Recent progress and new perspectives on metal amide and imide systems for solid-state hydrogen storage

Autores
Garroni, Sebastiano; Santoru, Antonio; Cao, Hujun; Dornheim, Martin; Klassen, Thomas; Milanese, Chiara; Gennari, Fabiana Cristina; Pistidda, Claudio
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Hydrogen storage in the solid state represents one of the most attractive and challenging ways to supply hydrogen to a proton exchange membrane (PEM) fuel cell. Although in the last 15 years a large variety of material systems have been identified as possible candidates for storing hydrogen, further efforts have to be made in the development of systems which meet the strict targets of the Fuel Cells and Hydrogen Joint Undertaking (FCH JU) and U.S. Department of Energy (DOE). Recent projections indicate that a system possessing: (i) an ideal enthalpy in the range of 20-50 kJ/mol H2, to use the heat produced by PEM fuel cell for providing the energy necessary for desorption; (ii) a gravimetric hydrogen density of 5 wt. % H2 and (iii) fast sorption kinetics below 110 °C is strongly recommended. Among the known hydrogen storage materials, amide and imide-based mixtures represent the most promising class of compounds for on-board applications; however, some barriers still have to be overcome before considering this class of material mature for real applications. In this review, the most relevant progresses made in the recent years as well as the kinetic and thermodynamic properties, experimentally measured for the most promising systems, are reported and properly discussed.
Fil: Garroni, Sebastiano. Universidad de Burgos; España
Fil: Santoru, Antonio. Helmholtz-Zentrum Geesthacht; Alemania
Fil: Cao, Hujun. Helmut Schmidt University; Alemania. Helmholtz-Zentrum Geesthacht; Alemania
Fil: Dornheim, Martin. Helmholtz-Zentrum Geesthacht; Alemania
Fil: Klassen, Thomas. Helmholtz-Zentrum Geesthacht; Alemania
Fil: Milanese, Chiara. University of Pavia; Italia
Fil: Gennari, Fabiana Cristina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Pistidda, Claudio. Helmholtz-Zentrum Geesthacht; Alemania
Materia
HYDROGEN STORAGE MATERIALS
METAL AMIDES
THERMODYNAMICS AND KINETICS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/97141
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Recent progress and new perspectives on metal amide and imide systems for solid-state hydrogen storageGarroni, SebastianoSantoru, AntonioCao, HujunDornheim, MartinKlassen, ThomasMilanese, ChiaraGennari, Fabiana CristinaPistidda, ClaudioHYDROGEN STORAGE MATERIALSMETAL AMIDESTHERMODYNAMICS AND KINETICShttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Hydrogen storage in the solid state represents one of the most attractive and challenging ways to supply hydrogen to a proton exchange membrane (PEM) fuel cell. Although in the last 15 years a large variety of material systems have been identified as possible candidates for storing hydrogen, further efforts have to be made in the development of systems which meet the strict targets of the Fuel Cells and Hydrogen Joint Undertaking (FCH JU) and U.S. Department of Energy (DOE). Recent projections indicate that a system possessing: (i) an ideal enthalpy in the range of 20-50 kJ/mol H2, to use the heat produced by PEM fuel cell for providing the energy necessary for desorption; (ii) a gravimetric hydrogen density of 5 wt. % H2 and (iii) fast sorption kinetics below 110 °C is strongly recommended. Among the known hydrogen storage materials, amide and imide-based mixtures represent the most promising class of compounds for on-board applications; however, some barriers still have to be overcome before considering this class of material mature for real applications. In this review, the most relevant progresses made in the recent years as well as the kinetic and thermodynamic properties, experimentally measured for the most promising systems, are reported and properly discussed.Fil: Garroni, Sebastiano. Universidad de Burgos; EspañaFil: Santoru, Antonio. Helmholtz-Zentrum Geesthacht; AlemaniaFil: Cao, Hujun. Helmut Schmidt University; Alemania. Helmholtz-Zentrum Geesthacht; AlemaniaFil: Dornheim, Martin. Helmholtz-Zentrum Geesthacht; AlemaniaFil: Klassen, Thomas. Helmholtz-Zentrum Geesthacht; AlemaniaFil: Milanese, Chiara. University of Pavia; ItaliaFil: Gennari, Fabiana Cristina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Pistidda, Claudio. Helmholtz-Zentrum Geesthacht; AlemaniaMDPI2018-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/97141Garroni, Sebastiano; Santoru, Antonio; Cao, Hujun; Dornheim, Martin; Klassen, Thomas; et al.; Recent progress and new perspectives on metal amide and imide systems for solid-state hydrogen storage; MDPI; Energies; 11; 5; 4-2018; 1-281996-1073CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.3390/en11051027info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1996-1073/11/5/1027info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:56:56Zoai:ri.conicet.gov.ar:11336/97141instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:56:57.174CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Recent progress and new perspectives on metal amide and imide systems for solid-state hydrogen storage
title Recent progress and new perspectives on metal amide and imide systems for solid-state hydrogen storage
spellingShingle Recent progress and new perspectives on metal amide and imide systems for solid-state hydrogen storage
Garroni, Sebastiano
HYDROGEN STORAGE MATERIALS
METAL AMIDES
THERMODYNAMICS AND KINETICS
title_short Recent progress and new perspectives on metal amide and imide systems for solid-state hydrogen storage
title_full Recent progress and new perspectives on metal amide and imide systems for solid-state hydrogen storage
title_fullStr Recent progress and new perspectives on metal amide and imide systems for solid-state hydrogen storage
title_full_unstemmed Recent progress and new perspectives on metal amide and imide systems for solid-state hydrogen storage
title_sort Recent progress and new perspectives on metal amide and imide systems for solid-state hydrogen storage
dc.creator.none.fl_str_mv Garroni, Sebastiano
Santoru, Antonio
Cao, Hujun
Dornheim, Martin
Klassen, Thomas
Milanese, Chiara
Gennari, Fabiana Cristina
Pistidda, Claudio
author Garroni, Sebastiano
author_facet Garroni, Sebastiano
Santoru, Antonio
Cao, Hujun
Dornheim, Martin
Klassen, Thomas
Milanese, Chiara
Gennari, Fabiana Cristina
Pistidda, Claudio
author_role author
author2 Santoru, Antonio
Cao, Hujun
Dornheim, Martin
Klassen, Thomas
Milanese, Chiara
Gennari, Fabiana Cristina
Pistidda, Claudio
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv HYDROGEN STORAGE MATERIALS
METAL AMIDES
THERMODYNAMICS AND KINETICS
topic HYDROGEN STORAGE MATERIALS
METAL AMIDES
THERMODYNAMICS AND KINETICS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Hydrogen storage in the solid state represents one of the most attractive and challenging ways to supply hydrogen to a proton exchange membrane (PEM) fuel cell. Although in the last 15 years a large variety of material systems have been identified as possible candidates for storing hydrogen, further efforts have to be made in the development of systems which meet the strict targets of the Fuel Cells and Hydrogen Joint Undertaking (FCH JU) and U.S. Department of Energy (DOE). Recent projections indicate that a system possessing: (i) an ideal enthalpy in the range of 20-50 kJ/mol H2, to use the heat produced by PEM fuel cell for providing the energy necessary for desorption; (ii) a gravimetric hydrogen density of 5 wt. % H2 and (iii) fast sorption kinetics below 110 °C is strongly recommended. Among the known hydrogen storage materials, amide and imide-based mixtures represent the most promising class of compounds for on-board applications; however, some barriers still have to be overcome before considering this class of material mature for real applications. In this review, the most relevant progresses made in the recent years as well as the kinetic and thermodynamic properties, experimentally measured for the most promising systems, are reported and properly discussed.
Fil: Garroni, Sebastiano. Universidad de Burgos; España
Fil: Santoru, Antonio. Helmholtz-Zentrum Geesthacht; Alemania
Fil: Cao, Hujun. Helmut Schmidt University; Alemania. Helmholtz-Zentrum Geesthacht; Alemania
Fil: Dornheim, Martin. Helmholtz-Zentrum Geesthacht; Alemania
Fil: Klassen, Thomas. Helmholtz-Zentrum Geesthacht; Alemania
Fil: Milanese, Chiara. University of Pavia; Italia
Fil: Gennari, Fabiana Cristina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Pistidda, Claudio. Helmholtz-Zentrum Geesthacht; Alemania
description Hydrogen storage in the solid state represents one of the most attractive and challenging ways to supply hydrogen to a proton exchange membrane (PEM) fuel cell. Although in the last 15 years a large variety of material systems have been identified as possible candidates for storing hydrogen, further efforts have to be made in the development of systems which meet the strict targets of the Fuel Cells and Hydrogen Joint Undertaking (FCH JU) and U.S. Department of Energy (DOE). Recent projections indicate that a system possessing: (i) an ideal enthalpy in the range of 20-50 kJ/mol H2, to use the heat produced by PEM fuel cell for providing the energy necessary for desorption; (ii) a gravimetric hydrogen density of 5 wt. % H2 and (iii) fast sorption kinetics below 110 °C is strongly recommended. Among the known hydrogen storage materials, amide and imide-based mixtures represent the most promising class of compounds for on-board applications; however, some barriers still have to be overcome before considering this class of material mature for real applications. In this review, the most relevant progresses made in the recent years as well as the kinetic and thermodynamic properties, experimentally measured for the most promising systems, are reported and properly discussed.
publishDate 2018
dc.date.none.fl_str_mv 2018-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/97141
Garroni, Sebastiano; Santoru, Antonio; Cao, Hujun; Dornheim, Martin; Klassen, Thomas; et al.; Recent progress and new perspectives on metal amide and imide systems for solid-state hydrogen storage; MDPI; Energies; 11; 5; 4-2018; 1-28
1996-1073
CONICET Digital
CONICET
url http://hdl.handle.net/11336/97141
identifier_str_mv Garroni, Sebastiano; Santoru, Antonio; Cao, Hujun; Dornheim, Martin; Klassen, Thomas; et al.; Recent progress and new perspectives on metal amide and imide systems for solid-state hydrogen storage; MDPI; Energies; 11; 5; 4-2018; 1-28
1996-1073
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.3390/en11051027
info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1996-1073/11/5/1027
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269430934929408
score 13.13397

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