Bulk prepolymerization of styrene in the presence of polybutadiene: Determination of grafting efficiency by size exclusion chromatography combined with a new extended model

Autores
Casis, Natalia; Estenoz, Diana Alejandra; Vega, Jorge Ruben; Meira, Gregorio Raul
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The bulk prepolymerization of styrene in the presence of polybutadiene for the production of highimpact polystyrene is analyzed and compared with an equivalent solution reaction described by Estenoz et al. in 1999. The heterogeneous model reported by Casis et al. in 2006 is extended to predict the bivariate distributions of the graft copolymer topologies; each topology is characterized by the number of trifunctional branching points per molecule. The developed model assumes polymerization in two phases and requires the adjustment of a single kinetic parameter. Grafting efficiencies determined by solvent extraction/gravimetry are compared with determinations obtained by the deconvolution of size exclusion chromatograms of the total polymer. The chromatographic technique is fast and simple, but it requires a representative polymerization/fractionation model.
Fil: Casis, Natalia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico Para la Industria Química; Argentina
Fil: Estenoz, Diana Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico Para la Industria Química; Argentina
Fil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico Para la Industria Química; Argentina
Fil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico Para la Industria Química; Argentina
Materia
Gel Permeation Chromatography (Gpc)
Graft Copolymers
Modeling
Polystyrene
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/18572
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/18572
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Bulk prepolymerization of styrene in the presence of polybutadiene: Determination of grafting efficiency by size exclusion chromatography combined with a new extended modelCasis, NataliaEstenoz, Diana AlejandraVega, Jorge RubenMeira, Gregorio RaulGel Permeation Chromatography (Gpc)Graft CopolymersModelingPolystyrenehttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The bulk prepolymerization of styrene in the presence of polybutadiene for the production of highimpact polystyrene is analyzed and compared with an equivalent solution reaction described by Estenoz et al. in 1999. The heterogeneous model reported by Casis et al. in 2006 is extended to predict the bivariate distributions of the graft copolymer topologies; each topology is characterized by the number of trifunctional branching points per molecule. The developed model assumes polymerization in two phases and requires the adjustment of a single kinetic parameter. Grafting efficiencies determined by solvent extraction/gravimetry are compared with determinations obtained by the deconvolution of size exclusion chromatograms of the total polymer. The chromatographic technique is fast and simple, but it requires a representative polymerization/fractionation model.Fil: Casis, Natalia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico Para la Industria Química; ArgentinaFil: Estenoz, Diana Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico Para la Industria Química; ArgentinaFil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico Para la Industria Química; ArgentinaFil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico Para la Industria Química; ArgentinaJohn Wiley & Sons Inc2009-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/18572Casis, Natalia; Estenoz, Diana Alejandra; Vega, Jorge Ruben; Meira, Gregorio Raul; Bulk prepolymerization of styrene in the presence of polybutadiene: Determination of grafting efficiency by size exclusion chromatography combined with a new extended model; John Wiley & Sons Inc; Journal Of Applied Polymer Science; 111; 3; 1-2009; 1508-15220021-8995enginfo:eu-repo/semantics/altIdentifier/doi/10.1002/app.29137info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/app.29137/abstractinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:00:17Zoai:ri.conicet.gov.ar:11336/18572instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:00:18.206CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Bulk prepolymerization of styrene in the presence of polybutadiene: Determination of grafting efficiency by size exclusion chromatography combined with a new extended model
title Bulk prepolymerization of styrene in the presence of polybutadiene: Determination of grafting efficiency by size exclusion chromatography combined with a new extended model
spellingShingle Bulk prepolymerization of styrene in the presence of polybutadiene: Determination of grafting efficiency by size exclusion chromatography combined with a new extended model
Casis, Natalia
Gel Permeation Chromatography (Gpc)
Graft Copolymers
Modeling
Polystyrene
title_short Bulk prepolymerization of styrene in the presence of polybutadiene: Determination of grafting efficiency by size exclusion chromatography combined with a new extended model
title_full Bulk prepolymerization of styrene in the presence of polybutadiene: Determination of grafting efficiency by size exclusion chromatography combined with a new extended model
title_fullStr Bulk prepolymerization of styrene in the presence of polybutadiene: Determination of grafting efficiency by size exclusion chromatography combined with a new extended model
title_full_unstemmed Bulk prepolymerization of styrene in the presence of polybutadiene: Determination of grafting efficiency by size exclusion chromatography combined with a new extended model
title_sort Bulk prepolymerization of styrene in the presence of polybutadiene: Determination of grafting efficiency by size exclusion chromatography combined with a new extended model
dc.creator.none.fl_str_mv Casis, Natalia
Estenoz, Diana Alejandra
Vega, Jorge Ruben
Meira, Gregorio Raul
author Casis, Natalia
author_facet Casis, Natalia
Estenoz, Diana Alejandra
Vega, Jorge Ruben
Meira, Gregorio Raul
author_role author
author2 Estenoz, Diana Alejandra
Vega, Jorge Ruben
Meira, Gregorio Raul
author2_role author
author
author
dc.subject.none.fl_str_mv Gel Permeation Chromatography (Gpc)
Graft Copolymers
Modeling
Polystyrene
topic Gel Permeation Chromatography (Gpc)
Graft Copolymers
Modeling
Polystyrene
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The bulk prepolymerization of styrene in the presence of polybutadiene for the production of highimpact polystyrene is analyzed and compared with an equivalent solution reaction described by Estenoz et al. in 1999. The heterogeneous model reported by Casis et al. in 2006 is extended to predict the bivariate distributions of the graft copolymer topologies; each topology is characterized by the number of trifunctional branching points per molecule. The developed model assumes polymerization in two phases and requires the adjustment of a single kinetic parameter. Grafting efficiencies determined by solvent extraction/gravimetry are compared with determinations obtained by the deconvolution of size exclusion chromatograms of the total polymer. The chromatographic technique is fast and simple, but it requires a representative polymerization/fractionation model.
Fil: Casis, Natalia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico Para la Industria Química; Argentina
Fil: Estenoz, Diana Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico Para la Industria Química; Argentina
Fil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico Para la Industria Química; Argentina
Fil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico Para la Industria Química; Argentina
description The bulk prepolymerization of styrene in the presence of polybutadiene for the production of highimpact polystyrene is analyzed and compared with an equivalent solution reaction described by Estenoz et al. in 1999. The heterogeneous model reported by Casis et al. in 2006 is extended to predict the bivariate distributions of the graft copolymer topologies; each topology is characterized by the number of trifunctional branching points per molecule. The developed model assumes polymerization in two phases and requires the adjustment of a single kinetic parameter. Grafting efficiencies determined by solvent extraction/gravimetry are compared with determinations obtained by the deconvolution of size exclusion chromatograms of the total polymer. The chromatographic technique is fast and simple, but it requires a representative polymerization/fractionation model.
publishDate 2009
dc.date.none.fl_str_mv 2009-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/18572
Casis, Natalia; Estenoz, Diana Alejandra; Vega, Jorge Ruben; Meira, Gregorio Raul; Bulk prepolymerization of styrene in the presence of polybutadiene: Determination of grafting efficiency by size exclusion chromatography combined with a new extended model; John Wiley & Sons Inc; Journal Of Applied Polymer Science; 111; 3; 1-2009; 1508-1522
0021-8995
url http://hdl.handle.net/11336/18572
identifier_str_mv Casis, Natalia; Estenoz, Diana Alejandra; Vega, Jorge Ruben; Meira, Gregorio Raul; Bulk prepolymerization of styrene in the presence of polybutadiene: Determination of grafting efficiency by size exclusion chromatography combined with a new extended model; John Wiley & Sons Inc; Journal Of Applied Polymer Science; 111; 3; 1-2009; 1508-1522
0021-8995
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/app.29137
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/app.29137/abstract
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Inc
publisher.none.fl_str_mv John Wiley & Sons Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613782957981696
score 13.070432

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