Efficient production of biodiesel from low-cost feedstock using zinc oleate as catalyst

Autores
Reinoso, Deborath Mariana; Damiani, Daniel Eduardo; Tonetto, Gabriela Marta
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this study, the synthesis of fatty acid methyl esters (FAME) by the transesterification of low-cost feedstock containing 10 and 22 wt.% free fatty acid (FFA), using zinc oleate (ZnOl) as catalyst, was investigated. The performance of the ZnOl salt in the reaction medium was evaluated in terms of activity and stability in the presence of free fatty acids. At 140 °C and 2 h of reaction time, triglyceride conversion was 100%, FAME yield was close to 95%, and fatty acid conversion was 75.9% and 82.6% for feedstock with 10 and 22 wt.% FFA, respectively. The zinc carboxylic salt was able to catalyze simultaneously the triglyceride transesterification and the fatty acid esterification reactions with high activity and selectivity under moderate operating conditions and slight FAME and triglycerides hydrolysis
Fil: Reinoso, Deborath Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
Fatty Acid Methyl Esters
Zinc Oleate
Low Cost Feedstock
Transesterifcation
Esterification
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/17790
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/17790
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Efficient production of biodiesel from low-cost feedstock using zinc oleate as catalystReinoso, Deborath MarianaDamiani, Daniel EduardoTonetto, Gabriela MartaFatty Acid Methyl EstersZinc OleateLow Cost FeedstockTransesterifcationEsterificationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2In this study, the synthesis of fatty acid methyl esters (FAME) by the transesterification of low-cost feedstock containing 10 and 22 wt.% free fatty acid (FFA), using zinc oleate (ZnOl) as catalyst, was investigated. The performance of the ZnOl salt in the reaction medium was evaluated in terms of activity and stability in the presence of free fatty acids. At 140 °C and 2 h of reaction time, triglyceride conversion was 100%, FAME yield was close to 95%, and fatty acid conversion was 75.9% and 82.6% for feedstock with 10 and 22 wt.% FFA, respectively. The zinc carboxylic salt was able to catalyze simultaneously the triglyceride transesterification and the fatty acid esterification reactions with high activity and selectivity under moderate operating conditions and slight FAME and triglycerides hydrolysisFil: Reinoso, Deborath Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaElsevier Science2015-03-21info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/17790Reinoso, Deborath Mariana; Damiani, Daniel Eduardo; Tonetto, Gabriela Marta; Efficient production of biodiesel from low-cost feedstock using zinc oleate as catalyst; Elsevier Science; Fuel Processing Technology; 134; 21-3-2015; 26-310378-3820enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.fuproc.2015.03.003info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0378382015001137info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:38:57Zoai:ri.conicet.gov.ar:11336/17790instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:38:57.32CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Efficient production of biodiesel from low-cost feedstock using zinc oleate as catalyst
title Efficient production of biodiesel from low-cost feedstock using zinc oleate as catalyst
spellingShingle Efficient production of biodiesel from low-cost feedstock using zinc oleate as catalyst
Reinoso, Deborath Mariana
Fatty Acid Methyl Esters
Zinc Oleate
Low Cost Feedstock
Transesterifcation
Esterification
title_short Efficient production of biodiesel from low-cost feedstock using zinc oleate as catalyst
title_full Efficient production of biodiesel from low-cost feedstock using zinc oleate as catalyst
title_fullStr Efficient production of biodiesel from low-cost feedstock using zinc oleate as catalyst
title_full_unstemmed Efficient production of biodiesel from low-cost feedstock using zinc oleate as catalyst
title_sort Efficient production of biodiesel from low-cost feedstock using zinc oleate as catalyst
dc.creator.none.fl_str_mv Reinoso, Deborath Mariana
Damiani, Daniel Eduardo
Tonetto, Gabriela Marta
author Reinoso, Deborath Mariana
author_facet Reinoso, Deborath Mariana
Damiani, Daniel Eduardo
Tonetto, Gabriela Marta
author_role author
author2 Damiani, Daniel Eduardo
Tonetto, Gabriela Marta
author2_role author
author
dc.subject.none.fl_str_mv Fatty Acid Methyl Esters
Zinc Oleate
Low Cost Feedstock
Transesterifcation
Esterification
topic Fatty Acid Methyl Esters
Zinc Oleate
Low Cost Feedstock
Transesterifcation
Esterification
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In this study, the synthesis of fatty acid methyl esters (FAME) by the transesterification of low-cost feedstock containing 10 and 22 wt.% free fatty acid (FFA), using zinc oleate (ZnOl) as catalyst, was investigated. The performance of the ZnOl salt in the reaction medium was evaluated in terms of activity and stability in the presence of free fatty acids. At 140 °C and 2 h of reaction time, triglyceride conversion was 100%, FAME yield was close to 95%, and fatty acid conversion was 75.9% and 82.6% for feedstock with 10 and 22 wt.% FFA, respectively. The zinc carboxylic salt was able to catalyze simultaneously the triglyceride transesterification and the fatty acid esterification reactions with high activity and selectivity under moderate operating conditions and slight FAME and triglycerides hydrolysis
Fil: Reinoso, Deborath Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description In this study, the synthesis of fatty acid methyl esters (FAME) by the transesterification of low-cost feedstock containing 10 and 22 wt.% free fatty acid (FFA), using zinc oleate (ZnOl) as catalyst, was investigated. The performance of the ZnOl salt in the reaction medium was evaluated in terms of activity and stability in the presence of free fatty acids. At 140 °C and 2 h of reaction time, triglyceride conversion was 100%, FAME yield was close to 95%, and fatty acid conversion was 75.9% and 82.6% for feedstock with 10 and 22 wt.% FFA, respectively. The zinc carboxylic salt was able to catalyze simultaneously the triglyceride transesterification and the fatty acid esterification reactions with high activity and selectivity under moderate operating conditions and slight FAME and triglycerides hydrolysis
publishDate 2015
dc.date.none.fl_str_mv 2015-03-21
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/17790
Reinoso, Deborath Mariana; Damiani, Daniel Eduardo; Tonetto, Gabriela Marta; Efficient production of biodiesel from low-cost feedstock using zinc oleate as catalyst; Elsevier Science; Fuel Processing Technology; 134; 21-3-2015; 26-31
0378-3820
url http://hdl.handle.net/11336/17790
identifier_str_mv Reinoso, Deborath Mariana; Damiani, Daniel Eduardo; Tonetto, Gabriela Marta; Efficient production of biodiesel from low-cost feedstock using zinc oleate as catalyst; Elsevier Science; Fuel Processing Technology; 134; 21-3-2015; 26-31
0378-3820
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.fuproc.2015.03.003
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0378382015001137
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614413358727168
score 13.070432

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