Experimental study of tautomeric equilibria of 2-cyanobenzoic acids in gas, solution and solid phase

Autores
Iglesias, Dacio Adhemar; Ruiz, Danila Luján; Allegretti, Patricia Ercilia
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
2-cyanobenzoic acids are very important compounds in several sciences, and it is because of this that studying their tautomeric equilibria is of great interest. Ring-chain tautomeric equilibria of 2-, 3- and 4- cyanobenzoic, 3-benzyl-2-cyanobenzoic and 1-cyano-2-naphthoic acids were studied in gas phase by means of mass spectrometry (MS). Furthermore, evidences of ring-chain tautomerism of 2-cyanobenzoic acid were found in solution using 1H and 13C nuclear magnetic resonance and in solid phase by infrared spectroscopy.
Fil: Iglesias, Dacio Adhemar. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina
Fil: Ruiz, Danila Luján. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina
Fil: Allegretti, Patricia Ercilia. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina
Materia
Cyanobenzoic acids
mass spectrometry
NMR
infrared spectroscopy
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/95562
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Experimental study of tautomeric equilibria of 2-cyanobenzoic acids in gas, solution and solid phaseIglesias, Dacio AdhemarRuiz, Danila LujánAllegretti, Patricia ErciliaCyanobenzoic acidsmass spectrometryNMRinfrared spectroscopyhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/12-cyanobenzoic acids are very important compounds in several sciences, and it is because of this that studying their tautomeric equilibria is of great interest. Ring-chain tautomeric equilibria of 2-, 3- and 4- cyanobenzoic, 3-benzyl-2-cyanobenzoic and 1-cyano-2-naphthoic acids were studied in gas phase by means of mass spectrometry (MS). Furthermore, evidences of ring-chain tautomerism of 2-cyanobenzoic acid were found in solution using 1H and 13C nuclear magnetic resonance and in solid phase by infrared spectroscopy.Fil: Iglesias, Dacio Adhemar. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; ArgentinaFil: Ruiz, Danila Luján. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; ArgentinaFil: Allegretti, Patricia Ercilia. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; ArgentinaLifescience Global2012-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/95562Iglesias, Dacio Adhemar; Ruiz, Danila Luján; Allegretti, Patricia Ercilia; Experimental study of tautomeric equilibria of 2-cyanobenzoic acids in gas, solution and solid phase; Lifescience Global; Journal of Applied Solution Chemistry and Modeling; 1; 2; 12-2012; 113-1201929-5030CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.lifescienceglobal.com/pms/index.php/JASCM/article/view/709info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-26T08:58:58Zoai:ri.conicet.gov.ar:11336/95562instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-26 08:58:58.914CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Experimental study of tautomeric equilibria of 2-cyanobenzoic acids in gas, solution and solid phase
title Experimental study of tautomeric equilibria of 2-cyanobenzoic acids in gas, solution and solid phase
spellingShingle Experimental study of tautomeric equilibria of 2-cyanobenzoic acids in gas, solution and solid phase
Iglesias, Dacio Adhemar
Cyanobenzoic acids
mass spectrometry
NMR
infrared spectroscopy
title_short Experimental study of tautomeric equilibria of 2-cyanobenzoic acids in gas, solution and solid phase
title_full Experimental study of tautomeric equilibria of 2-cyanobenzoic acids in gas, solution and solid phase
title_fullStr Experimental study of tautomeric equilibria of 2-cyanobenzoic acids in gas, solution and solid phase
title_full_unstemmed Experimental study of tautomeric equilibria of 2-cyanobenzoic acids in gas, solution and solid phase
title_sort Experimental study of tautomeric equilibria of 2-cyanobenzoic acids in gas, solution and solid phase
dc.creator.none.fl_str_mv Iglesias, Dacio Adhemar
Ruiz, Danila Luján
Allegretti, Patricia Ercilia
author Iglesias, Dacio Adhemar
author_facet Iglesias, Dacio Adhemar
Ruiz, Danila Luján
Allegretti, Patricia Ercilia
author_role author
author2 Ruiz, Danila Luján
Allegretti, Patricia Ercilia
author2_role author
author
dc.subject.none.fl_str_mv Cyanobenzoic acids
mass spectrometry
NMR
infrared spectroscopy
topic Cyanobenzoic acids
mass spectrometry
NMR
infrared spectroscopy
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv 2-cyanobenzoic acids are very important compounds in several sciences, and it is because of this that studying their tautomeric equilibria is of great interest. Ring-chain tautomeric equilibria of 2-, 3- and 4- cyanobenzoic, 3-benzyl-2-cyanobenzoic and 1-cyano-2-naphthoic acids were studied in gas phase by means of mass spectrometry (MS). Furthermore, evidences of ring-chain tautomerism of 2-cyanobenzoic acid were found in solution using 1H and 13C nuclear magnetic resonance and in solid phase by infrared spectroscopy.
Fil: Iglesias, Dacio Adhemar. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina
Fil: Ruiz, Danila Luján. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina
Fil: Allegretti, Patricia Ercilia. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina
description 2-cyanobenzoic acids are very important compounds in several sciences, and it is because of this that studying their tautomeric equilibria is of great interest. Ring-chain tautomeric equilibria of 2-, 3- and 4- cyanobenzoic, 3-benzyl-2-cyanobenzoic and 1-cyano-2-naphthoic acids were studied in gas phase by means of mass spectrometry (MS). Furthermore, evidences of ring-chain tautomerism of 2-cyanobenzoic acid were found in solution using 1H and 13C nuclear magnetic resonance and in solid phase by infrared spectroscopy.
publishDate 2012
dc.date.none.fl_str_mv 2012-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/95562
Iglesias, Dacio Adhemar; Ruiz, Danila Luján; Allegretti, Patricia Ercilia; Experimental study of tautomeric equilibria of 2-cyanobenzoic acids in gas, solution and solid phase; Lifescience Global; Journal of Applied Solution Chemistry and Modeling; 1; 2; 12-2012; 113-120
1929-5030
CONICET Digital
CONICET
url http://hdl.handle.net/11336/95562
identifier_str_mv Iglesias, Dacio Adhemar; Ruiz, Danila Luján; Allegretti, Patricia Ercilia; Experimental study of tautomeric equilibria of 2-cyanobenzoic acids in gas, solution and solid phase; Lifescience Global; Journal of Applied Solution Chemistry and Modeling; 1; 2; 12-2012; 113-120
1929-5030
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.lifescienceglobal.com/pms/index.php/JASCM/article/view/709
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Lifescience Global
publisher.none.fl_str_mv Lifescience Global
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.011256

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