Montmorillonite-alginate beads: Natural mineral and biopolymers based sorbent of paraquat herbicides
- Autores
- Etcheverry, Mariana; Cappa, Valeria Alejandra; Trelles, Jorge Abel; Zanini, Graciela Pilar
- Año de publicación
- 2017
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Beads of alginate montmorillonite have been used for the first time as sorbent of the cationic pesticide paraquat (PQ). They are a green material because they are formed by a biopolymer and a clay mineral, and because they allow using an energy efficient process to separate the beads after PQ adsorption. The general characterization of the beads, with montmorillonite contents ranging from 0% to 70%, has been carried out by elemental composition, FTIR and thermal analysis. The shape, external morphology and internal structure of the beads were examined by SEM. Wet beads were also observed with a digital camera. PQ adsorption was studied with adsorption isotherms from aqueous solutions, and maximum adsorption capacities (Qmax) were 0.093, 0.146, 0.187 and 0.278 mmol g−1 for montmorillonite contents of 0, 5, 30 and 70%, respectively. Qmax varied linearly with the clay content. The results show that montmorillonite is practically the only PQ sorbent, with alginate acting mainly as support of the clay particles, but playing a very important role allowing an effortless handling of the material and the adsorbed pollutant.
Fil: Etcheverry, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Cappa, Valeria Alejandra. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología. Laboratorio de Investigación en Biotecnología Sustentable; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Trelles, Jorge Abel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología. Laboratorio de Investigación en Biotecnología Sustentable; Argentina
Fil: Zanini, Graciela Pilar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina - Materia
-
Adsorption
Alginate
Beads
Montmorillonite
Paraquat - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/56510
Ver los metadatos del registro completo
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Montmorillonite-alginate beads: Natural mineral and biopolymers based sorbent of paraquat herbicidesEtcheverry, MarianaCappa, Valeria AlejandraTrelles, Jorge AbelZanini, Graciela PilarAdsorptionAlginateBeadsMontmorilloniteParaquathttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Beads of alginate montmorillonite have been used for the first time as sorbent of the cationic pesticide paraquat (PQ). They are a green material because they are formed by a biopolymer and a clay mineral, and because they allow using an energy efficient process to separate the beads after PQ adsorption. The general characterization of the beads, with montmorillonite contents ranging from 0% to 70%, has been carried out by elemental composition, FTIR and thermal analysis. The shape, external morphology and internal structure of the beads were examined by SEM. Wet beads were also observed with a digital camera. PQ adsorption was studied with adsorption isotherms from aqueous solutions, and maximum adsorption capacities (Qmax) were 0.093, 0.146, 0.187 and 0.278 mmol g−1 for montmorillonite contents of 0, 5, 30 and 70%, respectively. Qmax varied linearly with the clay content. The results show that montmorillonite is practically the only PQ sorbent, with alginate acting mainly as support of the clay particles, but playing a very important role allowing an effortless handling of the material and the adsorbed pollutant.Fil: Etcheverry, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Cappa, Valeria Alejandra. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología. Laboratorio de Investigación en Biotecnología Sustentable; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Trelles, Jorge Abel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología. Laboratorio de Investigación en Biotecnología Sustentable; ArgentinaFil: Zanini, Graciela Pilar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaElsevier Ltd2017-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/56510Etcheverry, Mariana; Cappa, Valeria Alejandra; Trelles, Jorge Abel; Zanini, Graciela Pilar; Montmorillonite-alginate beads: Natural mineral and biopolymers based sorbent of paraquat herbicides; Elsevier Ltd; Journal of Environmental Chemical Engineering; 5; 6; 12-2017; 5868-58752213-3437CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2213343717305766info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jece.2017.11.018info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:48:46Zoai:ri.conicet.gov.ar:11336/56510instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:48:47.006CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Montmorillonite-alginate beads: Natural mineral and biopolymers based sorbent of paraquat herbicides |
title |
Montmorillonite-alginate beads: Natural mineral and biopolymers based sorbent of paraquat herbicides |
spellingShingle |
Montmorillonite-alginate beads: Natural mineral and biopolymers based sorbent of paraquat herbicides Etcheverry, Mariana Adsorption Alginate Beads Montmorillonite Paraquat |
title_short |
Montmorillonite-alginate beads: Natural mineral and biopolymers based sorbent of paraquat herbicides |
title_full |
Montmorillonite-alginate beads: Natural mineral and biopolymers based sorbent of paraquat herbicides |
title_fullStr |
Montmorillonite-alginate beads: Natural mineral and biopolymers based sorbent of paraquat herbicides |
title_full_unstemmed |
Montmorillonite-alginate beads: Natural mineral and biopolymers based sorbent of paraquat herbicides |
title_sort |
Montmorillonite-alginate beads: Natural mineral and biopolymers based sorbent of paraquat herbicides |
dc.creator.none.fl_str_mv |
Etcheverry, Mariana Cappa, Valeria Alejandra Trelles, Jorge Abel Zanini, Graciela Pilar |
author |
Etcheverry, Mariana |
author_facet |
Etcheverry, Mariana Cappa, Valeria Alejandra Trelles, Jorge Abel Zanini, Graciela Pilar |
author_role |
author |
author2 |
Cappa, Valeria Alejandra Trelles, Jorge Abel Zanini, Graciela Pilar |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Adsorption Alginate Beads Montmorillonite Paraquat |
topic |
Adsorption Alginate Beads Montmorillonite Paraquat |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Beads of alginate montmorillonite have been used for the first time as sorbent of the cationic pesticide paraquat (PQ). They are a green material because they are formed by a biopolymer and a clay mineral, and because they allow using an energy efficient process to separate the beads after PQ adsorption. The general characterization of the beads, with montmorillonite contents ranging from 0% to 70%, has been carried out by elemental composition, FTIR and thermal analysis. The shape, external morphology and internal structure of the beads were examined by SEM. Wet beads were also observed with a digital camera. PQ adsorption was studied with adsorption isotherms from aqueous solutions, and maximum adsorption capacities (Qmax) were 0.093, 0.146, 0.187 and 0.278 mmol g−1 for montmorillonite contents of 0, 5, 30 and 70%, respectively. Qmax varied linearly with the clay content. The results show that montmorillonite is practically the only PQ sorbent, with alginate acting mainly as support of the clay particles, but playing a very important role allowing an effortless handling of the material and the adsorbed pollutant. Fil: Etcheverry, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina Fil: Cappa, Valeria Alejandra. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología. Laboratorio de Investigación en Biotecnología Sustentable; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Trelles, Jorge Abel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología. Laboratorio de Investigación en Biotecnología Sustentable; Argentina Fil: Zanini, Graciela Pilar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina |
description |
Beads of alginate montmorillonite have been used for the first time as sorbent of the cationic pesticide paraquat (PQ). They are a green material because they are formed by a biopolymer and a clay mineral, and because they allow using an energy efficient process to separate the beads after PQ adsorption. The general characterization of the beads, with montmorillonite contents ranging from 0% to 70%, has been carried out by elemental composition, FTIR and thermal analysis. The shape, external morphology and internal structure of the beads were examined by SEM. Wet beads were also observed with a digital camera. PQ adsorption was studied with adsorption isotherms from aqueous solutions, and maximum adsorption capacities (Qmax) were 0.093, 0.146, 0.187 and 0.278 mmol g−1 for montmorillonite contents of 0, 5, 30 and 70%, respectively. Qmax varied linearly with the clay content. The results show that montmorillonite is practically the only PQ sorbent, with alginate acting mainly as support of the clay particles, but playing a very important role allowing an effortless handling of the material and the adsorbed pollutant. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/56510 Etcheverry, Mariana; Cappa, Valeria Alejandra; Trelles, Jorge Abel; Zanini, Graciela Pilar; Montmorillonite-alginate beads: Natural mineral and biopolymers based sorbent of paraquat herbicides; Elsevier Ltd; Journal of Environmental Chemical Engineering; 5; 6; 12-2017; 5868-5875 2213-3437 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/56510 |
identifier_str_mv |
Etcheverry, Mariana; Cappa, Valeria Alejandra; Trelles, Jorge Abel; Zanini, Graciela Pilar; Montmorillonite-alginate beads: Natural mineral and biopolymers based sorbent of paraquat herbicides; Elsevier Ltd; Journal of Environmental Chemical Engineering; 5; 6; 12-2017; 5868-5875 2213-3437 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2213343717305766 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jece.2017.11.018 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Ltd |
publisher.none.fl_str_mv |
Elsevier Ltd |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842268939003887616 |
score |
13.13397 |