2-Methoxynaphthalene acylation using aluminum or copper salts of tungstophosphoric and tungstosilicic acids as catalysts

Autores
Mendez, Leticia Jesica; Torviso, Maria del Rosario; Pizzio, Luis Rene; Blanco, Mirta Noemi
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Aluminum or copper salts of the tungstophosphoric (TPA) and tungstosilicic (TSA) acids were synthesized. They present interesting characteristics as catalysts because they can have Lewis and/or Brønsted acidity. The salts were characterized by Fourier transform infrared (FT-IR) spectroscopy, measurement of the specific surface area BET, X-ray diffraction, differential scanning calorimetry (DSC) and estimation of the acidity by potentiometric titration with n-butylamine. The salts keep the Keggin structure of the [PW12O40]3− and [SiW12O40]4− heteropolyanions intact during the synthesis. The salts of TPA are thermally more stable than those of TSA. All the salts showed very strong acid sites by potentiometric titration, the acid strength and the number of acid sites being higher for the Al3+ salts. The salts also showed an excellent catalytic behavior in the reaction of 2-methoxynaphthalene acylation with acetic anhydride. The aluminum salts led to better yields, which are correlated with their higher acidity. Also, it was observed that the solvent nature has an effect on the attained conversion.
Fil: Mendez, Leticia Jesica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Torviso, Maria del Rosario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Blanco, Mirta Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Materia
Tungstophosphates
Tungstosilicates
Aluminum
Copper
2-Methoxynaphthalene
Acylation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31535
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/31535
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling 2-Methoxynaphthalene acylation using aluminum or copper salts of tungstophosphoric and tungstosilicic acids as catalystsMendez, Leticia JesicaTorviso, Maria del RosarioPizzio, Luis ReneBlanco, Mirta NoemiTungstophosphatesTungstosilicatesAluminumCopper2-MethoxynaphthaleneAcylationhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Aluminum or copper salts of the tungstophosphoric (TPA) and tungstosilicic (TSA) acids were synthesized. They present interesting characteristics as catalysts because they can have Lewis and/or Brønsted acidity. The salts were characterized by Fourier transform infrared (FT-IR) spectroscopy, measurement of the specific surface area BET, X-ray diffraction, differential scanning calorimetry (DSC) and estimation of the acidity by potentiometric titration with n-butylamine. The salts keep the Keggin structure of the [PW12O40]3− and [SiW12O40]4− heteropolyanions intact during the synthesis. The salts of TPA are thermally more stable than those of TSA. All the salts showed very strong acid sites by potentiometric titration, the acid strength and the number of acid sites being higher for the Al3+ salts. The salts also showed an excellent catalytic behavior in the reaction of 2-methoxynaphthalene acylation with acetic anhydride. The aluminum salts led to better yields, which are correlated with their higher acidity. Also, it was observed that the solvent nature has an effect on the attained conversion.Fil: Mendez, Leticia Jesica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Torviso, Maria del Rosario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Blanco, Mirta Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaElsevier Science2011-09-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31535Blanco, Mirta Noemi; Pizzio, Luis Rene; Torviso, Maria del Rosario; Mendez, Leticia Jesica; 2-Methoxynaphthalene acylation using aluminum or copper salts of tungstophosphoric and tungstosilicic acids as catalysts; Elsevier Science; Catalysis Today; 173; 1; 3-9-2011; 32-370920-5861CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2011.03.028info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0920586111002343info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:01:45Zoai:ri.conicet.gov.ar:11336/31535instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:01:45.911CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv 2-Methoxynaphthalene acylation using aluminum or copper salts of tungstophosphoric and tungstosilicic acids as catalysts
title 2-Methoxynaphthalene acylation using aluminum or copper salts of tungstophosphoric and tungstosilicic acids as catalysts
spellingShingle 2-Methoxynaphthalene acylation using aluminum or copper salts of tungstophosphoric and tungstosilicic acids as catalysts
Mendez, Leticia Jesica
Tungstophosphates
Tungstosilicates
Aluminum
Copper
2-Methoxynaphthalene
Acylation
title_short 2-Methoxynaphthalene acylation using aluminum or copper salts of tungstophosphoric and tungstosilicic acids as catalysts
title_full 2-Methoxynaphthalene acylation using aluminum or copper salts of tungstophosphoric and tungstosilicic acids as catalysts
title_fullStr 2-Methoxynaphthalene acylation using aluminum or copper salts of tungstophosphoric and tungstosilicic acids as catalysts
title_full_unstemmed 2-Methoxynaphthalene acylation using aluminum or copper salts of tungstophosphoric and tungstosilicic acids as catalysts
title_sort 2-Methoxynaphthalene acylation using aluminum or copper salts of tungstophosphoric and tungstosilicic acids as catalysts
dc.creator.none.fl_str_mv Mendez, Leticia Jesica
Torviso, Maria del Rosario
Pizzio, Luis Rene
Blanco, Mirta Noemi
author Mendez, Leticia Jesica
author_facet Mendez, Leticia Jesica
Torviso, Maria del Rosario
Pizzio, Luis Rene
Blanco, Mirta Noemi
author_role author
author2 Torviso, Maria del Rosario
Pizzio, Luis Rene
Blanco, Mirta Noemi
author2_role author
author
author
dc.subject.none.fl_str_mv Tungstophosphates
Tungstosilicates
Aluminum
Copper
2-Methoxynaphthalene
Acylation
topic Tungstophosphates
Tungstosilicates
Aluminum
Copper
2-Methoxynaphthalene
Acylation
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Aluminum or copper salts of the tungstophosphoric (TPA) and tungstosilicic (TSA) acids were synthesized. They present interesting characteristics as catalysts because they can have Lewis and/or Brønsted acidity. The salts were characterized by Fourier transform infrared (FT-IR) spectroscopy, measurement of the specific surface area BET, X-ray diffraction, differential scanning calorimetry (DSC) and estimation of the acidity by potentiometric titration with n-butylamine. The salts keep the Keggin structure of the [PW12O40]3− and [SiW12O40]4− heteropolyanions intact during the synthesis. The salts of TPA are thermally more stable than those of TSA. All the salts showed very strong acid sites by potentiometric titration, the acid strength and the number of acid sites being higher for the Al3+ salts. The salts also showed an excellent catalytic behavior in the reaction of 2-methoxynaphthalene acylation with acetic anhydride. The aluminum salts led to better yields, which are correlated with their higher acidity. Also, it was observed that the solvent nature has an effect on the attained conversion.
Fil: Mendez, Leticia Jesica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Torviso, Maria del Rosario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Blanco, Mirta Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
description Aluminum or copper salts of the tungstophosphoric (TPA) and tungstosilicic (TSA) acids were synthesized. They present interesting characteristics as catalysts because they can have Lewis and/or Brønsted acidity. The salts were characterized by Fourier transform infrared (FT-IR) spectroscopy, measurement of the specific surface area BET, X-ray diffraction, differential scanning calorimetry (DSC) and estimation of the acidity by potentiometric titration with n-butylamine. The salts keep the Keggin structure of the [PW12O40]3− and [SiW12O40]4− heteropolyanions intact during the synthesis. The salts of TPA are thermally more stable than those of TSA. All the salts showed very strong acid sites by potentiometric titration, the acid strength and the number of acid sites being higher for the Al3+ salts. The salts also showed an excellent catalytic behavior in the reaction of 2-methoxynaphthalene acylation with acetic anhydride. The aluminum salts led to better yields, which are correlated with their higher acidity. Also, it was observed that the solvent nature has an effect on the attained conversion.
publishDate 2011
dc.date.none.fl_str_mv 2011-09-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31535
Blanco, Mirta Noemi; Pizzio, Luis Rene; Torviso, Maria del Rosario; Mendez, Leticia Jesica; 2-Methoxynaphthalene acylation using aluminum or copper salts of tungstophosphoric and tungstosilicic acids as catalysts; Elsevier Science; Catalysis Today; 173; 1; 3-9-2011; 32-37
0920-5861
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31535
identifier_str_mv Blanco, Mirta Noemi; Pizzio, Luis Rene; Torviso, Maria del Rosario; Mendez, Leticia Jesica; 2-Methoxynaphthalene acylation using aluminum or copper salts of tungstophosphoric and tungstosilicic acids as catalysts; Elsevier Science; Catalysis Today; 173; 1; 3-9-2011; 32-37
0920-5861
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2011.03.028
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0920586111002343
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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