Valeric Biofuels from Biomass‐Derived γ‐Valerolactone: A Critical Overview of Production Processes

Autores
Martínez Figueredo, Karla Geraldine; Martínez, Francisco Agustín; Segobia, Dario Jobino; Bertero, Nicolas Maximiliano
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This review analyzes critically the production of valeric biofuels from γ-valerolactone, a relevant biomass-derived platform molecule. Initially, the main properties of valeric esters as fuels for spark- and compression-ignition engines are summarized. Then, catalytic routes to valeric esters from γ-valerolactone are meticulously analyzed, describing the acid- and metal-catalyzed reactions taking part in the tandem catalysis. Only works focused on the production of the valeric biofuels were considered, excluding the cases where these esters were observed in minor amounts or as byproducts. The role of the appropriate selection of the support, catalytic species, catalyst preparation and experimental conditions on the valeric ester productivity are thoroughly commented. Finally, some concluding remarks and perspectives are given, mentioning the areas where additional efforts must be done in order to turn the dream of a massive and renewable valeric biofuel production into a reality.
Fil: Martínez Figueredo, Karla Geraldine. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Martínez, Francisco Agustín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Segobia, Dario Jobino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Bertero, Nicolas Maximiliano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
BIOMASS
HETEROGENEOUS CATALYSIS
SUSTAINABLE CHEMISTRY
TANDEM CATALYSIS
VALERIC BIOFUELS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/225634
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/225634
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Valeric Biofuels from Biomass‐Derived γ‐Valerolactone: A Critical Overview of Production ProcessesMartínez Figueredo, Karla GeraldineMartínez, Francisco AgustínSegobia, Dario JobinoBertero, Nicolas MaximilianoBIOMASSHETEROGENEOUS CATALYSISSUSTAINABLE CHEMISTRYTANDEM CATALYSISVALERIC BIOFUELShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2This review analyzes critically the production of valeric biofuels from γ-valerolactone, a relevant biomass-derived platform molecule. Initially, the main properties of valeric esters as fuels for spark- and compression-ignition engines are summarized. Then, catalytic routes to valeric esters from γ-valerolactone are meticulously analyzed, describing the acid- and metal-catalyzed reactions taking part in the tandem catalysis. Only works focused on the production of the valeric biofuels were considered, excluding the cases where these esters were observed in minor amounts or as byproducts. The role of the appropriate selection of the support, catalytic species, catalyst preparation and experimental conditions on the valeric ester productivity are thoroughly commented. Finally, some concluding remarks and perspectives are given, mentioning the areas where additional efforts must be done in order to turn the dream of a massive and renewable valeric biofuel production into a reality.Fil: Martínez Figueredo, Karla Geraldine. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Martínez, Francisco Agustín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Segobia, Dario Jobino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Bertero, Nicolas Maximiliano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaWiley-VCH2023-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/225634Martínez Figueredo, Karla Geraldine; Martínez, Francisco Agustín; Segobia, Dario Jobino; Bertero, Nicolas Maximiliano; Valeric Biofuels from Biomass‐Derived γ‐Valerolactone: A Critical Overview of Production Processes; Wiley-VCH; ChemPlusChem; 88; 11; 9-2023; 1-222192-6506CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cplu.202300381info:eu-repo/semantics/altIdentifier/doi/10.1002/cplu.202300381info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:46:55Zoai:ri.conicet.gov.ar:11336/225634instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:46:55.654CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Valeric Biofuels from Biomass‐Derived γ‐Valerolactone: A Critical Overview of Production Processes
title Valeric Biofuels from Biomass‐Derived γ‐Valerolactone: A Critical Overview of Production Processes
spellingShingle Valeric Biofuels from Biomass‐Derived γ‐Valerolactone: A Critical Overview of Production Processes
Martínez Figueredo, Karla Geraldine
BIOMASS
HETEROGENEOUS CATALYSIS
SUSTAINABLE CHEMISTRY
TANDEM CATALYSIS
VALERIC BIOFUELS
title_short Valeric Biofuels from Biomass‐Derived γ‐Valerolactone: A Critical Overview of Production Processes
title_full Valeric Biofuels from Biomass‐Derived γ‐Valerolactone: A Critical Overview of Production Processes
title_fullStr Valeric Biofuels from Biomass‐Derived γ‐Valerolactone: A Critical Overview of Production Processes
title_full_unstemmed Valeric Biofuels from Biomass‐Derived γ‐Valerolactone: A Critical Overview of Production Processes
title_sort Valeric Biofuels from Biomass‐Derived γ‐Valerolactone: A Critical Overview of Production Processes
dc.creator.none.fl_str_mv Martínez Figueredo, Karla Geraldine
Martínez, Francisco Agustín
Segobia, Dario Jobino
Bertero, Nicolas Maximiliano
author Martínez Figueredo, Karla Geraldine
author_facet Martínez Figueredo, Karla Geraldine
Martínez, Francisco Agustín
Segobia, Dario Jobino
Bertero, Nicolas Maximiliano
author_role author
author2 Martínez, Francisco Agustín
Segobia, Dario Jobino
Bertero, Nicolas Maximiliano
author2_role author
author
author
dc.subject.none.fl_str_mv BIOMASS
HETEROGENEOUS CATALYSIS
SUSTAINABLE CHEMISTRY
TANDEM CATALYSIS
VALERIC BIOFUELS
topic BIOMASS
HETEROGENEOUS CATALYSIS
SUSTAINABLE CHEMISTRY
TANDEM CATALYSIS
VALERIC BIOFUELS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv This review analyzes critically the production of valeric biofuels from γ-valerolactone, a relevant biomass-derived platform molecule. Initially, the main properties of valeric esters as fuels for spark- and compression-ignition engines are summarized. Then, catalytic routes to valeric esters from γ-valerolactone are meticulously analyzed, describing the acid- and metal-catalyzed reactions taking part in the tandem catalysis. Only works focused on the production of the valeric biofuels were considered, excluding the cases where these esters were observed in minor amounts or as byproducts. The role of the appropriate selection of the support, catalytic species, catalyst preparation and experimental conditions on the valeric ester productivity are thoroughly commented. Finally, some concluding remarks and perspectives are given, mentioning the areas where additional efforts must be done in order to turn the dream of a massive and renewable valeric biofuel production into a reality.
Fil: Martínez Figueredo, Karla Geraldine. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Martínez, Francisco Agustín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Segobia, Dario Jobino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Bertero, Nicolas Maximiliano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description This review analyzes critically the production of valeric biofuels from γ-valerolactone, a relevant biomass-derived platform molecule. Initially, the main properties of valeric esters as fuels for spark- and compression-ignition engines are summarized. Then, catalytic routes to valeric esters from γ-valerolactone are meticulously analyzed, describing the acid- and metal-catalyzed reactions taking part in the tandem catalysis. Only works focused on the production of the valeric biofuels were considered, excluding the cases where these esters were observed in minor amounts or as byproducts. The role of the appropriate selection of the support, catalytic species, catalyst preparation and experimental conditions on the valeric ester productivity are thoroughly commented. Finally, some concluding remarks and perspectives are given, mentioning the areas where additional efforts must be done in order to turn the dream of a massive and renewable valeric biofuel production into a reality.
publishDate 2023
dc.date.none.fl_str_mv 2023-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/225634
Martínez Figueredo, Karla Geraldine; Martínez, Francisco Agustín; Segobia, Dario Jobino; Bertero, Nicolas Maximiliano; Valeric Biofuels from Biomass‐Derived γ‐Valerolactone: A Critical Overview of Production Processes; Wiley-VCH; ChemPlusChem; 88; 11; 9-2023; 1-22
2192-6506
CONICET Digital
CONICET
url http://hdl.handle.net/11336/225634
identifier_str_mv Martínez Figueredo, Karla Geraldine; Martínez, Francisco Agustín; Segobia, Dario Jobino; Bertero, Nicolas Maximiliano; Valeric Biofuels from Biomass‐Derived γ‐Valerolactone: A Critical Overview of Production Processes; Wiley-VCH; ChemPlusChem; 88; 11; 9-2023; 1-22
2192-6506
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cplu.202300381
info:eu-repo/semantics/altIdentifier/doi/10.1002/cplu.202300381
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley-VCH
publisher.none.fl_str_mv Wiley-VCH
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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