Environmentally friendly, nano lithium silicate anticorrosive coatings
- Autores
- Canosa, Guadalupe; Alfieri, Paula Vanesa; Giudice, Carlos Alberto
- Año de publicación
- 2012
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The aim of this study was to develop environmentally friendly, nano-structured inorganic coatings suitable for the protection of metal substrates. The formulation variables included (i) two binders based on lithium silicate of 7.5/1.0 silica/alkali molar ratio (one of them a commercial colloidal solution, and the other a laboratory-prepared nanosolution), (ii) eight pigment compositions based on two spherical microzinc alone (D 50/50 4 and 8 μm) and mixed with spherical nanozinc in three microzinc/nanozinc (w/w) ratios (90/10, 80/20 and 70/30) and finally (iii) six values of pigment volume concentration, PVC (from 47.5 to 70.0%). The electrode potentials were measured in sodium chloride solution at 25 °C and pH 7.0 during 70 days to establish the evolution of cathodic protection; in addition, panels were exposed in salt spray (fog) chamber to determine the degree of rusting and in 100% relative humidity to evaluate the blistering resistance. It was concluded that the variables alkaline silicate type, pigment composition and PVC values exhibited an important influence on the anticorrosive efficiency; very good performance was achieved with the nano-structured inorganic binder (7.5/1.0 SiO 2/Li 2O molar ratio) and the fine spherical microzinc (D 50/50 4 μm) modified with nanozinc (similar efficiency for 80/20 and 70/30 microzinc/nanozinc, w/w, ratios), in a wide range of PVC values (from 52.5 to 65.0% and from 47.5 to 60.0%, respectively).
Fil: Canosa, Guadalupe. Universidad Tecnologica Nacional. Facultad Regional La Plata; Argentina
Fil: Alfieri, Paula Vanesa. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
Fil: Giudice, Carlos Alberto. Universidad Tecnologica Nacional. Facultad Regional La Plata; Argentina - Materia
-
DEGREE OF BLISTERING
DEGREE OF RUSTING
ELECTRODE POTENTIAL
LITHIUM SILICATE
MICROZINC
NANOZINC - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/93914
Ver los metadatos del registro completo
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Environmentally friendly, nano lithium silicate anticorrosive coatingsCanosa, GuadalupeAlfieri, Paula VanesaGiudice, Carlos AlbertoDEGREE OF BLISTERINGDEGREE OF RUSTINGELECTRODE POTENTIALLITHIUM SILICATEMICROZINCNANOZINChttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The aim of this study was to develop environmentally friendly, nano-structured inorganic coatings suitable for the protection of metal substrates. The formulation variables included (i) two binders based on lithium silicate of 7.5/1.0 silica/alkali molar ratio (one of them a commercial colloidal solution, and the other a laboratory-prepared nanosolution), (ii) eight pigment compositions based on two spherical microzinc alone (D 50/50 4 and 8 μm) and mixed with spherical nanozinc in three microzinc/nanozinc (w/w) ratios (90/10, 80/20 and 70/30) and finally (iii) six values of pigment volume concentration, PVC (from 47.5 to 70.0%). The electrode potentials were measured in sodium chloride solution at 25 °C and pH 7.0 during 70 days to establish the evolution of cathodic protection; in addition, panels were exposed in salt spray (fog) chamber to determine the degree of rusting and in 100% relative humidity to evaluate the blistering resistance. It was concluded that the variables alkaline silicate type, pigment composition and PVC values exhibited an important influence on the anticorrosive efficiency; very good performance was achieved with the nano-structured inorganic binder (7.5/1.0 SiO 2/Li 2O molar ratio) and the fine spherical microzinc (D 50/50 4 μm) modified with nanozinc (similar efficiency for 80/20 and 70/30 microzinc/nanozinc, w/w, ratios), in a wide range of PVC values (from 52.5 to 65.0% and from 47.5 to 60.0%, respectively).Fil: Canosa, Guadalupe. Universidad Tecnologica Nacional. Facultad Regional La Plata; ArgentinaFil: Alfieri, Paula Vanesa. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: Giudice, Carlos Alberto. Universidad Tecnologica Nacional. Facultad Regional La Plata; ArgentinaElsevier Science Sa2012-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/93914Canosa, Guadalupe; Alfieri, Paula Vanesa; Giudice, Carlos Alberto; Environmentally friendly, nano lithium silicate anticorrosive coatings; Elsevier Science Sa; Progress in Organic Coatings; 73; 2-3; 2-2012; 178-1850300-9440CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0300944011003146info:eu-repo/semantics/altIdentifier/doi/10.1016/j.porgcoat.2011.10.013info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:00:45Zoai:ri.conicet.gov.ar:11336/93914instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:00:45.489CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Environmentally friendly, nano lithium silicate anticorrosive coatings |
title |
Environmentally friendly, nano lithium silicate anticorrosive coatings |
spellingShingle |
Environmentally friendly, nano lithium silicate anticorrosive coatings Canosa, Guadalupe DEGREE OF BLISTERING DEGREE OF RUSTING ELECTRODE POTENTIAL LITHIUM SILICATE MICROZINC NANOZINC |
title_short |
Environmentally friendly, nano lithium silicate anticorrosive coatings |
title_full |
Environmentally friendly, nano lithium silicate anticorrosive coatings |
title_fullStr |
Environmentally friendly, nano lithium silicate anticorrosive coatings |
title_full_unstemmed |
Environmentally friendly, nano lithium silicate anticorrosive coatings |
title_sort |
Environmentally friendly, nano lithium silicate anticorrosive coatings |
dc.creator.none.fl_str_mv |
Canosa, Guadalupe Alfieri, Paula Vanesa Giudice, Carlos Alberto |
author |
Canosa, Guadalupe |
author_facet |
Canosa, Guadalupe Alfieri, Paula Vanesa Giudice, Carlos Alberto |
author_role |
author |
author2 |
Alfieri, Paula Vanesa Giudice, Carlos Alberto |
author2_role |
author author |
dc.subject.none.fl_str_mv |
DEGREE OF BLISTERING DEGREE OF RUSTING ELECTRODE POTENTIAL LITHIUM SILICATE MICROZINC NANOZINC |
topic |
DEGREE OF BLISTERING DEGREE OF RUSTING ELECTRODE POTENTIAL LITHIUM SILICATE MICROZINC NANOZINC |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The aim of this study was to develop environmentally friendly, nano-structured inorganic coatings suitable for the protection of metal substrates. The formulation variables included (i) two binders based on lithium silicate of 7.5/1.0 silica/alkali molar ratio (one of them a commercial colloidal solution, and the other a laboratory-prepared nanosolution), (ii) eight pigment compositions based on two spherical microzinc alone (D 50/50 4 and 8 μm) and mixed with spherical nanozinc in three microzinc/nanozinc (w/w) ratios (90/10, 80/20 and 70/30) and finally (iii) six values of pigment volume concentration, PVC (from 47.5 to 70.0%). The electrode potentials were measured in sodium chloride solution at 25 °C and pH 7.0 during 70 days to establish the evolution of cathodic protection; in addition, panels were exposed in salt spray (fog) chamber to determine the degree of rusting and in 100% relative humidity to evaluate the blistering resistance. It was concluded that the variables alkaline silicate type, pigment composition and PVC values exhibited an important influence on the anticorrosive efficiency; very good performance was achieved with the nano-structured inorganic binder (7.5/1.0 SiO 2/Li 2O molar ratio) and the fine spherical microzinc (D 50/50 4 μm) modified with nanozinc (similar efficiency for 80/20 and 70/30 microzinc/nanozinc, w/w, ratios), in a wide range of PVC values (from 52.5 to 65.0% and from 47.5 to 60.0%, respectively). Fil: Canosa, Guadalupe. Universidad Tecnologica Nacional. Facultad Regional La Plata; Argentina Fil: Alfieri, Paula Vanesa. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina Fil: Giudice, Carlos Alberto. Universidad Tecnologica Nacional. Facultad Regional La Plata; Argentina |
description |
The aim of this study was to develop environmentally friendly, nano-structured inorganic coatings suitable for the protection of metal substrates. The formulation variables included (i) two binders based on lithium silicate of 7.5/1.0 silica/alkali molar ratio (one of them a commercial colloidal solution, and the other a laboratory-prepared nanosolution), (ii) eight pigment compositions based on two spherical microzinc alone (D 50/50 4 and 8 μm) and mixed with spherical nanozinc in three microzinc/nanozinc (w/w) ratios (90/10, 80/20 and 70/30) and finally (iii) six values of pigment volume concentration, PVC (from 47.5 to 70.0%). The electrode potentials were measured in sodium chloride solution at 25 °C and pH 7.0 during 70 days to establish the evolution of cathodic protection; in addition, panels were exposed in salt spray (fog) chamber to determine the degree of rusting and in 100% relative humidity to evaluate the blistering resistance. It was concluded that the variables alkaline silicate type, pigment composition and PVC values exhibited an important influence on the anticorrosive efficiency; very good performance was achieved with the nano-structured inorganic binder (7.5/1.0 SiO 2/Li 2O molar ratio) and the fine spherical microzinc (D 50/50 4 μm) modified with nanozinc (similar efficiency for 80/20 and 70/30 microzinc/nanozinc, w/w, ratios), in a wide range of PVC values (from 52.5 to 65.0% and from 47.5 to 60.0%, respectively). |
publishDate |
2012 |
dc.date.none.fl_str_mv |
2012-02 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/93914 Canosa, Guadalupe; Alfieri, Paula Vanesa; Giudice, Carlos Alberto; Environmentally friendly, nano lithium silicate anticorrosive coatings; Elsevier Science Sa; Progress in Organic Coatings; 73; 2-3; 2-2012; 178-185 0300-9440 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/93914 |
identifier_str_mv |
Canosa, Guadalupe; Alfieri, Paula Vanesa; Giudice, Carlos Alberto; Environmentally friendly, nano lithium silicate anticorrosive coatings; Elsevier Science Sa; Progress in Organic Coatings; 73; 2-3; 2-2012; 178-185 0300-9440 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0300944011003146 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.porgcoat.2011.10.013 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science Sa |
publisher.none.fl_str_mv |
Elsevier Science Sa |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613792787333120 |
score |
13.070432 |