The chemically ordered glass: the limiting composition for chemical order in amorphous packings of hard-sphere mixtures
- Autores
- Harrowell, Peter; Fernandez, Julian Roberto; Miracle, D. B.
- Año de publicación
- 2011
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- We consider the limits of chemical order (i.e. avoidance of solute-solute contact) in amorphous close-packed mixtures of hard spheres of two different sizes. The upper bound on the solute concentration, beyond which solute-solute contact cannot be avoided, is determined for a range of particle size ratios. Scaling the composition by this limiting value is found to collapse plots of the solute coordination and mixture energies as a function of composition for different values of size ratios onto a single master curve. A number of features of the behaviour of amorphous alloys in the vicinity of this limiting concentration are discussed.
Fil: Harrowell, Peter. University of Sydney; Australia
Fil: Fernandez, Julian Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; Argentina
Fil: Miracle, D. B.. Wright-Patterson Air Force Base; Estados Unidos - Materia
-
AMORPHOUS ALLOYS
GLASS TRANSITION
RANDOM CLOSE PACKING - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/192189
Ver los metadatos del registro completo
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spelling |
The chemically ordered glass: the limiting composition for chemical order in amorphous packings of hard-sphere mixturesHarrowell, PeterFernandez, Julian RobertoMiracle, D. B.AMORPHOUS ALLOYSGLASS TRANSITIONRANDOM CLOSE PACKINGhttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1We consider the limits of chemical order (i.e. avoidance of solute-solute contact) in amorphous close-packed mixtures of hard spheres of two different sizes. The upper bound on the solute concentration, beyond which solute-solute contact cannot be avoided, is determined for a range of particle size ratios. Scaling the composition by this limiting value is found to collapse plots of the solute coordination and mixture energies as a function of composition for different values of size ratios onto a single master curve. A number of features of the behaviour of amorphous alloys in the vicinity of this limiting concentration are discussed.Fil: Harrowell, Peter. University of Sydney; AustraliaFil: Fernandez, Julian Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; ArgentinaFil: Miracle, D. B.. Wright-Patterson Air Force Base; Estados UnidosTaylor & Francis Ltd2011-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/192189Harrowell, Peter; Fernandez, Julian Roberto; Miracle, D. B.; The chemically ordered glass: the limiting composition for chemical order in amorphous packings of hard-sphere mixtures; Taylor & Francis Ltd; Molecular Simulation; 37; 4; 3-2011; 293-2980892-7022CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1080/08927022.2010.548386info:eu-repo/semantics/altIdentifier/doi/10.1080/08927022.2010.548386info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:36:56Zoai:ri.conicet.gov.ar:11336/192189instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:36:56.478CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
The chemically ordered glass: the limiting composition for chemical order in amorphous packings of hard-sphere mixtures |
title |
The chemically ordered glass: the limiting composition for chemical order in amorphous packings of hard-sphere mixtures |
spellingShingle |
The chemically ordered glass: the limiting composition for chemical order in amorphous packings of hard-sphere mixtures Harrowell, Peter AMORPHOUS ALLOYS GLASS TRANSITION RANDOM CLOSE PACKING |
title_short |
The chemically ordered glass: the limiting composition for chemical order in amorphous packings of hard-sphere mixtures |
title_full |
The chemically ordered glass: the limiting composition for chemical order in amorphous packings of hard-sphere mixtures |
title_fullStr |
The chemically ordered glass: the limiting composition for chemical order in amorphous packings of hard-sphere mixtures |
title_full_unstemmed |
The chemically ordered glass: the limiting composition for chemical order in amorphous packings of hard-sphere mixtures |
title_sort |
The chemically ordered glass: the limiting composition for chemical order in amorphous packings of hard-sphere mixtures |
dc.creator.none.fl_str_mv |
Harrowell, Peter Fernandez, Julian Roberto Miracle, D. B. |
author |
Harrowell, Peter |
author_facet |
Harrowell, Peter Fernandez, Julian Roberto Miracle, D. B. |
author_role |
author |
author2 |
Fernandez, Julian Roberto Miracle, D. B. |
author2_role |
author author |
dc.subject.none.fl_str_mv |
AMORPHOUS ALLOYS GLASS TRANSITION RANDOM CLOSE PACKING |
topic |
AMORPHOUS ALLOYS GLASS TRANSITION RANDOM CLOSE PACKING |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.5 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
We consider the limits of chemical order (i.e. avoidance of solute-solute contact) in amorphous close-packed mixtures of hard spheres of two different sizes. The upper bound on the solute concentration, beyond which solute-solute contact cannot be avoided, is determined for a range of particle size ratios. Scaling the composition by this limiting value is found to collapse plots of the solute coordination and mixture energies as a function of composition for different values of size ratios onto a single master curve. A number of features of the behaviour of amorphous alloys in the vicinity of this limiting concentration are discussed. Fil: Harrowell, Peter. University of Sydney; Australia Fil: Fernandez, Julian Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; Argentina Fil: Miracle, D. B.. Wright-Patterson Air Force Base; Estados Unidos |
description |
We consider the limits of chemical order (i.e. avoidance of solute-solute contact) in amorphous close-packed mixtures of hard spheres of two different sizes. The upper bound on the solute concentration, beyond which solute-solute contact cannot be avoided, is determined for a range of particle size ratios. Scaling the composition by this limiting value is found to collapse plots of the solute coordination and mixture energies as a function of composition for different values of size ratios onto a single master curve. A number of features of the behaviour of amorphous alloys in the vicinity of this limiting concentration are discussed. |
publishDate |
2011 |
dc.date.none.fl_str_mv |
2011-03 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/192189 Harrowell, Peter; Fernandez, Julian Roberto; Miracle, D. B.; The chemically ordered glass: the limiting composition for chemical order in amorphous packings of hard-sphere mixtures; Taylor & Francis Ltd; Molecular Simulation; 37; 4; 3-2011; 293-298 0892-7022 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/192189 |
identifier_str_mv |
Harrowell, Peter; Fernandez, Julian Roberto; Miracle, D. B.; The chemically ordered glass: the limiting composition for chemical order in amorphous packings of hard-sphere mixtures; Taylor & Francis Ltd; Molecular Simulation; 37; 4; 3-2011; 293-298 0892-7022 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1080/08927022.2010.548386 info:eu-repo/semantics/altIdentifier/doi/10.1080/08927022.2010.548386 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Taylor & Francis Ltd |
publisher.none.fl_str_mv |
Taylor & Francis Ltd |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613161825599488 |
score |
13.070432 |