Mechanical Properties Enhancement in Potassium-Sodium Niobate Lead-free Piezoceramics: The impact of chemical modifications

Autores
Ramajo, Leandro Alfredo; Castro, Miriam Susana; Fernandez, José; Rubio Marcos, Fernado
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The development of (K0.44Na0.52Li0.04)(Nb0.86Ta0.10Sb0.04)O3-based (KNL-NTS) ceramics is attracting great interest because of environmental concerns. Most of the efforts have been concentrated on improving the electrical properties. However, it is desirable to develop ceramics with good electrical response and high mechanical properties. Therefore, the evaluation of the mechanical properties is substantial and little studied. The aim of this work is to study the mechanical properties of KNL-NTS lead free ceramics doped with Zr evaluating the effects that can give rise to improved mechanical properties. Our results show that the crystalline phase, size and shape of grains in the ceramics are affected by the doping amount. We found that the microstructure does have a close relationship to the mechanical response, more specifically; a uniform and fine grain microstructure is suitable to lead high mechanical strength. Based on these results, the chemical modifications with Zr+4 ions have a significantly positive influence on hardness, strength and fracture toughness values of KNL-NTS ceramics.
Fil: Ramajo, Leandro Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Castro, Miriam Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Fernandez, José. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Rubio Marcos, Fernado. Instituto de Ceramica y Vidrio de Madrid; España
Materia
Lead Free Ceramics
Piezoelectrics
Ferroelectrics
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/44315

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spelling Mechanical Properties Enhancement in Potassium-Sodium Niobate Lead-free Piezoceramics: The impact of chemical modificationsRamajo, Leandro AlfredoCastro, Miriam SusanaFernandez, JoséRubio Marcos, FernadoLead Free CeramicsPiezoelectricsFerroelectricshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The development of (K0.44Na0.52Li0.04)(Nb0.86Ta0.10Sb0.04)O3-based (KNL-NTS) ceramics is attracting great interest because of environmental concerns. Most of the efforts have been concentrated on improving the electrical properties. However, it is desirable to develop ceramics with good electrical response and high mechanical properties. Therefore, the evaluation of the mechanical properties is substantial and little studied. The aim of this work is to study the mechanical properties of KNL-NTS lead free ceramics doped with Zr evaluating the effects that can give rise to improved mechanical properties. Our results show that the crystalline phase, size and shape of grains in the ceramics are affected by the doping amount. We found that the microstructure does have a close relationship to the mechanical response, more specifically; a uniform and fine grain microstructure is suitable to lead high mechanical strength. Based on these results, the chemical modifications with Zr+4 ions have a significantly positive influence on hardness, strength and fracture toughness values of KNL-NTS ceramics.Fil: Ramajo, Leandro Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Castro, Miriam Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Fernandez, José. Instituto de Ceramica y Vidrio de Madrid; EspañaFil: Rubio Marcos, Fernado. Instituto de Ceramica y Vidrio de Madrid; EspañaSpringer2016-12-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/44315Ramajo, Leandro Alfredo; Castro, Miriam Susana; Fernandez, José; Rubio Marcos, Fernado; Mechanical Properties Enhancement in Potassium-Sodium Niobate Lead-free Piezoceramics: The impact of chemical modifications; Springer; Journal of Materials Science: Materials in Electronics; 28; 7; 15-12-2016; 5128-51340957-4522CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1007/s10854-016-6168-8info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs10854-016-6168-8info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-29T11:51:59Zoai:ri.conicet.gov.ar:11336/44315instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-29 11:52:00.101CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Mechanical Properties Enhancement in Potassium-Sodium Niobate Lead-free Piezoceramics: The impact of chemical modifications
title Mechanical Properties Enhancement in Potassium-Sodium Niobate Lead-free Piezoceramics: The impact of chemical modifications
spellingShingle Mechanical Properties Enhancement in Potassium-Sodium Niobate Lead-free Piezoceramics: The impact of chemical modifications
Ramajo, Leandro Alfredo
Lead Free Ceramics
Piezoelectrics
Ferroelectrics
title_short Mechanical Properties Enhancement in Potassium-Sodium Niobate Lead-free Piezoceramics: The impact of chemical modifications
title_full Mechanical Properties Enhancement in Potassium-Sodium Niobate Lead-free Piezoceramics: The impact of chemical modifications
title_fullStr Mechanical Properties Enhancement in Potassium-Sodium Niobate Lead-free Piezoceramics: The impact of chemical modifications
title_full_unstemmed Mechanical Properties Enhancement in Potassium-Sodium Niobate Lead-free Piezoceramics: The impact of chemical modifications
title_sort Mechanical Properties Enhancement in Potassium-Sodium Niobate Lead-free Piezoceramics: The impact of chemical modifications
dc.creator.none.fl_str_mv Ramajo, Leandro Alfredo
Castro, Miriam Susana
Fernandez, José
Rubio Marcos, Fernado
author Ramajo, Leandro Alfredo
author_facet Ramajo, Leandro Alfredo
Castro, Miriam Susana
Fernandez, José
Rubio Marcos, Fernado
author_role author
author2 Castro, Miriam Susana
Fernandez, José
Rubio Marcos, Fernado
author2_role author
author
author
dc.subject.none.fl_str_mv Lead Free Ceramics
Piezoelectrics
Ferroelectrics
topic Lead Free Ceramics
Piezoelectrics
Ferroelectrics
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The development of (K0.44Na0.52Li0.04)(Nb0.86Ta0.10Sb0.04)O3-based (KNL-NTS) ceramics is attracting great interest because of environmental concerns. Most of the efforts have been concentrated on improving the electrical properties. However, it is desirable to develop ceramics with good electrical response and high mechanical properties. Therefore, the evaluation of the mechanical properties is substantial and little studied. The aim of this work is to study the mechanical properties of KNL-NTS lead free ceramics doped with Zr evaluating the effects that can give rise to improved mechanical properties. Our results show that the crystalline phase, size and shape of grains in the ceramics are affected by the doping amount. We found that the microstructure does have a close relationship to the mechanical response, more specifically; a uniform and fine grain microstructure is suitable to lead high mechanical strength. Based on these results, the chemical modifications with Zr+4 ions have a significantly positive influence on hardness, strength and fracture toughness values of KNL-NTS ceramics.
Fil: Ramajo, Leandro Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Castro, Miriam Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Fernandez, José. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Rubio Marcos, Fernado. Instituto de Ceramica y Vidrio de Madrid; España
description The development of (K0.44Na0.52Li0.04)(Nb0.86Ta0.10Sb0.04)O3-based (KNL-NTS) ceramics is attracting great interest because of environmental concerns. Most of the efforts have been concentrated on improving the electrical properties. However, it is desirable to develop ceramics with good electrical response and high mechanical properties. Therefore, the evaluation of the mechanical properties is substantial and little studied. The aim of this work is to study the mechanical properties of KNL-NTS lead free ceramics doped with Zr evaluating the effects that can give rise to improved mechanical properties. Our results show that the crystalline phase, size and shape of grains in the ceramics are affected by the doping amount. We found that the microstructure does have a close relationship to the mechanical response, more specifically; a uniform and fine grain microstructure is suitable to lead high mechanical strength. Based on these results, the chemical modifications with Zr+4 ions have a significantly positive influence on hardness, strength and fracture toughness values of KNL-NTS ceramics.
publishDate 2016
dc.date.none.fl_str_mv 2016-12-15
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/44315
Ramajo, Leandro Alfredo; Castro, Miriam Susana; Fernandez, José; Rubio Marcos, Fernado; Mechanical Properties Enhancement in Potassium-Sodium Niobate Lead-free Piezoceramics: The impact of chemical modifications; Springer; Journal of Materials Science: Materials in Electronics; 28; 7; 15-12-2016; 5128-5134
0957-4522
CONICET Digital
CONICET
url http://hdl.handle.net/11336/44315
identifier_str_mv Ramajo, Leandro Alfredo; Castro, Miriam Susana; Fernandez, José; Rubio Marcos, Fernado; Mechanical Properties Enhancement in Potassium-Sodium Niobate Lead-free Piezoceramics: The impact of chemical modifications; Springer; Journal of Materials Science: Materials in Electronics; 28; 7; 15-12-2016; 5128-5134
0957-4522
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1007/s10854-016-6168-8
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs10854-016-6168-8
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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