Study of an energy-integrated biodiesel production process using supercritical methanol and a low-cost feedstock

Autores
Manuale, Débora Laura; Torres, Gerardo Carlos; Vera, Carlos Roman; Yori, Juan Carlos
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The supercritical biodiesel production process has some disadvantages such as: high reaction temperature,large molar methanol-to-oil ratios (R) and large energy consumption. To mitigate these problems, an energy integrated process in which biodiesel is obtained in a continuous tubular reactor operating at a reaction temperature of 280°C, R=20, a residence time of 1h and a pressure of 110bar, is proposed. A low-cost lipid feedstock (chicken oil) was used as raw material for testing the process. The enthalpy content of the stream exiting thesupercritical reactor was used to eliminate the unreacted methanol in an adiabatic flash drum. The operating conditions of the adiabatic flash were optimized to meet the specification of water and methanol content in the biodiesel phase and minimize the ester and acid content in the vapor phase. These conditions were: P=0.1bar and T=178°C. For these conditions the methanol content is 88?90% in the vapor phase and lower than 0.2% in the biodiesel phase. A scheme was developed for an energy integrated process maximizing the heat recovery. Composition, temperature and pressure of the streams were determined and also the amount of heat exchanged in each unit. In order to fulfill the quality restrictions the final content of FFA in the biodiesel product had to befurther adjusted by adsorption over bleaching silica.
Fil: Manuale, Débora Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Torres, Gerardo Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Vera, Carlos Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Yori, Juan Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
BIODIESEL
LOW COST FEEDSTOCKS
ENERGY INTEGRATED PROCCESS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/113454
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/113454
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Study of an energy-integrated biodiesel production process using supercritical methanol and a low-cost feedstockManuale, Débora LauraTorres, Gerardo CarlosVera, Carlos RomanYori, Juan CarlosBIODIESELLOW COST FEEDSTOCKSENERGY INTEGRATED PROCCESShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The supercritical biodiesel production process has some disadvantages such as: high reaction temperature,large molar methanol-to-oil ratios (R) and large energy consumption. To mitigate these problems, an energy integrated process in which biodiesel is obtained in a continuous tubular reactor operating at a reaction temperature of 280°C, R=20, a residence time of 1h and a pressure of 110bar, is proposed. A low-cost lipid feedstock (chicken oil) was used as raw material for testing the process. The enthalpy content of the stream exiting thesupercritical reactor was used to eliminate the unreacted methanol in an adiabatic flash drum. The operating conditions of the adiabatic flash were optimized to meet the specification of water and methanol content in the biodiesel phase and minimize the ester and acid content in the vapor phase. These conditions were: P=0.1bar and T=178°C. For these conditions the methanol content is 88?90% in the vapor phase and lower than 0.2% in the biodiesel phase. A scheme was developed for an energy integrated process maximizing the heat recovery. Composition, temperature and pressure of the streams were determined and also the amount of heat exchanged in each unit. In order to fulfill the quality restrictions the final content of FFA in the biodiesel product had to befurther adjusted by adsorption over bleaching silica.Fil: Manuale, Débora Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Torres, Gerardo Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Vera, Carlos Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Yori, Juan Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2015-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/113454Manuale, Débora Laura; Torres, Gerardo Carlos; Vera, Carlos Roman; Yori, Juan Carlos; Study of an energy-integrated biodiesel production process using supercritical methanol and a low-cost feedstock; Elsevier Science; Fuel Processing Technology; 140; 8-2015; 252-2610378-3820CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.fuproc.2015.08.026info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:01:37Zoai:ri.conicet.gov.ar:11336/113454instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:01:37.549CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Study of an energy-integrated biodiesel production process using supercritical methanol and a low-cost feedstock
title Study of an energy-integrated biodiesel production process using supercritical methanol and a low-cost feedstock
spellingShingle Study of an energy-integrated biodiesel production process using supercritical methanol and a low-cost feedstock
Manuale, Débora Laura
BIODIESEL
LOW COST FEEDSTOCKS
ENERGY INTEGRATED PROCCESS
title_short Study of an energy-integrated biodiesel production process using supercritical methanol and a low-cost feedstock
title_full Study of an energy-integrated biodiesel production process using supercritical methanol and a low-cost feedstock
title_fullStr Study of an energy-integrated biodiesel production process using supercritical methanol and a low-cost feedstock
title_full_unstemmed Study of an energy-integrated biodiesel production process using supercritical methanol and a low-cost feedstock
title_sort Study of an energy-integrated biodiesel production process using supercritical methanol and a low-cost feedstock
dc.creator.none.fl_str_mv Manuale, Débora Laura
Torres, Gerardo Carlos
Vera, Carlos Roman
Yori, Juan Carlos
author Manuale, Débora Laura
author_facet Manuale, Débora Laura
Torres, Gerardo Carlos
Vera, Carlos Roman
Yori, Juan Carlos
author_role author
author2 Torres, Gerardo Carlos
Vera, Carlos Roman
Yori, Juan Carlos
author2_role author
author
author
dc.subject.none.fl_str_mv BIODIESEL
LOW COST FEEDSTOCKS
ENERGY INTEGRATED PROCCESS
topic BIODIESEL
LOW COST FEEDSTOCKS
ENERGY INTEGRATED PROCCESS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The supercritical biodiesel production process has some disadvantages such as: high reaction temperature,large molar methanol-to-oil ratios (R) and large energy consumption. To mitigate these problems, an energy integrated process in which biodiesel is obtained in a continuous tubular reactor operating at a reaction temperature of 280°C, R=20, a residence time of 1h and a pressure of 110bar, is proposed. A low-cost lipid feedstock (chicken oil) was used as raw material for testing the process. The enthalpy content of the stream exiting thesupercritical reactor was used to eliminate the unreacted methanol in an adiabatic flash drum. The operating conditions of the adiabatic flash were optimized to meet the specification of water and methanol content in the biodiesel phase and minimize the ester and acid content in the vapor phase. These conditions were: P=0.1bar and T=178°C. For these conditions the methanol content is 88?90% in the vapor phase and lower than 0.2% in the biodiesel phase. A scheme was developed for an energy integrated process maximizing the heat recovery. Composition, temperature and pressure of the streams were determined and also the amount of heat exchanged in each unit. In order to fulfill the quality restrictions the final content of FFA in the biodiesel product had to befurther adjusted by adsorption over bleaching silica.
Fil: Manuale, Débora Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Torres, Gerardo Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Vera, Carlos Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Yori, Juan Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description The supercritical biodiesel production process has some disadvantages such as: high reaction temperature,large molar methanol-to-oil ratios (R) and large energy consumption. To mitigate these problems, an energy integrated process in which biodiesel is obtained in a continuous tubular reactor operating at a reaction temperature of 280°C, R=20, a residence time of 1h and a pressure of 110bar, is proposed. A low-cost lipid feedstock (chicken oil) was used as raw material for testing the process. The enthalpy content of the stream exiting thesupercritical reactor was used to eliminate the unreacted methanol in an adiabatic flash drum. The operating conditions of the adiabatic flash were optimized to meet the specification of water and methanol content in the biodiesel phase and minimize the ester and acid content in the vapor phase. These conditions were: P=0.1bar and T=178°C. For these conditions the methanol content is 88?90% in the vapor phase and lower than 0.2% in the biodiesel phase. A scheme was developed for an energy integrated process maximizing the heat recovery. Composition, temperature and pressure of the streams were determined and also the amount of heat exchanged in each unit. In order to fulfill the quality restrictions the final content of FFA in the biodiesel product had to befurther adjusted by adsorption over bleaching silica.
publishDate 2015
dc.date.none.fl_str_mv 2015-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/113454
Manuale, Débora Laura; Torres, Gerardo Carlos; Vera, Carlos Roman; Yori, Juan Carlos; Study of an energy-integrated biodiesel production process using supercritical methanol and a low-cost feedstock; Elsevier Science; Fuel Processing Technology; 140; 8-2015; 252-261
0378-3820
CONICET Digital
CONICET
url http://hdl.handle.net/11336/113454
identifier_str_mv Manuale, Débora Laura; Torres, Gerardo Carlos; Vera, Carlos Roman; Yori, Juan Carlos; Study of an energy-integrated biodiesel production process using supercritical methanol and a low-cost feedstock; Elsevier Science; Fuel Processing Technology; 140; 8-2015; 252-261
0378-3820
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.fuproc.2015.08.026
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.993085

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