Visible-light photopolymerization of DGEBA promoted by silsesquioxanes functionalized with cycloaliphatic epoxy groups
- Autores
- Dell'erba, Ignacio Esteban; Arenas, Gustavo Francisco; Schroeder, Walter Fabian
- Año de publicación
- 2016
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Diglycidyl ether of bisphenol A (DGEBA) is among the most popular and widely used epoxy monomers. This monomer is commonly used in thermal network polymerizations with amines, phenols, isocyanates or mercaptans as curing agents. However, the photoinitiated polymerization of DGEBA is very sluggish and hence finds little use in high-speed photocuring applications. In this contribution, we demonstrated that this monomer can undergo very fast visible-light photopolymerization when combined with a silsesquioxane (SSO) functionalized with reactive epoxycyclohexane groups. The SSO was synthesized via alkoxysilane hydrolysis/condensation chemistry, using DGEBA as a solvent. We found that the photopolymerization of DGEBA is markedly accelerated as the amount of SSO in the mixture is increased. The promoter effect on the reactivity of DGEBA was ascribed to a combination of both thermal and copolymerization effects. Using dynamic mechanical analysis, we demonstrated that the resulting hybrid materials present a single-phase network structure, where the SSO species function as highly multifunctional epoxy reactants.
Fil: Dell'erba, Ignacio Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Arenas, Gustavo Francisco. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Departamento de Física; Argentina
Fil: Schroeder, Walter Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina - Materia
-
Epoxy Networks
Photoinitiated Cationic Polymerization
Silsesquioxanes - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/39642
Ver los metadatos del registro completo
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Visible-light photopolymerization of DGEBA promoted by silsesquioxanes functionalized with cycloaliphatic epoxy groupsDell'erba, Ignacio EstebanArenas, Gustavo FranciscoSchroeder, Walter FabianEpoxy NetworksPhotoinitiated Cationic PolymerizationSilsesquioxanesDiglycidyl ether of bisphenol A (DGEBA) is among the most popular and widely used epoxy monomers. This monomer is commonly used in thermal network polymerizations with amines, phenols, isocyanates or mercaptans as curing agents. However, the photoinitiated polymerization of DGEBA is very sluggish and hence finds little use in high-speed photocuring applications. In this contribution, we demonstrated that this monomer can undergo very fast visible-light photopolymerization when combined with a silsesquioxane (SSO) functionalized with reactive epoxycyclohexane groups. The SSO was synthesized via alkoxysilane hydrolysis/condensation chemistry, using DGEBA as a solvent. We found that the photopolymerization of DGEBA is markedly accelerated as the amount of SSO in the mixture is increased. The promoter effect on the reactivity of DGEBA was ascribed to a combination of both thermal and copolymerization effects. Using dynamic mechanical analysis, we demonstrated that the resulting hybrid materials present a single-phase network structure, where the SSO species function as highly multifunctional epoxy reactants.Fil: Dell'erba, Ignacio Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Arenas, Gustavo Francisco. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Departamento de Física; ArgentinaFil: Schroeder, Walter Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaElsevier2016-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/39642Dell'erba, Ignacio Esteban; Arenas, Gustavo Francisco; Schroeder, Walter Fabian; Visible-light photopolymerization of DGEBA promoted by silsesquioxanes functionalized with cycloaliphatic epoxy groups; Elsevier; Polymer; 83; 1-2016; 172-1810032-3861CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymer.2015.12.013info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0032386115304262info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:50:08Zoai:ri.conicet.gov.ar:11336/39642instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:50:08.888CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Visible-light photopolymerization of DGEBA promoted by silsesquioxanes functionalized with cycloaliphatic epoxy groups |
title |
Visible-light photopolymerization of DGEBA promoted by silsesquioxanes functionalized with cycloaliphatic epoxy groups |
spellingShingle |
Visible-light photopolymerization of DGEBA promoted by silsesquioxanes functionalized with cycloaliphatic epoxy groups Dell'erba, Ignacio Esteban Epoxy Networks Photoinitiated Cationic Polymerization Silsesquioxanes |
title_short |
Visible-light photopolymerization of DGEBA promoted by silsesquioxanes functionalized with cycloaliphatic epoxy groups |
title_full |
Visible-light photopolymerization of DGEBA promoted by silsesquioxanes functionalized with cycloaliphatic epoxy groups |
title_fullStr |
Visible-light photopolymerization of DGEBA promoted by silsesquioxanes functionalized with cycloaliphatic epoxy groups |
title_full_unstemmed |
Visible-light photopolymerization of DGEBA promoted by silsesquioxanes functionalized with cycloaliphatic epoxy groups |
title_sort |
Visible-light photopolymerization of DGEBA promoted by silsesquioxanes functionalized with cycloaliphatic epoxy groups |
dc.creator.none.fl_str_mv |
Dell'erba, Ignacio Esteban Arenas, Gustavo Francisco Schroeder, Walter Fabian |
author |
Dell'erba, Ignacio Esteban |
author_facet |
Dell'erba, Ignacio Esteban Arenas, Gustavo Francisco Schroeder, Walter Fabian |
author_role |
author |
author2 |
Arenas, Gustavo Francisco Schroeder, Walter Fabian |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Epoxy Networks Photoinitiated Cationic Polymerization Silsesquioxanes |
topic |
Epoxy Networks Photoinitiated Cationic Polymerization Silsesquioxanes |
dc.description.none.fl_txt_mv |
Diglycidyl ether of bisphenol A (DGEBA) is among the most popular and widely used epoxy monomers. This monomer is commonly used in thermal network polymerizations with amines, phenols, isocyanates or mercaptans as curing agents. However, the photoinitiated polymerization of DGEBA is very sluggish and hence finds little use in high-speed photocuring applications. In this contribution, we demonstrated that this monomer can undergo very fast visible-light photopolymerization when combined with a silsesquioxane (SSO) functionalized with reactive epoxycyclohexane groups. The SSO was synthesized via alkoxysilane hydrolysis/condensation chemistry, using DGEBA as a solvent. We found that the photopolymerization of DGEBA is markedly accelerated as the amount of SSO in the mixture is increased. The promoter effect on the reactivity of DGEBA was ascribed to a combination of both thermal and copolymerization effects. Using dynamic mechanical analysis, we demonstrated that the resulting hybrid materials present a single-phase network structure, where the SSO species function as highly multifunctional epoxy reactants. Fil: Dell'erba, Ignacio Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Arenas, Gustavo Francisco. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Departamento de Física; Argentina Fil: Schroeder, Walter Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina |
description |
Diglycidyl ether of bisphenol A (DGEBA) is among the most popular and widely used epoxy monomers. This monomer is commonly used in thermal network polymerizations with amines, phenols, isocyanates or mercaptans as curing agents. However, the photoinitiated polymerization of DGEBA is very sluggish and hence finds little use in high-speed photocuring applications. In this contribution, we demonstrated that this monomer can undergo very fast visible-light photopolymerization when combined with a silsesquioxane (SSO) functionalized with reactive epoxycyclohexane groups. The SSO was synthesized via alkoxysilane hydrolysis/condensation chemistry, using DGEBA as a solvent. We found that the photopolymerization of DGEBA is markedly accelerated as the amount of SSO in the mixture is increased. The promoter effect on the reactivity of DGEBA was ascribed to a combination of both thermal and copolymerization effects. Using dynamic mechanical analysis, we demonstrated that the resulting hybrid materials present a single-phase network structure, where the SSO species function as highly multifunctional epoxy reactants. |
publishDate |
2016 |
dc.date.none.fl_str_mv |
2016-01 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/39642 Dell'erba, Ignacio Esteban; Arenas, Gustavo Francisco; Schroeder, Walter Fabian; Visible-light photopolymerization of DGEBA promoted by silsesquioxanes functionalized with cycloaliphatic epoxy groups; Elsevier; Polymer; 83; 1-2016; 172-181 0032-3861 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/39642 |
identifier_str_mv |
Dell'erba, Ignacio Esteban; Arenas, Gustavo Francisco; Schroeder, Walter Fabian; Visible-light photopolymerization of DGEBA promoted by silsesquioxanes functionalized with cycloaliphatic epoxy groups; Elsevier; Polymer; 83; 1-2016; 172-181 0032-3861 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymer.2015.12.013 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0032386115304262 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842269015962025984 |
score |
13.13397 |