Effect of Temperature and Potassium Chloride Impurity on the Relative ⟨101̅0⟩ Tilt Grain Boundary and Surface Free Energies in Ice

Autores
Di Prinzio, Carlos Leonardo; Druetta, Esteban; Nasello, Olga Beatriz
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The ratio of the grain boundary free energies relative to the surface free energies γgb/γs can be determined by measuring the root angles of the grooves formed at the intersection of the grain boundary with the free surface. The grooves were copied by plastic replicas, and the topographic details were revealed with a laser confocal 3D microscope. Values of γgb/γs were determined for high purity and potassium chloride doped ice bicrystals annealed at −5 and −18 °C. The studied samples were ⟨101̅0⟩/ψ tilt grain boundaries with ψ between 10 and 180°. The used KCl concentrations were 1 and 10 μmol/l, and the conductivity of the pure ice was 0.3 μS. ⟨101̅0⟩/60° grain boundary relative energies were also determined for different grain boundary inclinations. All the γgb/γs obtained values were analyzed and compared using the CSL (coincidence site lattice) theory. For pure samples annealed at −18 °C, an important variation of γgb/γs with the grain boundary inclination was found. In general, a remarkable correspondence between CSL planar density Γ and γgb/γs was observed. Results also showed that the increase of temperature and the impurity changes significantly γgb/γs.
Fil: Di Prinzio, Carlos Leonardo. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Druetta, Esteban. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Fil: Nasello, Olga Beatriz. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Materia
Grain Boundary
Ice
Confocal Microscope
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31679
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/31679
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Effect of Temperature and Potassium Chloride Impurity on the Relative ⟨101̅0⟩ Tilt Grain Boundary and Surface Free Energies in IceDi Prinzio, Carlos LeonardoDruetta, EstebanNasello, Olga BeatrizGrain BoundaryIceConfocal Microscopehttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The ratio of the grain boundary free energies relative to the surface free energies γgb/γs can be determined by measuring the root angles of the grooves formed at the intersection of the grain boundary with the free surface. The grooves were copied by plastic replicas, and the topographic details were revealed with a laser confocal 3D microscope. Values of γgb/γs were determined for high purity and potassium chloride doped ice bicrystals annealed at −5 and −18 °C. The studied samples were ⟨101̅0⟩/ψ tilt grain boundaries with ψ between 10 and 180°. The used KCl concentrations were 1 and 10 μmol/l, and the conductivity of the pure ice was 0.3 μS. ⟨101̅0⟩/60° grain boundary relative energies were also determined for different grain boundary inclinations. All the γgb/γs obtained values were analyzed and compared using the CSL (coincidence site lattice) theory. For pure samples annealed at −18 °C, an important variation of γgb/γs with the grain boundary inclination was found. In general, a remarkable correspondence between CSL planar density Γ and γgb/γs was observed. Results also showed that the increase of temperature and the impurity changes significantly γgb/γs.Fil: Di Prinzio, Carlos Leonardo. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaFil: Druetta, Esteban. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; ArgentinaFil: Nasello, Olga Beatriz. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaAmerican Chemical Society2014-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/vnd.openxmlformats-officedocument.wordprocessingml.documentapplication/pdfhttp://hdl.handle.net/11336/31679Di Prinzio, Carlos Leonardo; Druetta, Esteban; Nasello, Olga Beatriz; Effect of Temperature and Potassium Chloride Impurity on the Relative ⟨101̅0⟩ Tilt Grain Boundary and Surface Free Energies in Ice; American Chemical Society; Journal of Physical Chemistry B; 118; 47; 9-2014; 13365-133701520-6106CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/doi/10.1021/jp504134vinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:01:05Zoai:ri.conicet.gov.ar:11336/31679instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:01:06.212CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effect of Temperature and Potassium Chloride Impurity on the Relative ⟨101̅0⟩ Tilt Grain Boundary and Surface Free Energies in Ice
title Effect of Temperature and Potassium Chloride Impurity on the Relative ⟨101̅0⟩ Tilt Grain Boundary and Surface Free Energies in Ice
spellingShingle Effect of Temperature and Potassium Chloride Impurity on the Relative ⟨101̅0⟩ Tilt Grain Boundary and Surface Free Energies in Ice
Di Prinzio, Carlos Leonardo
Grain Boundary
Ice
Confocal Microscope
title_short Effect of Temperature and Potassium Chloride Impurity on the Relative ⟨101̅0⟩ Tilt Grain Boundary and Surface Free Energies in Ice
title_full Effect of Temperature and Potassium Chloride Impurity on the Relative ⟨101̅0⟩ Tilt Grain Boundary and Surface Free Energies in Ice
title_fullStr Effect of Temperature and Potassium Chloride Impurity on the Relative ⟨101̅0⟩ Tilt Grain Boundary and Surface Free Energies in Ice
title_full_unstemmed Effect of Temperature and Potassium Chloride Impurity on the Relative ⟨101̅0⟩ Tilt Grain Boundary and Surface Free Energies in Ice
title_sort Effect of Temperature and Potassium Chloride Impurity on the Relative ⟨101̅0⟩ Tilt Grain Boundary and Surface Free Energies in Ice
dc.creator.none.fl_str_mv Di Prinzio, Carlos Leonardo
Druetta, Esteban
Nasello, Olga Beatriz
author Di Prinzio, Carlos Leonardo
author_facet Di Prinzio, Carlos Leonardo
Druetta, Esteban
Nasello, Olga Beatriz
author_role author
author2 Druetta, Esteban
Nasello, Olga Beatriz
author2_role author
author
dc.subject.none.fl_str_mv Grain Boundary
Ice
Confocal Microscope
topic Grain Boundary
Ice
Confocal Microscope
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The ratio of the grain boundary free energies relative to the surface free energies γgb/γs can be determined by measuring the root angles of the grooves formed at the intersection of the grain boundary with the free surface. The grooves were copied by plastic replicas, and the topographic details were revealed with a laser confocal 3D microscope. Values of γgb/γs were determined for high purity and potassium chloride doped ice bicrystals annealed at −5 and −18 °C. The studied samples were ⟨101̅0⟩/ψ tilt grain boundaries with ψ between 10 and 180°. The used KCl concentrations were 1 and 10 μmol/l, and the conductivity of the pure ice was 0.3 μS. ⟨101̅0⟩/60° grain boundary relative energies were also determined for different grain boundary inclinations. All the γgb/γs obtained values were analyzed and compared using the CSL (coincidence site lattice) theory. For pure samples annealed at −18 °C, an important variation of γgb/γs with the grain boundary inclination was found. In general, a remarkable correspondence between CSL planar density Γ and γgb/γs was observed. Results also showed that the increase of temperature and the impurity changes significantly γgb/γs.
Fil: Di Prinzio, Carlos Leonardo. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Druetta, Esteban. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Fil: Nasello, Olga Beatriz. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
description The ratio of the grain boundary free energies relative to the surface free energies γgb/γs can be determined by measuring the root angles of the grooves formed at the intersection of the grain boundary with the free surface. The grooves were copied by plastic replicas, and the topographic details were revealed with a laser confocal 3D microscope. Values of γgb/γs were determined for high purity and potassium chloride doped ice bicrystals annealed at −5 and −18 °C. The studied samples were ⟨101̅0⟩/ψ tilt grain boundaries with ψ between 10 and 180°. The used KCl concentrations were 1 and 10 μmol/l, and the conductivity of the pure ice was 0.3 μS. ⟨101̅0⟩/60° grain boundary relative energies were also determined for different grain boundary inclinations. All the γgb/γs obtained values were analyzed and compared using the CSL (coincidence site lattice) theory. For pure samples annealed at −18 °C, an important variation of γgb/γs with the grain boundary inclination was found. In general, a remarkable correspondence between CSL planar density Γ and γgb/γs was observed. Results also showed that the increase of temperature and the impurity changes significantly γgb/γs.
publishDate 2014
dc.date.none.fl_str_mv 2014-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31679
Di Prinzio, Carlos Leonardo; Druetta, Esteban; Nasello, Olga Beatriz; Effect of Temperature and Potassium Chloride Impurity on the Relative ⟨101̅0⟩ Tilt Grain Boundary and Surface Free Energies in Ice; American Chemical Society; Journal of Physical Chemistry B; 118; 47; 9-2014; 13365-13370
1520-6106
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31679
identifier_str_mv Di Prinzio, Carlos Leonardo; Druetta, Esteban; Nasello, Olga Beatriz; Effect of Temperature and Potassium Chloride Impurity on the Relative ⟨101̅0⟩ Tilt Grain Boundary and Surface Free Energies in Ice; American Chemical Society; Journal of Physical Chemistry B; 118; 47; 9-2014; 13365-13370
1520-6106
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/
info:eu-repo/semantics/altIdentifier/doi/10.1021/jp504134v
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/vnd.openxmlformats-officedocument.wordprocessingml.document
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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