Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains

Autores
Zucchi, Ileana Alicia; Galante, Maria Jose; Williams, Roberto Juan Jose; Franchini, Elsa; Galy, Jocelyne; Gérard, Jean François
Año de publicación
2007
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Several studies have recently reported the use of monofunctional octahedral oligomeric silsesquioxanes (monofunctional POSS) to modify polymer networks. In most of these studies the final material is depicted as a network with pendent POSS units randomly dispersed in the structure. The aim of this paper is to show that this representation is generally not correct due to the occurrence of a polymerization-induced phase separation (PIPS) process. In this sense, monofunctional POSS are not different from different types of rubbers, thermoplastics, or liquid crystals used to modify polymer networks. Although some authors have noticed the occurrence of PIPS in particular systems, a comparative study of the effect of the chemical structure of POSS and its prereaction with one of the monomers on the morphologies generated has not been previously reported. Glycidyloxypropyl-heptaisobutyl POSS (iBu-GlyPOSS) and glycidyloxypropyl-heptaphenyl POSS (Ph-GlyPOSS) were used to modify an epoxy network based on diglycidyl ether of bisphenol A (DGEBA) and 4,4′-methylenebis(2,6-diethylaniline) (MDEA). POSS was introduced in the formulation either nonreacted or prereacted with MDEA (molar ratio POSS/MDEA: 1/10). While both nonreacted and prereacted iBu-GlyPOSS were soluble in the epoxy - amine precursors at the polymerization temperature (135°C), only prereacted Ph-GlyPOSS could be dissolved in epoxyamine precursors. For every case a polymerization-induced phase separation took place. For the nonreacted iBuGlyPOSS this process led to a dispersion of spherical particles with sizes in the range of the micrometers that crystallized upon cooling. Both prereacted POSS led to different types of amorphous biphasic structures. Therefore, the nature of the organic inert group and the prereaction of a monofunctional POSS can be used to control the morphologies generated in the POSS-modified polymer network.
Fil: Zucchi, Ileana Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Galante, Maria Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Franchini, Elsa. Institut National des Sciences Appliquées de Lyon; Francia
Fil: Galy, Jocelyne. Institut National des Sciences Appliquées de Lyon; Francia
Fil: Gérard, Jean François. Institut National des Sciences Appliquées de Lyon; Francia
Materia
Polyhedral Silsesquioxane
Epoxy Resin
Amine
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/70405
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domainsZucchi, Ileana AliciaGalante, Maria JoseWilliams, Roberto Juan JoseFranchini, ElsaGaly, JocelyneGérard, Jean FrançoisPolyhedral SilsesquioxaneEpoxy ResinAminehttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Several studies have recently reported the use of monofunctional octahedral oligomeric silsesquioxanes (monofunctional POSS) to modify polymer networks. In most of these studies the final material is depicted as a network with pendent POSS units randomly dispersed in the structure. The aim of this paper is to show that this representation is generally not correct due to the occurrence of a polymerization-induced phase separation (PIPS) process. In this sense, monofunctional POSS are not different from different types of rubbers, thermoplastics, or liquid crystals used to modify polymer networks. Although some authors have noticed the occurrence of PIPS in particular systems, a comparative study of the effect of the chemical structure of POSS and its prereaction with one of the monomers on the morphologies generated has not been previously reported. Glycidyloxypropyl-heptaisobutyl POSS (iBu-GlyPOSS) and glycidyloxypropyl-heptaphenyl POSS (Ph-GlyPOSS) were used to modify an epoxy network based on diglycidyl ether of bisphenol A (DGEBA) and 4,4′-methylenebis(2,6-diethylaniline) (MDEA). POSS was introduced in the formulation either nonreacted or prereacted with MDEA (molar ratio POSS/MDEA: 1/10). While both nonreacted and prereacted iBu-GlyPOSS were soluble in the epoxy - amine precursors at the polymerization temperature (135°C), only prereacted Ph-GlyPOSS could be dissolved in epoxyamine precursors. For every case a polymerization-induced phase separation took place. For the nonreacted iBuGlyPOSS this process led to a dispersion of spherical particles with sizes in the range of the micrometers that crystallized upon cooling. Both prereacted POSS led to different types of amorphous biphasic structures. Therefore, the nature of the organic inert group and the prereaction of a monofunctional POSS can be used to control the morphologies generated in the POSS-modified polymer network.Fil: Zucchi, Ileana Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Galante, Maria Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Franchini, Elsa. Institut National des Sciences Appliquées de Lyon; FranciaFil: Galy, Jocelyne. Institut National des Sciences Appliquées de Lyon; FranciaFil: Gérard, Jean François. Institut National des Sciences Appliquées de Lyon; FranciaAmerican Chemical Society2007-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/70405Zucchi, Ileana Alicia; Galante, Maria Jose; Williams, Roberto Juan Jose; Franchini, Elsa; Galy, Jocelyne; et al.; Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains; American Chemical Society; Macromolecules; 40; 4; 2-2007; 1274-12820024-9297CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ma062188yinfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/ma062188yinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:13:26Zoai:ri.conicet.gov.ar:11336/70405instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:13:27.229CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains
title Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains
spellingShingle Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains
Zucchi, Ileana Alicia
Polyhedral Silsesquioxane
Epoxy Resin
Amine
title_short Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains
title_full Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains
title_fullStr Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains
title_full_unstemmed Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains
title_sort Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains
dc.creator.none.fl_str_mv Zucchi, Ileana Alicia
Galante, Maria Jose
Williams, Roberto Juan Jose
Franchini, Elsa
Galy, Jocelyne
Gérard, Jean François
author Zucchi, Ileana Alicia
author_facet Zucchi, Ileana Alicia
Galante, Maria Jose
Williams, Roberto Juan Jose
Franchini, Elsa
Galy, Jocelyne
Gérard, Jean François
author_role author
author2 Galante, Maria Jose
Williams, Roberto Juan Jose
Franchini, Elsa
Galy, Jocelyne
Gérard, Jean François
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Polyhedral Silsesquioxane
Epoxy Resin
Amine
topic Polyhedral Silsesquioxane
Epoxy Resin
Amine
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Several studies have recently reported the use of monofunctional octahedral oligomeric silsesquioxanes (monofunctional POSS) to modify polymer networks. In most of these studies the final material is depicted as a network with pendent POSS units randomly dispersed in the structure. The aim of this paper is to show that this representation is generally not correct due to the occurrence of a polymerization-induced phase separation (PIPS) process. In this sense, monofunctional POSS are not different from different types of rubbers, thermoplastics, or liquid crystals used to modify polymer networks. Although some authors have noticed the occurrence of PIPS in particular systems, a comparative study of the effect of the chemical structure of POSS and its prereaction with one of the monomers on the morphologies generated has not been previously reported. Glycidyloxypropyl-heptaisobutyl POSS (iBu-GlyPOSS) and glycidyloxypropyl-heptaphenyl POSS (Ph-GlyPOSS) were used to modify an epoxy network based on diglycidyl ether of bisphenol A (DGEBA) and 4,4′-methylenebis(2,6-diethylaniline) (MDEA). POSS was introduced in the formulation either nonreacted or prereacted with MDEA (molar ratio POSS/MDEA: 1/10). While both nonreacted and prereacted iBu-GlyPOSS were soluble in the epoxy - amine precursors at the polymerization temperature (135°C), only prereacted Ph-GlyPOSS could be dissolved in epoxyamine precursors. For every case a polymerization-induced phase separation took place. For the nonreacted iBuGlyPOSS this process led to a dispersion of spherical particles with sizes in the range of the micrometers that crystallized upon cooling. Both prereacted POSS led to different types of amorphous biphasic structures. Therefore, the nature of the organic inert group and the prereaction of a monofunctional POSS can be used to control the morphologies generated in the POSS-modified polymer network.
Fil: Zucchi, Ileana Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Galante, Maria Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Franchini, Elsa. Institut National des Sciences Appliquées de Lyon; Francia
Fil: Galy, Jocelyne. Institut National des Sciences Appliquées de Lyon; Francia
Fil: Gérard, Jean François. Institut National des Sciences Appliquées de Lyon; Francia
description Several studies have recently reported the use of monofunctional octahedral oligomeric silsesquioxanes (monofunctional POSS) to modify polymer networks. In most of these studies the final material is depicted as a network with pendent POSS units randomly dispersed in the structure. The aim of this paper is to show that this representation is generally not correct due to the occurrence of a polymerization-induced phase separation (PIPS) process. In this sense, monofunctional POSS are not different from different types of rubbers, thermoplastics, or liquid crystals used to modify polymer networks. Although some authors have noticed the occurrence of PIPS in particular systems, a comparative study of the effect of the chemical structure of POSS and its prereaction with one of the monomers on the morphologies generated has not been previously reported. Glycidyloxypropyl-heptaisobutyl POSS (iBu-GlyPOSS) and glycidyloxypropyl-heptaphenyl POSS (Ph-GlyPOSS) were used to modify an epoxy network based on diglycidyl ether of bisphenol A (DGEBA) and 4,4′-methylenebis(2,6-diethylaniline) (MDEA). POSS was introduced in the formulation either nonreacted or prereacted with MDEA (molar ratio POSS/MDEA: 1/10). While both nonreacted and prereacted iBu-GlyPOSS were soluble in the epoxy - amine precursors at the polymerization temperature (135°C), only prereacted Ph-GlyPOSS could be dissolved in epoxyamine precursors. For every case a polymerization-induced phase separation took place. For the nonreacted iBuGlyPOSS this process led to a dispersion of spherical particles with sizes in the range of the micrometers that crystallized upon cooling. Both prereacted POSS led to different types of amorphous biphasic structures. Therefore, the nature of the organic inert group and the prereaction of a monofunctional POSS can be used to control the morphologies generated in the POSS-modified polymer network.
publishDate 2007
dc.date.none.fl_str_mv 2007-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/70405
Zucchi, Ileana Alicia; Galante, Maria Jose; Williams, Roberto Juan Jose; Franchini, Elsa; Galy, Jocelyne; et al.; Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains; American Chemical Society; Macromolecules; 40; 4; 2-2007; 1274-1282
0024-9297
CONICET Digital
CONICET
url http://hdl.handle.net/11336/70405
identifier_str_mv Zucchi, Ileana Alicia; Galante, Maria Jose; Williams, Roberto Juan Jose; Franchini, Elsa; Galy, Jocelyne; et al.; Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains; American Chemical Society; Macromolecules; 40; 4; 2-2007; 1274-1282
0024-9297
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/ma062188y
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/ma062188y
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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