Empirical viscous coefficients of dilute solutions of tetraethylene glycol dimethyl ether in 2-propanol and in 2-butanol at different temperatures

Autores
Aznarez, Silvia; Amid, Adrián; Ferreyra de Ruiz Holgado, Mercedes Marta Elsa; Arancibia, Eleuterio Luis
Año de publicación
2004
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This paper reports experimental viscosities and densities of binary mixtures containing tetraethylene glycol dimethyl ether+(2-propanol, 2-butanol) at four different temperatures (288.15, 298.15, 308.15 and 318.15 K), over the mole fraction (x) range of tetraethylene glycol dimethyl ether between 0 V x V 0.1 and at atmospheric pressure. The empirical coefficients (bG, cG and DG1,2*0) were determined from the viscosity values of the binary mixtures in the dilute zone of tetraethylene glycol dimethyl ether, using the Tamamushi – Isono empirical relationship between the thermodynamic function, DG1,2*0, with the mole fraction of tetraethylene glycol dimethyl ether (x) at a particular temperature. The Jones –Dole coefficient (B) was calculated in a graphical way. Both contributions, the energetic and the volumetric ones, to coefficient (B) were obtained. A comparative study of the Jones –Dole coefficient B and the coefficient bG of the solutions of tetraethylene glycol dimethyl ether in 2-alkanol with tetraethylene glycol dimethyl ether in 1-alkanol data, obtained from literature, was carried out. The results are discussed qualitatively using the rate process Eyring theory, applied to viscous flow.
Fil: Aznarez, Silvia. Universidad Nacional del Comahue; Argentina
Fil: Amid, Adrián. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Ingeniería en Procesos y Gestión Industrial; Argentina
Fil: Ferreyra de Ruiz Holgado, Mercedes Marta Elsa. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Ingeniería en Procesos y Gestión Industrial; Argentina
Fil: Arancibia, Eleuterio Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Ingeniería en Procesos y Gestión Industrial; Argentina
Materia
VISCOSITY
DENSITY
TETRAETHYLENEGLYCOL DIMETHYL ETHER
2-PROPANOL
2-BUTANOL
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/105654
Acceder
id CONICETDig_3844c5b8452346d6a2f668da98160361
oai_identifier_str oai:ri.conicet.gov.ar:11336/105654
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Empirical viscous coefficients of dilute solutions of tetraethylene glycol dimethyl ether in 2-propanol and in 2-butanol at different temperaturesAznarez, SilviaAmid, AdriánFerreyra de Ruiz Holgado, Mercedes Marta ElsaArancibia, Eleuterio LuisVISCOSITYDENSITYTETRAETHYLENEGLYCOL DIMETHYL ETHER2-PROPANOL2-BUTANOLhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1This paper reports experimental viscosities and densities of binary mixtures containing tetraethylene glycol dimethyl ether+(2-propanol, 2-butanol) at four different temperatures (288.15, 298.15, 308.15 and 318.15 K), over the mole fraction (x) range of tetraethylene glycol dimethyl ether between 0 V x V 0.1 and at atmospheric pressure. The empirical coefficients (bG, cG and DG1,2*0) were determined from the viscosity values of the binary mixtures in the dilute zone of tetraethylene glycol dimethyl ether, using the Tamamushi – Isono empirical relationship between the thermodynamic function, DG1,2*0, with the mole fraction of tetraethylene glycol dimethyl ether (x) at a particular temperature. The Jones –Dole coefficient (B) was calculated in a graphical way. Both contributions, the energetic and the volumetric ones, to coefficient (B) were obtained. A comparative study of the Jones –Dole coefficient B and the coefficient bG of the solutions of tetraethylene glycol dimethyl ether in 2-alkanol with tetraethylene glycol dimethyl ether in 1-alkanol data, obtained from literature, was carried out. The results are discussed qualitatively using the rate process Eyring theory, applied to viscous flow.Fil: Aznarez, Silvia. Universidad Nacional del Comahue; ArgentinaFil: Amid, Adrián. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Ingeniería en Procesos y Gestión Industrial; ArgentinaFil: Ferreyra de Ruiz Holgado, Mercedes Marta Elsa. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Ingeniería en Procesos y Gestión Industrial; ArgentinaFil: Arancibia, Eleuterio Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Ingeniería en Procesos y Gestión Industrial; ArgentinaElsevier Science2004-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/105654Aznarez, Silvia; Amid, Adrián; Ferreyra de Ruiz Holgado, Mercedes Marta Elsa; Arancibia, Eleuterio Luis; Empirical viscous coefficients of dilute solutions of tetraethylene glycol dimethyl ether in 2-propanol and in 2-butanol at different temperatures; Elsevier Science; Journal of Molecular Liquids; 115; 2-3; 11-2004; 69-740167-73221873-3166CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.molliq.2004.04.002info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0167732204001217info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:00:51Zoai:ri.conicet.gov.ar:11336/105654instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:00:51.577CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Empirical viscous coefficients of dilute solutions of tetraethylene glycol dimethyl ether in 2-propanol and in 2-butanol at different temperatures
title Empirical viscous coefficients of dilute solutions of tetraethylene glycol dimethyl ether in 2-propanol and in 2-butanol at different temperatures
spellingShingle Empirical viscous coefficients of dilute solutions of tetraethylene glycol dimethyl ether in 2-propanol and in 2-butanol at different temperatures
Aznarez, Silvia
VISCOSITY
DENSITY
TETRAETHYLENEGLYCOL DIMETHYL ETHER
2-PROPANOL
2-BUTANOL
title_short Empirical viscous coefficients of dilute solutions of tetraethylene glycol dimethyl ether in 2-propanol and in 2-butanol at different temperatures
title_full Empirical viscous coefficients of dilute solutions of tetraethylene glycol dimethyl ether in 2-propanol and in 2-butanol at different temperatures
title_fullStr Empirical viscous coefficients of dilute solutions of tetraethylene glycol dimethyl ether in 2-propanol and in 2-butanol at different temperatures
title_full_unstemmed Empirical viscous coefficients of dilute solutions of tetraethylene glycol dimethyl ether in 2-propanol and in 2-butanol at different temperatures
title_sort Empirical viscous coefficients of dilute solutions of tetraethylene glycol dimethyl ether in 2-propanol and in 2-butanol at different temperatures
dc.creator.none.fl_str_mv Aznarez, Silvia
Amid, Adrián
Ferreyra de Ruiz Holgado, Mercedes Marta Elsa
Arancibia, Eleuterio Luis
author Aznarez, Silvia
author_facet Aznarez, Silvia
Amid, Adrián
Ferreyra de Ruiz Holgado, Mercedes Marta Elsa
Arancibia, Eleuterio Luis
author_role author
author2 Amid, Adrián
Ferreyra de Ruiz Holgado, Mercedes Marta Elsa
Arancibia, Eleuterio Luis
author2_role author
author
author
dc.subject.none.fl_str_mv VISCOSITY
DENSITY
TETRAETHYLENEGLYCOL DIMETHYL ETHER
2-PROPANOL
2-BUTANOL
topic VISCOSITY
DENSITY
TETRAETHYLENEGLYCOL DIMETHYL ETHER
2-PROPANOL
2-BUTANOL
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv This paper reports experimental viscosities and densities of binary mixtures containing tetraethylene glycol dimethyl ether+(2-propanol, 2-butanol) at four different temperatures (288.15, 298.15, 308.15 and 318.15 K), over the mole fraction (x) range of tetraethylene glycol dimethyl ether between 0 V x V 0.1 and at atmospheric pressure. The empirical coefficients (bG, cG and DG1,2*0) were determined from the viscosity values of the binary mixtures in the dilute zone of tetraethylene glycol dimethyl ether, using the Tamamushi – Isono empirical relationship between the thermodynamic function, DG1,2*0, with the mole fraction of tetraethylene glycol dimethyl ether (x) at a particular temperature. The Jones –Dole coefficient (B) was calculated in a graphical way. Both contributions, the energetic and the volumetric ones, to coefficient (B) were obtained. A comparative study of the Jones –Dole coefficient B and the coefficient bG of the solutions of tetraethylene glycol dimethyl ether in 2-alkanol with tetraethylene glycol dimethyl ether in 1-alkanol data, obtained from literature, was carried out. The results are discussed qualitatively using the rate process Eyring theory, applied to viscous flow.
Fil: Aznarez, Silvia. Universidad Nacional del Comahue; Argentina
Fil: Amid, Adrián. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Ingeniería en Procesos y Gestión Industrial; Argentina
Fil: Ferreyra de Ruiz Holgado, Mercedes Marta Elsa. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Ingeniería en Procesos y Gestión Industrial; Argentina
Fil: Arancibia, Eleuterio Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Ingeniería en Procesos y Gestión Industrial; Argentina
description This paper reports experimental viscosities and densities of binary mixtures containing tetraethylene glycol dimethyl ether+(2-propanol, 2-butanol) at four different temperatures (288.15, 298.15, 308.15 and 318.15 K), over the mole fraction (x) range of tetraethylene glycol dimethyl ether between 0 V x V 0.1 and at atmospheric pressure. The empirical coefficients (bG, cG and DG1,2*0) were determined from the viscosity values of the binary mixtures in the dilute zone of tetraethylene glycol dimethyl ether, using the Tamamushi – Isono empirical relationship between the thermodynamic function, DG1,2*0, with the mole fraction of tetraethylene glycol dimethyl ether (x) at a particular temperature. The Jones –Dole coefficient (B) was calculated in a graphical way. Both contributions, the energetic and the volumetric ones, to coefficient (B) were obtained. A comparative study of the Jones –Dole coefficient B and the coefficient bG of the solutions of tetraethylene glycol dimethyl ether in 2-alkanol with tetraethylene glycol dimethyl ether in 1-alkanol data, obtained from literature, was carried out. The results are discussed qualitatively using the rate process Eyring theory, applied to viscous flow.
publishDate 2004
dc.date.none.fl_str_mv 2004-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/105654
Aznarez, Silvia; Amid, Adrián; Ferreyra de Ruiz Holgado, Mercedes Marta Elsa; Arancibia, Eleuterio Luis; Empirical viscous coefficients of dilute solutions of tetraethylene glycol dimethyl ether in 2-propanol and in 2-butanol at different temperatures; Elsevier Science; Journal of Molecular Liquids; 115; 2-3; 11-2004; 69-74
0167-7322
1873-3166
CONICET Digital
CONICET
url http://hdl.handle.net/11336/105654
identifier_str_mv Aznarez, Silvia; Amid, Adrián; Ferreyra de Ruiz Holgado, Mercedes Marta Elsa; Arancibia, Eleuterio Luis; Empirical viscous coefficients of dilute solutions of tetraethylene glycol dimethyl ether in 2-propanol and in 2-butanol at different temperatures; Elsevier Science; Journal of Molecular Liquids; 115; 2-3; 11-2004; 69-74
0167-7322
1873-3166
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.molliq.2004.04.002
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0167732204001217
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269663299371008
score 13.13397

Publicaciones similares