Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains
- Autores
- Zucchi, Ileana Alicia; Galante, Maria Jose; Williams, Roberto Juan Jose; Franchini, Elsa; Galy, Jocelyne; Gérard, Jean François
- Año de publicación
- 2007
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Several studies have recently reported the use of monofunctional octahedral oligomeric silsesquioxanes (monofunctional POSS) to modify polymer networks. In most of these studies the final material is depicted as a network with pendent POSS units randomly dispersed in the structure. The aim of this paper is to show that this representation is generally not correct due to the occurrence of a polymerization-induced phase separation (PIPS) process. In this sense, monofunctional POSS are not different from different types of rubbers, thermoplastics, or liquid crystals used to modify polymer networks. Although some authors have noticed the occurrence of PIPS in particular systems, a comparative study of the effect of the chemical structure of POSS and its prereaction with one of the monomers on the morphologies generated has not been previously reported. Glycidyloxypropyl-heptaisobutyl POSS (iBu-GlyPOSS) and glycidyloxypropyl-heptaphenyl POSS (Ph-GlyPOSS) were used to modify an epoxy network based on diglycidyl ether of bisphenol A (DGEBA) and 4,4′-methylenebis(2,6-diethylaniline) (MDEA). POSS was introduced in the formulation either nonreacted or prereacted with MDEA (molar ratio POSS/MDEA: 1/10). While both nonreacted and prereacted iBu-GlyPOSS were soluble in the epoxy - amine precursors at the polymerization temperature (135°C), only prereacted Ph-GlyPOSS could be dissolved in epoxyamine precursors. For every case a polymerization-induced phase separation took place. For the nonreacted iBuGlyPOSS this process led to a dispersion of spherical particles with sizes in the range of the micrometers that crystallized upon cooling. Both prereacted POSS led to different types of amorphous biphasic structures. Therefore, the nature of the organic inert group and the prereaction of a monofunctional POSS can be used to control the morphologies generated in the POSS-modified polymer network.
Fil: Zucchi, Ileana Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Galante, Maria Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Franchini, Elsa. Institut National des Sciences Appliquées de Lyon; Francia
Fil: Galy, Jocelyne. Institut National des Sciences Appliquées de Lyon; Francia
Fil: Gérard, Jean François. Institut National des Sciences Appliquées de Lyon; Francia - Materia
-
Polyhedral Silsesquioxane
Epoxy Resin
Amine - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/70405
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Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domainsZucchi, Ileana AliciaGalante, Maria JoseWilliams, Roberto Juan JoseFranchini, ElsaGaly, JocelyneGérard, Jean FrançoisPolyhedral SilsesquioxaneEpoxy ResinAminehttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Several studies have recently reported the use of monofunctional octahedral oligomeric silsesquioxanes (monofunctional POSS) to modify polymer networks. In most of these studies the final material is depicted as a network with pendent POSS units randomly dispersed in the structure. The aim of this paper is to show that this representation is generally not correct due to the occurrence of a polymerization-induced phase separation (PIPS) process. In this sense, monofunctional POSS are not different from different types of rubbers, thermoplastics, or liquid crystals used to modify polymer networks. Although some authors have noticed the occurrence of PIPS in particular systems, a comparative study of the effect of the chemical structure of POSS and its prereaction with one of the monomers on the morphologies generated has not been previously reported. Glycidyloxypropyl-heptaisobutyl POSS (iBu-GlyPOSS) and glycidyloxypropyl-heptaphenyl POSS (Ph-GlyPOSS) were used to modify an epoxy network based on diglycidyl ether of bisphenol A (DGEBA) and 4,4′-methylenebis(2,6-diethylaniline) (MDEA). POSS was introduced in the formulation either nonreacted or prereacted with MDEA (molar ratio POSS/MDEA: 1/10). While both nonreacted and prereacted iBu-GlyPOSS were soluble in the epoxy - amine precursors at the polymerization temperature (135°C), only prereacted Ph-GlyPOSS could be dissolved in epoxyamine precursors. For every case a polymerization-induced phase separation took place. For the nonreacted iBuGlyPOSS this process led to a dispersion of spherical particles with sizes in the range of the micrometers that crystallized upon cooling. Both prereacted POSS led to different types of amorphous biphasic structures. Therefore, the nature of the organic inert group and the prereaction of a monofunctional POSS can be used to control the morphologies generated in the POSS-modified polymer network.Fil: Zucchi, Ileana Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Galante, Maria Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Franchini, Elsa. Institut National des Sciences Appliquées de Lyon; FranciaFil: Galy, Jocelyne. Institut National des Sciences Appliquées de Lyon; FranciaFil: Gérard, Jean François. Institut National des Sciences Appliquées de Lyon; FranciaAmerican Chemical Society2007-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/70405Zucchi, Ileana Alicia; Galante, Maria Jose; Williams, Roberto Juan Jose; Franchini, Elsa; Galy, Jocelyne; et al.; Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains; American Chemical Society; Macromolecules; 40; 4; 2-2007; 1274-12820024-9297CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ma062188yinfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/ma062188yinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:00:52Zoai:ri.conicet.gov.ar:11336/70405instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:00:53.345CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains |
title |
Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains |
spellingShingle |
Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains Zucchi, Ileana Alicia Polyhedral Silsesquioxane Epoxy Resin Amine |
title_short |
Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains |
title_full |
Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains |
title_fullStr |
Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains |
title_full_unstemmed |
Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains |
title_sort |
Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains |
dc.creator.none.fl_str_mv |
Zucchi, Ileana Alicia Galante, Maria Jose Williams, Roberto Juan Jose Franchini, Elsa Galy, Jocelyne Gérard, Jean François |
author |
Zucchi, Ileana Alicia |
author_facet |
Zucchi, Ileana Alicia Galante, Maria Jose Williams, Roberto Juan Jose Franchini, Elsa Galy, Jocelyne Gérard, Jean François |
author_role |
author |
author2 |
Galante, Maria Jose Williams, Roberto Juan Jose Franchini, Elsa Galy, Jocelyne Gérard, Jean François |
author2_role |
author author author author author |
dc.subject.none.fl_str_mv |
Polyhedral Silsesquioxane Epoxy Resin Amine |
topic |
Polyhedral Silsesquioxane Epoxy Resin Amine |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Several studies have recently reported the use of monofunctional octahedral oligomeric silsesquioxanes (monofunctional POSS) to modify polymer networks. In most of these studies the final material is depicted as a network with pendent POSS units randomly dispersed in the structure. The aim of this paper is to show that this representation is generally not correct due to the occurrence of a polymerization-induced phase separation (PIPS) process. In this sense, monofunctional POSS are not different from different types of rubbers, thermoplastics, or liquid crystals used to modify polymer networks. Although some authors have noticed the occurrence of PIPS in particular systems, a comparative study of the effect of the chemical structure of POSS and its prereaction with one of the monomers on the morphologies generated has not been previously reported. Glycidyloxypropyl-heptaisobutyl POSS (iBu-GlyPOSS) and glycidyloxypropyl-heptaphenyl POSS (Ph-GlyPOSS) were used to modify an epoxy network based on diglycidyl ether of bisphenol A (DGEBA) and 4,4′-methylenebis(2,6-diethylaniline) (MDEA). POSS was introduced in the formulation either nonreacted or prereacted with MDEA (molar ratio POSS/MDEA: 1/10). While both nonreacted and prereacted iBu-GlyPOSS were soluble in the epoxy - amine precursors at the polymerization temperature (135°C), only prereacted Ph-GlyPOSS could be dissolved in epoxyamine precursors. For every case a polymerization-induced phase separation took place. For the nonreacted iBuGlyPOSS this process led to a dispersion of spherical particles with sizes in the range of the micrometers that crystallized upon cooling. Both prereacted POSS led to different types of amorphous biphasic structures. Therefore, the nature of the organic inert group and the prereaction of a monofunctional POSS can be used to control the morphologies generated in the POSS-modified polymer network. Fil: Zucchi, Ileana Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Galante, Maria Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Franchini, Elsa. Institut National des Sciences Appliquées de Lyon; Francia Fil: Galy, Jocelyne. Institut National des Sciences Appliquées de Lyon; Francia Fil: Gérard, Jean François. Institut National des Sciences Appliquées de Lyon; Francia |
description |
Several studies have recently reported the use of monofunctional octahedral oligomeric silsesquioxanes (monofunctional POSS) to modify polymer networks. In most of these studies the final material is depicted as a network with pendent POSS units randomly dispersed in the structure. The aim of this paper is to show that this representation is generally not correct due to the occurrence of a polymerization-induced phase separation (PIPS) process. In this sense, monofunctional POSS are not different from different types of rubbers, thermoplastics, or liquid crystals used to modify polymer networks. Although some authors have noticed the occurrence of PIPS in particular systems, a comparative study of the effect of the chemical structure of POSS and its prereaction with one of the monomers on the morphologies generated has not been previously reported. Glycidyloxypropyl-heptaisobutyl POSS (iBu-GlyPOSS) and glycidyloxypropyl-heptaphenyl POSS (Ph-GlyPOSS) were used to modify an epoxy network based on diglycidyl ether of bisphenol A (DGEBA) and 4,4′-methylenebis(2,6-diethylaniline) (MDEA). POSS was introduced in the formulation either nonreacted or prereacted with MDEA (molar ratio POSS/MDEA: 1/10). While both nonreacted and prereacted iBu-GlyPOSS were soluble in the epoxy - amine precursors at the polymerization temperature (135°C), only prereacted Ph-GlyPOSS could be dissolved in epoxyamine precursors. For every case a polymerization-induced phase separation took place. For the nonreacted iBuGlyPOSS this process led to a dispersion of spherical particles with sizes in the range of the micrometers that crystallized upon cooling. Both prereacted POSS led to different types of amorphous biphasic structures. Therefore, the nature of the organic inert group and the prereaction of a monofunctional POSS can be used to control the morphologies generated in the POSS-modified polymer network. |
publishDate |
2007 |
dc.date.none.fl_str_mv |
2007-02 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/70405 Zucchi, Ileana Alicia; Galante, Maria Jose; Williams, Roberto Juan Jose; Franchini, Elsa; Galy, Jocelyne; et al.; Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains; American Chemical Society; Macromolecules; 40; 4; 2-2007; 1274-1282 0024-9297 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/70405 |
identifier_str_mv |
Zucchi, Ileana Alicia; Galante, Maria Jose; Williams, Roberto Juan Jose; Franchini, Elsa; Galy, Jocelyne; et al.; Monofunctional epoxy-POSS dispersed in epoxy - Amine networks: Effect of a prereaction on the morphology and crystallinity of POSS domains; American Chemical Society; Macromolecules; 40; 4; 2-2007; 1274-1282 0024-9297 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1021/ma062188y info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/ma062188y |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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score |
13.13397 |