Electrochemical performance evaluation of a Ni/Fe mixed oxide natural clay composite as anode material for Li-ion batteries

Autores
Rodríguez Carrillo, Augusto Manuel; Ortiz, Mariela Gisela; Thomas, Jorge Enrique; Visintin, Arnaldo
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A Ni/Fe mixed oxide natural clay composite was obtained by simple addition of bentonite natural clay sample after coprecipitation of layered double hydroxide (Ni0.75Fe0.25(OH)2(CO3)0.125) precursor; later this composite was sintered at 400 °C. The natural clay was collected from La Plata city (Argentina), and this has been used without further purification treatment. The electrochemical characterization allowed to identify stability improvement of the charge-discharge capacity values for the materials with calcination (35 % capacity retention after 60 cycles) against an anode prepared without clay (only 8 % retention). However, the anodic material without clay delivered a higher discharge capacity than the anode material with clay, as expected, due to the lacking the non-electroactive clay quantity. Physical characterization of the materials, such as nitrogen physisorption, showed a smaller particle diameter (37 nm against 54 nm) for the mixed oxides with and without natural clay, respectively. Despite this, by scanning electron microscopy a greater size difference was observed in the morphology for the oxide- natural clay composites. This could be because the smaller particle size along the interstitial space of the consecutive clay flakes and the pore volume of the material could be produced a synergistic effect between them; and thus promote a buffered volumetric expansion. This is generally reported to be responsible for the low charge- discharge cyclic performance observed in the conversion anodes. Also, the process of re-dissolution of the hydroxide precursor in the basic media, followed by the double hydroxide re-precipitation from Ni+2 and Fe+3 which are adsorbed in negative sites of the clay could be responsible for the achievement of the smaller size particles.
Fil: Rodríguez Carrillo, Augusto Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Ortiz, Mariela Gisela. Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Thomas, Jorge Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. YPF - Tecnología; Argentina
Fil: Visintin, Arnaldo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Materia
ANODE
LAYERED DOUBLE HYDROXIDE
LITHIUM-ION BATTERY
NATURAL CLAY MINERAL
NI/FE OXIDE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/241573
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/241573
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Electrochemical performance evaluation of a Ni/Fe mixed oxide natural clay composite as anode material for Li-ion batteriesRodríguez Carrillo, Augusto ManuelOrtiz, Mariela GiselaThomas, Jorge EnriqueVisintin, ArnaldoANODELAYERED DOUBLE HYDROXIDELITHIUM-ION BATTERYNATURAL CLAY MINERALNI/FE OXIDEhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2A Ni/Fe mixed oxide natural clay composite was obtained by simple addition of bentonite natural clay sample after coprecipitation of layered double hydroxide (Ni0.75Fe0.25(OH)2(CO3)0.125) precursor; later this composite was sintered at 400 °C. The natural clay was collected from La Plata city (Argentina), and this has been used without further purification treatment. The electrochemical characterization allowed to identify stability improvement of the charge-discharge capacity values for the materials with calcination (35 % capacity retention after 60 cycles) against an anode prepared without clay (only 8 % retention). However, the anodic material without clay delivered a higher discharge capacity than the anode material with clay, as expected, due to the lacking the non-electroactive clay quantity. Physical characterization of the materials, such as nitrogen physisorption, showed a smaller particle diameter (37 nm against 54 nm) for the mixed oxides with and without natural clay, respectively. Despite this, by scanning electron microscopy a greater size difference was observed in the morphology for the oxide- natural clay composites. This could be because the smaller particle size along the interstitial space of the consecutive clay flakes and the pore volume of the material could be produced a synergistic effect between them; and thus promote a buffered volumetric expansion. This is generally reported to be responsible for the low charge- discharge cyclic performance observed in the conversion anodes. Also, the process of re-dissolution of the hydroxide precursor in the basic media, followed by the double hydroxide re-precipitation from Ni+2 and Fe+3 which are adsorbed in negative sites of the clay could be responsible for the achievement of the smaller size particles.Fil: Rodríguez Carrillo, Augusto Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Ortiz, Mariela Gisela. Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Thomas, Jorge Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. YPF - Tecnología; ArgentinaFil: Visintin, Arnaldo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaPergamon-Elsevier Science Ltd2024-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/241573Rodríguez Carrillo, Augusto Manuel; Ortiz, Mariela Gisela; Thomas, Jorge Enrique; Visintin, Arnaldo; Electrochemical performance evaluation of a Ni/Fe mixed oxide natural clay composite as anode material for Li-ion batteries; Pergamon-Elsevier Science Ltd; Electrochimica Acta; 479; 143869; 3-2024; 1-400013-4686CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0013468624001130info:eu-repo/semantics/altIdentifier/doi/10.1016/j.electacta.2024.143869info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:05:56Zoai:ri.conicet.gov.ar:11336/241573instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:05:56.826CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Electrochemical performance evaluation of a Ni/Fe mixed oxide natural clay composite as anode material for Li-ion batteries
title Electrochemical performance evaluation of a Ni/Fe mixed oxide natural clay composite as anode material for Li-ion batteries
spellingShingle Electrochemical performance evaluation of a Ni/Fe mixed oxide natural clay composite as anode material for Li-ion batteries
Rodríguez Carrillo, Augusto Manuel
ANODE
LAYERED DOUBLE HYDROXIDE
LITHIUM-ION BATTERY
NATURAL CLAY MINERAL
NI/FE OXIDE
title_short Electrochemical performance evaluation of a Ni/Fe mixed oxide natural clay composite as anode material for Li-ion batteries
title_full Electrochemical performance evaluation of a Ni/Fe mixed oxide natural clay composite as anode material for Li-ion batteries
title_fullStr Electrochemical performance evaluation of a Ni/Fe mixed oxide natural clay composite as anode material for Li-ion batteries
title_full_unstemmed Electrochemical performance evaluation of a Ni/Fe mixed oxide natural clay composite as anode material for Li-ion batteries
title_sort Electrochemical performance evaluation of a Ni/Fe mixed oxide natural clay composite as anode material for Li-ion batteries
dc.creator.none.fl_str_mv Rodríguez Carrillo, Augusto Manuel
Ortiz, Mariela Gisela
Thomas, Jorge Enrique
Visintin, Arnaldo
author Rodríguez Carrillo, Augusto Manuel
author_facet Rodríguez Carrillo, Augusto Manuel
Ortiz, Mariela Gisela
Thomas, Jorge Enrique
Visintin, Arnaldo
author_role author
author2 Ortiz, Mariela Gisela
Thomas, Jorge Enrique
Visintin, Arnaldo
author2_role author
author
author
dc.subject.none.fl_str_mv ANODE
LAYERED DOUBLE HYDROXIDE
LITHIUM-ION BATTERY
NATURAL CLAY MINERAL
NI/FE OXIDE
topic ANODE
LAYERED DOUBLE HYDROXIDE
LITHIUM-ION BATTERY
NATURAL CLAY MINERAL
NI/FE OXIDE
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A Ni/Fe mixed oxide natural clay composite was obtained by simple addition of bentonite natural clay sample after coprecipitation of layered double hydroxide (Ni0.75Fe0.25(OH)2(CO3)0.125) precursor; later this composite was sintered at 400 °C. The natural clay was collected from La Plata city (Argentina), and this has been used without further purification treatment. The electrochemical characterization allowed to identify stability improvement of the charge-discharge capacity values for the materials with calcination (35 % capacity retention after 60 cycles) against an anode prepared without clay (only 8 % retention). However, the anodic material without clay delivered a higher discharge capacity than the anode material with clay, as expected, due to the lacking the non-electroactive clay quantity. Physical characterization of the materials, such as nitrogen physisorption, showed a smaller particle diameter (37 nm against 54 nm) for the mixed oxides with and without natural clay, respectively. Despite this, by scanning electron microscopy a greater size difference was observed in the morphology for the oxide- natural clay composites. This could be because the smaller particle size along the interstitial space of the consecutive clay flakes and the pore volume of the material could be produced a synergistic effect between them; and thus promote a buffered volumetric expansion. This is generally reported to be responsible for the low charge- discharge cyclic performance observed in the conversion anodes. Also, the process of re-dissolution of the hydroxide precursor in the basic media, followed by the double hydroxide re-precipitation from Ni+2 and Fe+3 which are adsorbed in negative sites of the clay could be responsible for the achievement of the smaller size particles.
Fil: Rodríguez Carrillo, Augusto Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Ortiz, Mariela Gisela. Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Thomas, Jorge Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. YPF - Tecnología; Argentina
Fil: Visintin, Arnaldo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
description A Ni/Fe mixed oxide natural clay composite was obtained by simple addition of bentonite natural clay sample after coprecipitation of layered double hydroxide (Ni0.75Fe0.25(OH)2(CO3)0.125) precursor; later this composite was sintered at 400 °C. The natural clay was collected from La Plata city (Argentina), and this has been used without further purification treatment. The electrochemical characterization allowed to identify stability improvement of the charge-discharge capacity values for the materials with calcination (35 % capacity retention after 60 cycles) against an anode prepared without clay (only 8 % retention). However, the anodic material without clay delivered a higher discharge capacity than the anode material with clay, as expected, due to the lacking the non-electroactive clay quantity. Physical characterization of the materials, such as nitrogen physisorption, showed a smaller particle diameter (37 nm against 54 nm) for the mixed oxides with and without natural clay, respectively. Despite this, by scanning electron microscopy a greater size difference was observed in the morphology for the oxide- natural clay composites. This could be because the smaller particle size along the interstitial space of the consecutive clay flakes and the pore volume of the material could be produced a synergistic effect between them; and thus promote a buffered volumetric expansion. This is generally reported to be responsible for the low charge- discharge cyclic performance observed in the conversion anodes. Also, the process of re-dissolution of the hydroxide precursor in the basic media, followed by the double hydroxide re-precipitation from Ni+2 and Fe+3 which are adsorbed in negative sites of the clay could be responsible for the achievement of the smaller size particles.
publishDate 2024
dc.date.none.fl_str_mv 2024-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/241573
Rodríguez Carrillo, Augusto Manuel; Ortiz, Mariela Gisela; Thomas, Jorge Enrique; Visintin, Arnaldo; Electrochemical performance evaluation of a Ni/Fe mixed oxide natural clay composite as anode material for Li-ion batteries; Pergamon-Elsevier Science Ltd; Electrochimica Acta; 479; 143869; 3-2024; 1-40
0013-4686
CONICET Digital
CONICET
url http://hdl.handle.net/11336/241573
identifier_str_mv Rodríguez Carrillo, Augusto Manuel; Ortiz, Mariela Gisela; Thomas, Jorge Enrique; Visintin, Arnaldo; Electrochemical performance evaluation of a Ni/Fe mixed oxide natural clay composite as anode material for Li-ion batteries; Pergamon-Elsevier Science Ltd; Electrochimica Acta; 479; 143869; 3-2024; 1-40
0013-4686
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0013468624001130
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.electacta.2024.143869
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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