Cathodic stripping square-wave voltammetry for assessing As(III) removal with synthetic mixed oxides
- Autores
- Heredia, Angelica Constanza; Gómez Avila, Jenny; Garay, Fernando Sebastian; Crivello, Mónica Elsie
- Año de publicación
- 2017
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The possibility of counting with a reliable and economic system for filtering large volumes of water contaminated with arsenic is highly desired since different species of this element conform a major health risk through contamination of drinking and irrigation water supplies. In this work, the adsorption of As(III) species from aqueous solutions onto Mixed Oxides (MOs) synthesized from Layered Double Hydroxides (LDHs) has been assessed by cathodic stripping Square-wave voltammetry (CS-SWV). This electrochemical technique provides the fast, reliable, and systematic analysis required for studding the numerous aqueous samples. The optimized protocol consisted on the accumulation of arsenic for 60 s at ?0.4 V, in presence of 0.5 mM Cu(II), 0.3 µM pyrrolidine dithiocarbamate (PDTC), and 0.9 M HCl, followed by a reductive scan to ?1.0 V. A stable and well-defined peak was observed at ?0.780 V, with a linear range that goes from 2 µg L?1 to 110 µg L?1 of As(III). A value of limit of detection (LOD) = 4 µgL?1 was calculated as 3 times the ratio between the standard deviation of the ordinate and slope of the linear regression curve. The presence of Cu(II) increases the signal of current and minimizes the effect of interfering species, while the ligand PDTC forms a complex that stabilizes the signal observed during the cathodic scan.A series of MgAlFe ternary LDHs with different iron content and their MOs have been synthesized by co-precipitation and characterized by diverse techniques. XPS and DRUV-Vis analysis showed that the Fe(III) ions can be found in tetrahedral and octahedral coordination environments, while SEM micrographs, evidenced the cluster formation and aggregates of particles when the Fe/(Fe+Al) molar ratio is increased. The capacity of MOs for removing As(III) has been studied at different contact times in a batch reactor and in all cases removals of As(III) above 75% were achieved.
Fil: Heredia, Angelica Constanza. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Gómez Avila, Jenny. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Garay, Fernando Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Crivello, Mónica Elsie. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina - Materia
-
Electroanalisis
Hidroxidos Dobles Laminares
Arsenico
Swv - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/42881
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Cathodic stripping square-wave voltammetry for assessing As(III) removal with synthetic mixed oxidesHeredia, Angelica ConstanzaGómez Avila, JennyGaray, Fernando SebastianCrivello, Mónica ElsieElectroanalisisHidroxidos Dobles LaminaresArsenicoSwvhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The possibility of counting with a reliable and economic system for filtering large volumes of water contaminated with arsenic is highly desired since different species of this element conform a major health risk through contamination of drinking and irrigation water supplies. In this work, the adsorption of As(III) species from aqueous solutions onto Mixed Oxides (MOs) synthesized from Layered Double Hydroxides (LDHs) has been assessed by cathodic stripping Square-wave voltammetry (CS-SWV). This electrochemical technique provides the fast, reliable, and systematic analysis required for studding the numerous aqueous samples. The optimized protocol consisted on the accumulation of arsenic for 60 s at ?0.4 V, in presence of 0.5 mM Cu(II), 0.3 µM pyrrolidine dithiocarbamate (PDTC), and 0.9 M HCl, followed by a reductive scan to ?1.0 V. A stable and well-defined peak was observed at ?0.780 V, with a linear range that goes from 2 µg L?1 to 110 µg L?1 of As(III). A value of limit of detection (LOD) = 4 µgL?1 was calculated as 3 times the ratio between the standard deviation of the ordinate and slope of the linear regression curve. The presence of Cu(II) increases the signal of current and minimizes the effect of interfering species, while the ligand PDTC forms a complex that stabilizes the signal observed during the cathodic scan.A series of MgAlFe ternary LDHs with different iron content and their MOs have been synthesized by co-precipitation and characterized by diverse techniques. XPS and DRUV-Vis analysis showed that the Fe(III) ions can be found in tetrahedral and octahedral coordination environments, while SEM micrographs, evidenced the cluster formation and aggregates of particles when the Fe/(Fe+Al) molar ratio is increased. The capacity of MOs for removing As(III) has been studied at different contact times in a batch reactor and in all cases removals of As(III) above 75% were achieved.Fil: Heredia, Angelica Constanza. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Gómez Avila, Jenny. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Garay, Fernando Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Crivello, Mónica Elsie. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaSpringer2017-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/42881Heredia, Angelica Constanza; Gómez Avila, Jenny; Garay, Fernando Sebastian; Crivello, Mónica Elsie; Cathodic stripping square-wave voltammetry for assessing As(III) removal with synthetic mixed oxides; Springer; Journal of Solid State Electrochemistry (print); 21; 12; 11-2017; 3619-36291432-84881433-0768CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1007/s10008-017-3709-xinfo:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs10008-017-3709-xinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:44:07Zoai:ri.conicet.gov.ar:11336/42881instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:44:08.204CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Cathodic stripping square-wave voltammetry for assessing As(III) removal with synthetic mixed oxides |
title |
Cathodic stripping square-wave voltammetry for assessing As(III) removal with synthetic mixed oxides |
spellingShingle |
Cathodic stripping square-wave voltammetry for assessing As(III) removal with synthetic mixed oxides Heredia, Angelica Constanza Electroanalisis Hidroxidos Dobles Laminares Arsenico Swv |
title_short |
Cathodic stripping square-wave voltammetry for assessing As(III) removal with synthetic mixed oxides |
title_full |
Cathodic stripping square-wave voltammetry for assessing As(III) removal with synthetic mixed oxides |
title_fullStr |
Cathodic stripping square-wave voltammetry for assessing As(III) removal with synthetic mixed oxides |
title_full_unstemmed |
Cathodic stripping square-wave voltammetry for assessing As(III) removal with synthetic mixed oxides |
title_sort |
Cathodic stripping square-wave voltammetry for assessing As(III) removal with synthetic mixed oxides |
dc.creator.none.fl_str_mv |
Heredia, Angelica Constanza Gómez Avila, Jenny Garay, Fernando Sebastian Crivello, Mónica Elsie |
author |
Heredia, Angelica Constanza |
author_facet |
Heredia, Angelica Constanza Gómez Avila, Jenny Garay, Fernando Sebastian Crivello, Mónica Elsie |
author_role |
author |
author2 |
Gómez Avila, Jenny Garay, Fernando Sebastian Crivello, Mónica Elsie |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Electroanalisis Hidroxidos Dobles Laminares Arsenico Swv |
topic |
Electroanalisis Hidroxidos Dobles Laminares Arsenico Swv |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The possibility of counting with a reliable and economic system for filtering large volumes of water contaminated with arsenic is highly desired since different species of this element conform a major health risk through contamination of drinking and irrigation water supplies. In this work, the adsorption of As(III) species from aqueous solutions onto Mixed Oxides (MOs) synthesized from Layered Double Hydroxides (LDHs) has been assessed by cathodic stripping Square-wave voltammetry (CS-SWV). This electrochemical technique provides the fast, reliable, and systematic analysis required for studding the numerous aqueous samples. The optimized protocol consisted on the accumulation of arsenic for 60 s at ?0.4 V, in presence of 0.5 mM Cu(II), 0.3 µM pyrrolidine dithiocarbamate (PDTC), and 0.9 M HCl, followed by a reductive scan to ?1.0 V. A stable and well-defined peak was observed at ?0.780 V, with a linear range that goes from 2 µg L?1 to 110 µg L?1 of As(III). A value of limit of detection (LOD) = 4 µgL?1 was calculated as 3 times the ratio between the standard deviation of the ordinate and slope of the linear regression curve. The presence of Cu(II) increases the signal of current and minimizes the effect of interfering species, while the ligand PDTC forms a complex that stabilizes the signal observed during the cathodic scan.A series of MgAlFe ternary LDHs with different iron content and their MOs have been synthesized by co-precipitation and characterized by diverse techniques. XPS and DRUV-Vis analysis showed that the Fe(III) ions can be found in tetrahedral and octahedral coordination environments, while SEM micrographs, evidenced the cluster formation and aggregates of particles when the Fe/(Fe+Al) molar ratio is increased. The capacity of MOs for removing As(III) has been studied at different contact times in a batch reactor and in all cases removals of As(III) above 75% were achieved. Fil: Heredia, Angelica Constanza. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina Fil: Gómez Avila, Jenny. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina Fil: Garay, Fernando Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina Fil: Crivello, Mónica Elsie. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina |
description |
The possibility of counting with a reliable and economic system for filtering large volumes of water contaminated with arsenic is highly desired since different species of this element conform a major health risk through contamination of drinking and irrigation water supplies. In this work, the adsorption of As(III) species from aqueous solutions onto Mixed Oxides (MOs) synthesized from Layered Double Hydroxides (LDHs) has been assessed by cathodic stripping Square-wave voltammetry (CS-SWV). This electrochemical technique provides the fast, reliable, and systematic analysis required for studding the numerous aqueous samples. The optimized protocol consisted on the accumulation of arsenic for 60 s at ?0.4 V, in presence of 0.5 mM Cu(II), 0.3 µM pyrrolidine dithiocarbamate (PDTC), and 0.9 M HCl, followed by a reductive scan to ?1.0 V. A stable and well-defined peak was observed at ?0.780 V, with a linear range that goes from 2 µg L?1 to 110 µg L?1 of As(III). A value of limit of detection (LOD) = 4 µgL?1 was calculated as 3 times the ratio between the standard deviation of the ordinate and slope of the linear regression curve. The presence of Cu(II) increases the signal of current and minimizes the effect of interfering species, while the ligand PDTC forms a complex that stabilizes the signal observed during the cathodic scan.A series of MgAlFe ternary LDHs with different iron content and their MOs have been synthesized by co-precipitation and characterized by diverse techniques. XPS and DRUV-Vis analysis showed that the Fe(III) ions can be found in tetrahedral and octahedral coordination environments, while SEM micrographs, evidenced the cluster formation and aggregates of particles when the Fe/(Fe+Al) molar ratio is increased. The capacity of MOs for removing As(III) has been studied at different contact times in a batch reactor and in all cases removals of As(III) above 75% were achieved. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017-11 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/42881 Heredia, Angelica Constanza; Gómez Avila, Jenny; Garay, Fernando Sebastian; Crivello, Mónica Elsie; Cathodic stripping square-wave voltammetry for assessing As(III) removal with synthetic mixed oxides; Springer; Journal of Solid State Electrochemistry (print); 21; 12; 11-2017; 3619-3629 1432-8488 1433-0768 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/42881 |
identifier_str_mv |
Heredia, Angelica Constanza; Gómez Avila, Jenny; Garay, Fernando Sebastian; Crivello, Mónica Elsie; Cathodic stripping square-wave voltammetry for assessing As(III) removal with synthetic mixed oxides; Springer; Journal of Solid State Electrochemistry (print); 21; 12; 11-2017; 3619-3629 1432-8488 1433-0768 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1007/s10008-017-3709-x info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs10008-017-3709-x |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Springer |
publisher.none.fl_str_mv |
Springer |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613388947161088 |
score |
13.070432 |