Highly selective and ultrasensitive turn-on luminescence chemosensor for mercury (II) determination based on the rhodamine 6G derivative FC1 and Au nanoparticles

Autores
Brasca, Romina; Onaindia, María Celeste; Goicoechea, Hector Casimiro; Muñoz de la Peña, Arsenio; Culzoni, Maria Julia
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A method for the detection and quantitation of Hg2+ in aqueous samples by fluorescence spectroscopy is presented. It consists of a turn-on sensor developed by coupling Gold nanoparticles (AuNPs) with the rhodamine 6G derivative FC1, in which the response is generated by a mercury-induced ring-opening reaction. The AuNPs were included in order to improve the sensitivity of the method towards the analyte, maintaining its high selectivity. The method was validated in terms of linearity, precision and accuracy, and applied to the quantitation of Hg2+ in Milli-Q and tap water with and without spiked analyte. The limit of detection and quantitation were 0.15 µg·L-1 and 0.43 µg·L-1, respectively, constituting a substantial improvement of sensitivity in comparison with the previously reported detection of Hg2+ with free FC1.
Fil: Brasca, Romina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral; Argentina
Fil: Onaindia, María Celeste. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral; Argentina
Fil: Goicoechea, Hector Casimiro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral; Argentina
Fil: Muñoz de la Peña, Arsenio. Universidad de Extremadura; España
Fil: Culzoni, Maria Julia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral; Argentina
Materia
AQUEOUS SOLUTION
AU NANOPARTICLES
FLUORIMETRIC ASSAY
HG2+ CHEMOSENSOR
RHODAMINE 6G DERIVATIVE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/71542
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/71542
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Highly selective and ultrasensitive turn-on luminescence chemosensor for mercury (II) determination based on the rhodamine 6G derivative FC1 and Au nanoparticlesBrasca, RominaOnaindia, María CelesteGoicoechea, Hector CasimiroMuñoz de la Peña, ArsenioCulzoni, Maria JuliaAQUEOUS SOLUTIONAU NANOPARTICLESFLUORIMETRIC ASSAYHG2+ CHEMOSENSORRHODAMINE 6G DERIVATIVEhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A method for the detection and quantitation of Hg2+ in aqueous samples by fluorescence spectroscopy is presented. It consists of a turn-on sensor developed by coupling Gold nanoparticles (AuNPs) with the rhodamine 6G derivative FC1, in which the response is generated by a mercury-induced ring-opening reaction. The AuNPs were included in order to improve the sensitivity of the method towards the analyte, maintaining its high selectivity. The method was validated in terms of linearity, precision and accuracy, and applied to the quantitation of Hg2+ in Milli-Q and tap water with and without spiked analyte. The limit of detection and quantitation were 0.15 µg·L-1 and 0.43 µg·L-1, respectively, constituting a substantial improvement of sensitivity in comparison with the previously reported detection of Hg2+ with free FC1.Fil: Brasca, Romina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral; ArgentinaFil: Onaindia, María Celeste. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral; ArgentinaFil: Goicoechea, Hector Casimiro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral; ArgentinaFil: Muñoz de la Peña, Arsenio. Universidad de Extremadura; EspañaFil: Culzoni, Maria Julia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral; ArgentinaMolecular Diversity Preservation International2016-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/71542Brasca, Romina; Onaindia, María Celeste; Goicoechea, Hector Casimiro; Muñoz de la Peña, Arsenio; Culzoni, Maria Julia; Highly selective and ultrasensitive turn-on luminescence chemosensor for mercury (II) determination based on the rhodamine 6G derivative FC1 and Au nanoparticles; Molecular Diversity Preservation International; Sensors; 16; 10; 10-2016; 1-121424-8220CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1424-8220/16/10/1652info:eu-repo/semantics/altIdentifier/doi/10.3390/s16101652info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:46:39Zoai:ri.conicet.gov.ar:11336/71542instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:46:40.174CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Highly selective and ultrasensitive turn-on luminescence chemosensor for mercury (II) determination based on the rhodamine 6G derivative FC1 and Au nanoparticles
title Highly selective and ultrasensitive turn-on luminescence chemosensor for mercury (II) determination based on the rhodamine 6G derivative FC1 and Au nanoparticles
spellingShingle Highly selective and ultrasensitive turn-on luminescence chemosensor for mercury (II) determination based on the rhodamine 6G derivative FC1 and Au nanoparticles
Brasca, Romina
AQUEOUS SOLUTION
AU NANOPARTICLES
FLUORIMETRIC ASSAY
HG2+ CHEMOSENSOR
RHODAMINE 6G DERIVATIVE
title_short Highly selective and ultrasensitive turn-on luminescence chemosensor for mercury (II) determination based on the rhodamine 6G derivative FC1 and Au nanoparticles
title_full Highly selective and ultrasensitive turn-on luminescence chemosensor for mercury (II) determination based on the rhodamine 6G derivative FC1 and Au nanoparticles
title_fullStr Highly selective and ultrasensitive turn-on luminescence chemosensor for mercury (II) determination based on the rhodamine 6G derivative FC1 and Au nanoparticles
title_full_unstemmed Highly selective and ultrasensitive turn-on luminescence chemosensor for mercury (II) determination based on the rhodamine 6G derivative FC1 and Au nanoparticles
title_sort Highly selective and ultrasensitive turn-on luminescence chemosensor for mercury (II) determination based on the rhodamine 6G derivative FC1 and Au nanoparticles
dc.creator.none.fl_str_mv Brasca, Romina
Onaindia, María Celeste
Goicoechea, Hector Casimiro
Muñoz de la Peña, Arsenio
Culzoni, Maria Julia
author Brasca, Romina
author_facet Brasca, Romina
Onaindia, María Celeste
Goicoechea, Hector Casimiro
Muñoz de la Peña, Arsenio
Culzoni, Maria Julia
author_role author
author2 Onaindia, María Celeste
Goicoechea, Hector Casimiro
Muñoz de la Peña, Arsenio
Culzoni, Maria Julia
author2_role author
author
author
author
dc.subject.none.fl_str_mv AQUEOUS SOLUTION
AU NANOPARTICLES
FLUORIMETRIC ASSAY
HG2+ CHEMOSENSOR
RHODAMINE 6G DERIVATIVE
topic AQUEOUS SOLUTION
AU NANOPARTICLES
FLUORIMETRIC ASSAY
HG2+ CHEMOSENSOR
RHODAMINE 6G DERIVATIVE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A method for the detection and quantitation of Hg2+ in aqueous samples by fluorescence spectroscopy is presented. It consists of a turn-on sensor developed by coupling Gold nanoparticles (AuNPs) with the rhodamine 6G derivative FC1, in which the response is generated by a mercury-induced ring-opening reaction. The AuNPs were included in order to improve the sensitivity of the method towards the analyte, maintaining its high selectivity. The method was validated in terms of linearity, precision and accuracy, and applied to the quantitation of Hg2+ in Milli-Q and tap water with and without spiked analyte. The limit of detection and quantitation were 0.15 µg·L-1 and 0.43 µg·L-1, respectively, constituting a substantial improvement of sensitivity in comparison with the previously reported detection of Hg2+ with free FC1.
Fil: Brasca, Romina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral; Argentina
Fil: Onaindia, María Celeste. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral; Argentina
Fil: Goicoechea, Hector Casimiro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral; Argentina
Fil: Muñoz de la Peña, Arsenio. Universidad de Extremadura; España
Fil: Culzoni, Maria Julia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral; Argentina
description A method for the detection and quantitation of Hg2+ in aqueous samples by fluorescence spectroscopy is presented. It consists of a turn-on sensor developed by coupling Gold nanoparticles (AuNPs) with the rhodamine 6G derivative FC1, in which the response is generated by a mercury-induced ring-opening reaction. The AuNPs were included in order to improve the sensitivity of the method towards the analyte, maintaining its high selectivity. The method was validated in terms of linearity, precision and accuracy, and applied to the quantitation of Hg2+ in Milli-Q and tap water with and without spiked analyte. The limit of detection and quantitation were 0.15 µg·L-1 and 0.43 µg·L-1, respectively, constituting a substantial improvement of sensitivity in comparison with the previously reported detection of Hg2+ with free FC1.
publishDate 2016
dc.date.none.fl_str_mv 2016-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/71542
Brasca, Romina; Onaindia, María Celeste; Goicoechea, Hector Casimiro; Muñoz de la Peña, Arsenio; Culzoni, Maria Julia; Highly selective and ultrasensitive turn-on luminescence chemosensor for mercury (II) determination based on the rhodamine 6G derivative FC1 and Au nanoparticles; Molecular Diversity Preservation International; Sensors; 16; 10; 10-2016; 1-12
1424-8220
CONICET Digital
CONICET
url http://hdl.handle.net/11336/71542
identifier_str_mv Brasca, Romina; Onaindia, María Celeste; Goicoechea, Hector Casimiro; Muñoz de la Peña, Arsenio; Culzoni, Maria Julia; Highly selective and ultrasensitive turn-on luminescence chemosensor for mercury (II) determination based on the rhodamine 6G derivative FC1 and Au nanoparticles; Molecular Diversity Preservation International; Sensors; 16; 10; 10-2016; 1-12
1424-8220
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1424-8220/16/10/1652
info:eu-repo/semantics/altIdentifier/doi/10.3390/s16101652
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Molecular Diversity Preservation International
publisher.none.fl_str_mv Molecular Diversity Preservation International
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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