Exploring physical and chemical properties in new multifunctional indium-, bismuth-, and zinc-based 1D and 2D coordination polymers

Autores
Gomez, Germán Ernesto; D'Vries, R.F.; Lionello, Diego Fernando; Aguirre Díaz, L.M.; Spinosa, M.; Costa, C.S.; Fuertes, María Cecilia; Pizarro, R.A.; Kaczmarek, A.M.; Ellena, J.; Rozes, L.; Iglesias, M.; Van Deun, R.; Sanchez, C.; Monge, M.A.; Soler Illia, Galo Juan de Avila Arturo
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Main group element coordination polymers (MGE-CPs) are important compounds for the development of multifunctional materials. However, there has been a shortage of studies regarding their structural, optical, catalytic, mechanical, and antibacterial properties. This work presents an exhaustive study of a set of crystalline MGE-CPs obtained from bismuth and indium metals and iminodiacetate, 1,2,4,5-benzenetetracarboxylate, and 2,2′-bipyridine as building blocks. An in-depth topological analysis of the networks was carried out. Additionally, nanoindentation studies were performed on two representative low-dimensional compounds in order to find the relationships between their structural features and their intrinsic mechanical properties (hardness and elasticity). The solid-state photoluminescence (SSPL) properties were also studied in terms of excitation, emission, lifetimes values, and CIE chromaticites. Moreover, the heterogeneous catalytic activities of the compounds were evaluated with the cyanosilylation reaction using a set of carbonylic substrates under solvent-free conditions. Finally, the inhibitory effect of the Bi-CPs on the growth of microorganisms such as Escherichia coli, Salmonella enterica serovar Typhimurium, and Pseudomonas aeruginosa, which are associated with relevant infectious diseases, is reported.
Fil: Gomez, Germán Ernesto. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: D'Vries, R.F.. Universidad Santiago de Cali; Colombia. Universidade de Sao Paulo; Brasil
Fil: Lionello, Diego Fernando. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Instituto Sabato; Argentina
Fil: Aguirre Díaz, L.M.. Instituto de Ciencia de Materiales de Madrid; España
Fil: Spinosa, M.. Comisión Nacional de Energía Atómica; Argentina
Fil: Costa, C.S.. Comisión Nacional de Energía Atómica; Argentina
Fil: Fuertes, María Cecilia. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Pizarro, R.A.. Comisión Nacional de Energía Atómica; Argentina
Fil: Kaczmarek, A.M.. University of Ghent; Bélgica
Fil: Ellena, J.. Universidade de Sao Paulo; Brasil
Fil: Rozes, L.. Centre National de la Recherche Scientifique; Francia
Fil: Iglesias, M.. Instituto de Ciencia de Materiales de Madrid; España
Fil: Van Deun, R.. University of Ghent; Bélgica
Fil: Sanchez, C.. Centre National de la Recherche Scientifique; Francia
Fil: Monge, M.A.. Instituto de Ciencia de Materiales de Madrid; España
Fil: Soler Illia, Galo Juan de Avila Arturo. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
COORDINATION POLYMERS
MULTIFUNCTIONAL MATERIALS
CATALYSIS
MECHANICAL PROPERTIES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/117663
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/117663
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Exploring physical and chemical properties in new multifunctional indium-, bismuth-, and zinc-based 1D and 2D coordination polymersGomez, Germán ErnestoD'Vries, R.F.Lionello, Diego FernandoAguirre Díaz, L.M.Spinosa, M.Costa, C.S.Fuertes, María CeciliaPizarro, R.A.Kaczmarek, A.M.Ellena, J.Rozes, L.Iglesias, M.Van Deun, R.Sanchez, C.Monge, M.A.Soler Illia, Galo Juan de Avila ArturoCOORDINATION POLYMERSMULTIFUNCTIONAL MATERIALSCATALYSISMECHANICAL PROPERTIEShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Main group element coordination polymers (MGE-CPs) are important compounds for the development of multifunctional materials. However, there has been a shortage of studies regarding their structural, optical, catalytic, mechanical, and antibacterial properties. This work presents an exhaustive study of a set of crystalline MGE-CPs obtained from bismuth and indium metals and iminodiacetate, 1,2,4,5-benzenetetracarboxylate, and 2,2′-bipyridine as building blocks. An in-depth topological analysis of the networks was carried out. Additionally, nanoindentation studies were performed on two representative low-dimensional compounds in order to find the relationships between their structural features and their intrinsic mechanical properties (hardness and elasticity). The solid-state photoluminescence (SSPL) properties were also studied in terms of excitation, emission, lifetimes values, and CIE chromaticites. Moreover, the heterogeneous catalytic activities of the compounds were evaluated with the cyanosilylation reaction using a set of carbonylic substrates under solvent-free conditions. Finally, the inhibitory effect of the Bi-CPs on the growth of microorganisms such as Escherichia coli, Salmonella enterica serovar Typhimurium, and Pseudomonas aeruginosa, which are associated with relevant infectious diseases, is reported.Fil: Gomez, Germán Ernesto. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: D'Vries, R.F.. Universidad Santiago de Cali; Colombia. Universidade de Sao Paulo; BrasilFil: Lionello, Diego Fernando. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Instituto Sabato; ArgentinaFil: Aguirre Díaz, L.M.. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Spinosa, M.. Comisión Nacional de Energía Atómica; ArgentinaFil: Costa, C.S.. Comisión Nacional de Energía Atómica; ArgentinaFil: Fuertes, María Cecilia. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Pizarro, R.A.. Comisión Nacional de Energía Atómica; ArgentinaFil: Kaczmarek, A.M.. University of Ghent; BélgicaFil: Ellena, J.. Universidade de Sao Paulo; BrasilFil: Rozes, L.. Centre National de la Recherche Scientifique; FranciaFil: Iglesias, M.. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Van Deun, R.. University of Ghent; BélgicaFil: Sanchez, C.. Centre National de la Recherche Scientifique; FranciaFil: Monge, M.A.. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Soler Illia, Galo Juan de Avila Arturo. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaRoyal Society of Chemistry2018-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/117663Gomez, Germán Ernesto; D'Vries, R.F.; Lionello, Diego Fernando; Aguirre Díaz, L.M.; Spinosa, M.; et al.; Exploring physical and chemical properties in new multifunctional indium-, bismuth-, and zinc-based 1D and 2D coordination polymers; Royal Society of Chemistry; Dalton Transactions; 47; 6; 1-2018; 1808-18181477-9226CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2017/DT/C7DT04287Finfo:eu-repo/semantics/altIdentifier/doi/10.1039/C7DT04287Finfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:00:27Zoai:ri.conicet.gov.ar:11336/117663instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:00:28.154CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Exploring physical and chemical properties in new multifunctional indium-, bismuth-, and zinc-based 1D and 2D coordination polymers
title Exploring physical and chemical properties in new multifunctional indium-, bismuth-, and zinc-based 1D and 2D coordination polymers
spellingShingle Exploring physical and chemical properties in new multifunctional indium-, bismuth-, and zinc-based 1D and 2D coordination polymers
Gomez, Germán Ernesto
COORDINATION POLYMERS
MULTIFUNCTIONAL MATERIALS
CATALYSIS
MECHANICAL PROPERTIES
title_short Exploring physical and chemical properties in new multifunctional indium-, bismuth-, and zinc-based 1D and 2D coordination polymers
title_full Exploring physical and chemical properties in new multifunctional indium-, bismuth-, and zinc-based 1D and 2D coordination polymers
title_fullStr Exploring physical and chemical properties in new multifunctional indium-, bismuth-, and zinc-based 1D and 2D coordination polymers
title_full_unstemmed Exploring physical and chemical properties in new multifunctional indium-, bismuth-, and zinc-based 1D and 2D coordination polymers
title_sort Exploring physical and chemical properties in new multifunctional indium-, bismuth-, and zinc-based 1D and 2D coordination polymers
dc.creator.none.fl_str_mv Gomez, Germán Ernesto
D'Vries, R.F.
Lionello, Diego Fernando
Aguirre Díaz, L.M.
Spinosa, M.
Costa, C.S.
Fuertes, María Cecilia
Pizarro, R.A.
Kaczmarek, A.M.
Ellena, J.
Rozes, L.
Iglesias, M.
Van Deun, R.
Sanchez, C.
Monge, M.A.
Soler Illia, Galo Juan de Avila Arturo
author Gomez, Germán Ernesto
author_facet Gomez, Germán Ernesto
D'Vries, R.F.
Lionello, Diego Fernando
Aguirre Díaz, L.M.
Spinosa, M.
Costa, C.S.
Fuertes, María Cecilia
Pizarro, R.A.
Kaczmarek, A.M.
Ellena, J.
Rozes, L.
Iglesias, M.
Van Deun, R.
Sanchez, C.
Monge, M.A.
Soler Illia, Galo Juan de Avila Arturo
author_role author
author2 D'Vries, R.F.
Lionello, Diego Fernando
Aguirre Díaz, L.M.
Spinosa, M.
Costa, C.S.
Fuertes, María Cecilia
Pizarro, R.A.
Kaczmarek, A.M.
Ellena, J.
Rozes, L.
Iglesias, M.
Van Deun, R.
Sanchez, C.
Monge, M.A.
Soler Illia, Galo Juan de Avila Arturo
author2_role author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv COORDINATION POLYMERS
MULTIFUNCTIONAL MATERIALS
CATALYSIS
MECHANICAL PROPERTIES
topic COORDINATION POLYMERS
MULTIFUNCTIONAL MATERIALS
CATALYSIS
MECHANICAL PROPERTIES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Main group element coordination polymers (MGE-CPs) are important compounds for the development of multifunctional materials. However, there has been a shortage of studies regarding their structural, optical, catalytic, mechanical, and antibacterial properties. This work presents an exhaustive study of a set of crystalline MGE-CPs obtained from bismuth and indium metals and iminodiacetate, 1,2,4,5-benzenetetracarboxylate, and 2,2′-bipyridine as building blocks. An in-depth topological analysis of the networks was carried out. Additionally, nanoindentation studies were performed on two representative low-dimensional compounds in order to find the relationships between their structural features and their intrinsic mechanical properties (hardness and elasticity). The solid-state photoluminescence (SSPL) properties were also studied in terms of excitation, emission, lifetimes values, and CIE chromaticites. Moreover, the heterogeneous catalytic activities of the compounds were evaluated with the cyanosilylation reaction using a set of carbonylic substrates under solvent-free conditions. Finally, the inhibitory effect of the Bi-CPs on the growth of microorganisms such as Escherichia coli, Salmonella enterica serovar Typhimurium, and Pseudomonas aeruginosa, which are associated with relevant infectious diseases, is reported.
Fil: Gomez, Germán Ernesto. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: D'Vries, R.F.. Universidad Santiago de Cali; Colombia. Universidade de Sao Paulo; Brasil
Fil: Lionello, Diego Fernando. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Instituto Sabato; Argentina
Fil: Aguirre Díaz, L.M.. Instituto de Ciencia de Materiales de Madrid; España
Fil: Spinosa, M.. Comisión Nacional de Energía Atómica; Argentina
Fil: Costa, C.S.. Comisión Nacional de Energía Atómica; Argentina
Fil: Fuertes, María Cecilia. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Pizarro, R.A.. Comisión Nacional de Energía Atómica; Argentina
Fil: Kaczmarek, A.M.. University of Ghent; Bélgica
Fil: Ellena, J.. Universidade de Sao Paulo; Brasil
Fil: Rozes, L.. Centre National de la Recherche Scientifique; Francia
Fil: Iglesias, M.. Instituto de Ciencia de Materiales de Madrid; España
Fil: Van Deun, R.. University of Ghent; Bélgica
Fil: Sanchez, C.. Centre National de la Recherche Scientifique; Francia
Fil: Monge, M.A.. Instituto de Ciencia de Materiales de Madrid; España
Fil: Soler Illia, Galo Juan de Avila Arturo. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description Main group element coordination polymers (MGE-CPs) are important compounds for the development of multifunctional materials. However, there has been a shortage of studies regarding their structural, optical, catalytic, mechanical, and antibacterial properties. This work presents an exhaustive study of a set of crystalline MGE-CPs obtained from bismuth and indium metals and iminodiacetate, 1,2,4,5-benzenetetracarboxylate, and 2,2′-bipyridine as building blocks. An in-depth topological analysis of the networks was carried out. Additionally, nanoindentation studies were performed on two representative low-dimensional compounds in order to find the relationships between their structural features and their intrinsic mechanical properties (hardness and elasticity). The solid-state photoluminescence (SSPL) properties were also studied in terms of excitation, emission, lifetimes values, and CIE chromaticites. Moreover, the heterogeneous catalytic activities of the compounds were evaluated with the cyanosilylation reaction using a set of carbonylic substrates under solvent-free conditions. Finally, the inhibitory effect of the Bi-CPs on the growth of microorganisms such as Escherichia coli, Salmonella enterica serovar Typhimurium, and Pseudomonas aeruginosa, which are associated with relevant infectious diseases, is reported.
publishDate 2018
dc.date.none.fl_str_mv 2018-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/117663
Gomez, Germán Ernesto; D'Vries, R.F.; Lionello, Diego Fernando; Aguirre Díaz, L.M.; Spinosa, M.; et al.; Exploring physical and chemical properties in new multifunctional indium-, bismuth-, and zinc-based 1D and 2D coordination polymers; Royal Society of Chemistry; Dalton Transactions; 47; 6; 1-2018; 1808-1818
1477-9226
CONICET Digital
CONICET
url http://hdl.handle.net/11336/117663
identifier_str_mv Gomez, Germán Ernesto; D'Vries, R.F.; Lionello, Diego Fernando; Aguirre Díaz, L.M.; Spinosa, M.; et al.; Exploring physical and chemical properties in new multifunctional indium-, bismuth-, and zinc-based 1D and 2D coordination polymers; Royal Society of Chemistry; Dalton Transactions; 47; 6; 1-2018; 1808-1818
1477-9226
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
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info:eu-repo/semantics/altIdentifier/doi/10.1039/C7DT04287F
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
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eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
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reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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