any shift in the pKa1 or pKa2 of the substance due to changes in the solvent composition or temperature. In this work, the two dissociation constants of o-phthalic acid were independently determined for different compositions of acetonitrile/water mixtures within the range from 0 % to 70 % by weight, in steps of 10 %, and at different temperatures from (15 to 50) °C, in steps of 5 °C. The dependence of ln Ka on the inverse of temperature has been examined by using statistical methods, and the corresponding ionization thermodynamic functions have been calculated for different acetonitrile compositions. Fil: Gagliardi, Leonardo Gabriel. Universidad de Barcelona; España. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina Fil: Castells, Cecilia Beatriz Marta. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina Fil: Rosés, Martí. Universidad de Barcelona; España Fil: Ràfols, Clara. Universidad de Barcelona; España Fil: Bosch, Elisabeth. Universidad de Barcelona; España |
description |
Potassium hydrogen phthalate (KHP) is a primary titrimetric standard, and KHP solutions are also used as standards for pH reference values, in pure water or in hydrorganic solvent mixtures. However, the pH of these solutions can be affected by any shift in the pKa1 or pKa2 of the substance due to changes in the solvent composition or temperature. In this work, the two dissociation constants of o-phthalic acid were independently determined for different compositions of acetonitrile/water mixtures within the range from 0 % to 70 % by weight, in steps of 10 %, and at different temperatures from (15 to 50) °C, in steps of 5 °C. The dependence of ln Ka on the inverse of temperature has been examined by using statistical methods, and the corresponding ionization thermodynamic functions have been calculated for different acetonitrile compositions. |
publishDate |
2010 |
dc.date.none.fl_str_mv |
2010-01 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/95495 Gagliardi, Leonardo Gabriel; Castells, Cecilia Beatriz Marta; Rosés, Martí; Ràfols, Clara; Bosch, Elisabeth; Acid-base dissociation constants of o-phthalic acid in acetonitrile/water mixtures over the (15 to 50) °C temperature range and related thermodynamic quantities; American Chemical Society; Journal of Chemical and Engineering Data; 55; 1; 1-2010; 85-91 0021-9568 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/95495 |
identifier_str_mv |
Gagliardi, Leonardo Gabriel; Castells, Cecilia Beatriz Marta; Rosés, Martí; Ràfols, Clara; Bosch, Elisabeth; Acid-base dissociation constants of o-phthalic acid in acetonitrile/water mixtures over the (15 to 50) °C temperature range and related thermodynamic quantities; American Chemical Society; Journal of Chemical and Engineering Data; 55; 1; 1-2010; 85-91 0021-9568 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/je900273d info:eu-repo/semantics/altIdentifier/doi/10.1021/je900273d |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614305712963584 |
score |
13.070432 |